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Photosensitive Metal—Organic Systems
In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
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In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
ADVANCES IN CHEMISTRY SERIES 238
Photosensitive Metal—Organic Systems
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Mechanistic Principles and Applications
Charles Kutal, EDITOR University of Georgia
Nick Serpone, EDITOR Concordia University
Developed from a symposium sponsored by the Division of Inorganic Chemistry of the American Chemical Society
American Chemical Society, Washington, DC 1993
In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
Library ofCongressCataloging-in-PublicationData Photosensitive metal-organic systems : mechanistic principles and applications / Charles Kutal, editor, Nick Serpone, editor,
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p.
cm.—(Advances in Chemistry Series, ISSN 0065-2393; 238).
"Developed from a symposium sponsored by the Division of Inorganic Chem istry at the Fourth Chemical Congress of North America (202nd National Meeting of the American Chemical Society), New York, New York, August 25-30, 1991." Includes bibliographical references and index. ISBN 0-8412-2527-3 1. Photocatalysis—Congresses. 2. Organic compounds—Congresses. 3. Organometallic compounds—Congresses. I. Kutal, Charles. II. Serpone, Nick, 1939. III. American Chemical Society. Division of Inorganic Chemistry. IV. Chemical Congress of North America (4th : 1991 : New York, NY). V . Series QD1.A355 no. 238 [QD716.P45] 540 s—dc20 [547.1'35]
93-22823 CIP
The paper used in this publication meets the minimum requirements of American National Standard for Information Sciences—Permanence of Paper for Printed Library Materials, ANSI Z39.48-1984.
Copyright © 1993 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per-copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, M A 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means—graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN T H E UNITED STATES O F A M E R I C A
In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
1993 Advisory Board Advances in Chemistry Series M . Joan Comstock, Series Editor V . Dean Adams
Bonnie Lawlor
University of Nevada— Reno
Institute for Scientific Information
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Douglas R. Lloyd Robert J. Alaimo
The University of Texas at Austin
Procter & Gamble Pharmaceuticals, Inc.
Robert McGorrin Kraft General Foods
Mark Arnold University of Iowa
Julius J. Menn
David Baker
Plant Sciences Institute, U.S. Department of Agriculture
University of Tennessee
Vincent Pecoraro Arindam Bose
University of Michigan
Pfizer Central Research
Marshall Phillips Robert F. Brady, Jr.
Delmont Laboratories
Naval Research Laboratory
George W. Roberts Margaret A . Cavanaugh
North Carolina State University
National Science Foundation
A. Truman Schwartz Dennis W. Hess
Macalaster College
Lehigh University
John R. Shapley Hiroshi Ito I B M Almaden Research Center
University of Illinois at Urbana-Champaign
Madeleine M . Joullie
L. Somasundaram
University of Pennsylvania
DuPont
Gretchen S. Kohl
Peter Willett
Dow-Corning Corporation
University of Sheffield (England)
In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
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FOREWORD The A D V A N C E S IN C H E M I S T R Y SERIES was founded in 1949 by the Amer ican Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would other wise be fragmented because their papers would be distributed among several journals or not published at all. Papers are reviewed critically according to ACS editorial standards and receive the careful attention and processing characteristic of A C S publications. Volumes in the A D V A N C E S IN C H E M I S T R Y SERIES maintain the integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.
In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
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ABOUT THE EDITORS CHARLES KUTAL is a professor and Head of the Department of Chemistry at the University of Georgia. He received his Ph.D. and M . S . from the University of Illinois and his B.S. from Knox College. He is the recipient of the Undergradu ate Teaching Award and the Chemist of the Year Award of the Northeast Georgia section of the American Chemical Society. Kutal has authored more than 70 articles and chapters dealing with the photochemistry of inorganic and organometallic compounds, solar energy conversion and storage, and photosensitive polymer materials. He is coeditor of the books Solar Energy: Chemical Conversion and Storage and Electron Transfer in Biology and the Solid State.
NICK SERPONE is a professor and Director of the Laboratory of Pure and Applied Studies in Catalysis, Environment, and Materials in the Department of Chemistry and Biochemistry at Concordia University. He received his Ph.D. from Cornell University and his B.Sc. from Sir George Williams University. He was the founder and the first Director of the Canadian Center for Picosecond Laser Spectroscopy (1981-1987). He is the holder of one patent and has authored more than 180 journal articles and review papers, coedited three books, and jointly translated one book (French to English). He was visiting professor at the University of Bologna, Italy (1975-1976), an invited professor at the Ecole Polytech nique Fédérale of Lausanne, Switzerland (1983-1984), and a visiting pro fessor and Directeur de Recherche at the Ecole Centrale de Lyon, France (1990—1991). His principal research interests are in heterogeneous photocatalysis, environmental and inorganic photochemistry, picosecond laser spectroscopy, and imaging science.
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In Photosensitive Metal—Organic Systems; Kutal, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1993.
