Physicochemical hydrodynamics (Levich, Veniamin G.)

tive list of chemicals needed for the entire course, apparatus list for the student locker and additional equipment needed in the laboratory. A list o...
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observation. The student report includes a serieli of essay questions which require careful obsemation and interpretation of data. It is also suggested that the student report include equations for all the reactions involved. The experiments are a little more sophisticated than thhse found in the usual high school laboratory manual. Excellent suggestions are contained in the teacher's manual. These include a general commentary on each oxperirnent, lists of chemicals for each experiment, a quantitative list of chemicals needed for the entire course, apparatus list for the student locker and additional equipment needed in the laboratory. A list of stock solutions and their DreDaration is also included.

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JAMES H. LOEALIN College of W m t e r Wooster, Ohio PhysicochemiralHydrodynamics

Vaiomin G. Larich, Academy of Sciences, USSR. Translated by Seripta. Technica, Inc. Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1962. xvi 700 pp. Figs. and tables. 16 X 23.5 em. $15.

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This is the translation into English of the second edition of a book which was first published in the U.S.S.R. in 1952. The translation was prepared by Scripta Technica, Inc. and edited by L. E. Scriven assisted by A. Acrivos, J. Newman, T. J. ductory experiment on laboratory techHanratty, S. Bmckenstein, and W. E. niques appears to be very well written and Rana. I t should prove to he s. veritable easily followed by the beginner. gold mine of information for chemists and The author should be complimented far chemical engineers who deal with small his effort to improve upon the laboratory scale hydrodynamics including especidly instruction in the high school. the motion of drops, bubbles, and pt~rticles WILLIAMSCAEE~NER in fluid media, wave motion on s liquid surface, and motion in thin films. AlParma City Schools though the title of the book stresses hydroParma, Ohio dynamics, the other transport phenomena are not neglected. For instance, there are Calculations in Physieal Chemistry sections on convective diffusion to the surface of a rotating disk, diffusion in the B. W . V . Hawes and N . H. Dauies. concentration range near a critical solution John Wiley and Sans, Inc., New York, point, the passage of current through an 1062. xiv 203 pp. Tables. 14 X electrolytic solution, and the effect o 21 em. 54.50. surface active agents on the motion of This little book covers the areas of bubbles, dmps and waves. Many of these classical physical chemistry as well as topics ilre just beginning to attract attenhaving chapters an Atomic Physics and tion in the United States, and i t ia quite Nuclear Chemistry and Molecular S t n w surprising to find that Professor Levich ture. Each chapter consists of a series and his colleagues have been working of prnhlems with notes given to guide intensively on such problems for a period of 20 years during which the theory has the student in solving them. The result been developed to the point where an will give the studont practice in the authoritative monograph could be premanipulation of chemical calculation8 pared. but does not serve too well in giving The material has been presented in an him a better insight into the theory hehind the problem, so that he can later eaaily understood manner. Although the tackle the non-standard problems he may development of each topic eventually results in a mathematical analysis, the face. Answers for all problems are given sctuel calculations are usually accoma t the end of the book. panied by a good narrative discussion in The problcms a t r e for t h r most part fairly straightforward and routine, and which the salient points are clearly pre3ented. Within a. given broad area, the do not involve extensive calculations, zuthor frequently discusses s. series of graphicel integrations, etc., which are related problems of increasing complexity often encountered in practice. The book md physical reality. The methods of was designed to give British students higher mathematics are used whenever practice for the various examinations that they ilre required. However, one never are a part of the British educational :ets the feeling that the author is solving a system. Many of the problems are actually taken from previous examinations. mathematical exercise as an end in itself. In many cases, appropriate approximaRegretably the authors have not recalculated data to conform to the '*C = tions are used in order to reduce the eomolcxity of the analysis. As one would 12.W00 atomic mass scale. They also :rpcct, this means that most of the dishave not been consistent in their eonxssions of such phenomena. as diffusion to ventions of cell patentids and use bath Srope and particles are framed within the oxidation and reduction half-cell poten:ontext of boundary layer theory. tials rather than changing them to conThere may be a few advanced underform to recommendations of the Stockholm convention. (Continued on pare A829) equipment. All the laboratory equipment is pictured.

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Volume 40, Number 10, October 1963

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B O O K REVIEWS graduate students who have progressed t o the point where they can profitably study from this hook, but i t is probably brst desmibed as a. graduate level text. Since only five and one-half pages arc devoted to the continuity equation, the KavierStokrs equations, and hydrodpnsmic boundary conditions, study from a book such as "Transport Phenomena" hy Bird, Stcwnrt, and Lightfoot would appear to he a prrrequisite to effcetive use of "Physicorlrrmiesl Hydrodynamics." Roughly the snnw amount of space is devoted t o stating the erpations of eonvectivc diffusion. Alt,hongh t,ho book is not suitable as a first trxt, in transport phenomena, s t least not without extensive supplementiltion, there is little doubt that many of the topics disrussrd in it will find their way into advanced courses. The book is not a. particulilrly handsnme volume. The equations were apparently reproduced from the original Russian edition and, as s. result, the symbols used in the text are somewhat different than those used in the equations. Furthermore, too many of the letters are improperly iormcd; for instance, there are eleven flaws an page fiva On first reading, elcven ohvinus typographical errors were detected in the first sixty pages, but other sections were bettcr. I n summary, "Physicachemieal Hydrodynamics" is undoubtedly a n important hook which will influence thinking and

research for many yearn to come. Wc are fortunate that i t has been translated into English.

EUGE~VE H. WISSLER University of Tezas Austin

Nouveou Troiti d a Chemie Mindrole. Volume 9, Titene, Zirconium, Hafnium, a n d Thorium

Paul Pascal, general editor. Masson ot Cie., Paris, 1983. xnrix 1211 pp. Figs. and tables. 17.5 X 26 cm. ZOONF, broch6; 212NF, eartonnE toile.

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Volume 9 and the eighth volume of Pascal's new treatise on inorganic chemistry are organized to cover the materids concerning elements of Group IV. This volume is devoted to titanium, zirconium, hafnium, and thorium. ChrEtian and Freundlich are authors of the section un titanium, Albert, Langcron, and Lehr of that on zirconium and hafnium, and Flahaut is sale author of the section on thorium. About half of the volume is reserved for the material on zirconium and hafnium, and the remainder is about equally divided betw-een titanium and thorium. Much emphasis is placed upon processes for the extraction and pmification of the four elements, particularly for those involving zirconium and hafnium. Much attention has been given to the bibliographies, and there are some 6600 (Continued on page A8301

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