Anal. Chem. 2004, 76, 3236-3243
Pinched Inlet Split Flow Thin Fractionation for Continuous Particle Fractionation: Application to Marine Sediments for Size-Dependent Analysis of PCDD/Fs and Metals Myeong Hee Moon,*,† Hyun-Joo Kim,† So-Yeon Kwon,‡ Se-Jin Lee,§ Yoon-Seok Chang,§ and Heungbin Lim|
Department of Chemistry, Yonsei University, Seoul, 120-749, Korea, Department of Chemistry, Pusan National University, Pusan, 609-735, Korea, School of Environmental Science & Engineering, Pohang University of Science & Technology, Pohang, 790-784, Korea, and Department of Chemistry, Dankook University, Seoul, 140-714, Korea
It is demonstrated that split-flow thin (SPLITT) fractionation, a continuous separation technique for sorting particles or macromolecules, can be utilized for the fractionation of environmental particles to study a sizedependent analysis of pollutants. In this study, focuses are made on the use of a pinched inlet gravitational SPLITT fractionation, a modified form of SPLITT channel formed by reducing the sample inlet thickness of the channel to improve separation efficiency, to separate marine sediments into five different sizes (