Photochemical hydrogen production with ... - ACS Publications

May 14, 1985 - and Cadmium Zinc Sulfide Modified by Sliver Sulfide. Jean-Frangois Reber*1 11and Milos Rusek. Ciba-Geigy, Central Research Laboratories...
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J. Phys. Chem. 1986, 90, 824-834

824

Photochemical Hydrogen Production with Platinized Suspensions of Cadmium Sulfide and Cadmium Zinc Sulfide Modified by Sliver Sulfide Jean-Frangois Reber*1

11and

Milos Rusek

Ciba-Geigy, Central Research Laboratories, CH-4002 Basel, Switzerland (Received: May 14, 1985)

J. Phys. Chem. 1986.90:824-834. Downloaded from pubs.acs.org by UNIV OF WEST LONDON on 11/25/18. For personal use only.

An efficient hydrogen production can be achieved by irradiating suspensions of platinized CdS in solutions of S2~ and/or S032' ions. However, the photocatalytic activity of CdS powders strongly depends on their specific surface area. Only CdS photocatalysts with very low (