Photoinduced Ligand Redistribution Chemistry of Quadruply Bonded

Photoinduced Ligand Redistribution Chemistry of Quadruply Bonded Mo2Cl2(6-mhp)2(PR3)2 Complexes. Ann M. Macintosh, and Daniel G. Nocera*. Inorg...
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Inorg. Chem. 1997, 36, 1274

Additions and Corrections 1996, Volume 35 Ann M. Macintosh and Daniel G. Nocera*: Photoinduced Ligand Redistribution Chemistry of Quadruply Bonded Mo2Cl2(6-mhp)2(PR3)2 Complexes. Page 7137. Columns from Table 1 were cut and pasted into Table 2 to set formatting in Microsoft Word; we regrettably forgot to change the values upon performing this operation. Consequently, every value in Table 2 is incorrect. (The photolysis quantum yields described in the Abstract, however, are correct.) The corrected Table 2 is as follows. Table 2. Solvent Dependence of Selected Photophysical Data and Photolysis Quantum Yields for cis-Mo2Cl2(6-mhp)2(PMe2Ph)2 solvent

Φem

τ/ns

Φp/104 a

DMF THF C6H6

0.064 0.18 0.20

23 60 55

9.7 6.4 4.2

a Photolysis quantum yield for the disappearance of cis-Mo Cl (62 2 mhp)2(PMe2Ph)2 with 405-nm irradiation.

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© 1997 American Chemical Society