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Plasmonic Nanoparticles as Light Harvesting Enhancers in Perovskite Solar Cells: a User's Guide Sol Carretero-Palacios, Alberto Jiménez-Solano, and Hernan Miguez ACS Energy Lett., Just Accepted Manuscript • Publication Date (Web): 17 Jun 2016 Downloaded from http://pubs.acs.org on June 17, 2016
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ACS Energy Letters
Plasmonic Nanoparticles as Light Harvesting Enhancers in Perovskite Solar Cells: a User’s Guide S. Carretero-Palacios, A. Jiménez-Solano, H. Míguez* Institute of Materials Science of Seville, Spanish National Research Council-University of Seville, Calle Américo Vespucio 49, 41092, Seville, Spain. *
[email protected] Abstract In this Perspective we discuss the implications of employing metal particles of different shape, size and composition as absorption enhancers in methyl ammonium lead iodide perovskite solar cells, with the aim of establishing some guidelines for the future development of plasmonic resonance based photovoltaic devices. Hybrid perovskites present an extraordinarily high absorption coefficient which, as we show here, makes it difficult to extrapolate concepts and designs that are applied to other solution processed photovoltaic materials. Besides, the variability of the optical constants attained from perovskite films of seemingly similar composition further complicates the analysis. We demonstrate that, by means of rigorous design, it is possible to provide a realistic prediction of the magnitude of the absorption enhancement that can be reached for perovskite films embedding metal particles. Based on this, we foresee that localized surface plasmon effects will provide a means to attain highly efficient perovskite solar cells using thinner films than usually employed, hence facilitating collection of photocarriers and significantly reducing the amount of potentially toxic lead present in the device.
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ACS Energy Letters
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The use of metallic nanostructures is frequently proposed as a means to enhance the performance of photovoltaic devices.1-6 In particular, the use of metal nanoparticles and arrangements of them have been explored for almost all types of solar cells,7 be they solid state8,9 or solution processed.10-23 Perovskite solar cells (PSC), based on thin semiconductor layers with hybrid organic-metal halide composition, are not an exemption.24-30 Although these films are already efficient light harvesters, several features motivate the development of new ways to enhance even further their absorption. First, for the typical film thicknesses for which high structural quality is attained, photon capture is not as high in the range of 600 nm
