Plutonium Chemistry - ACS Publications - American Chemical Society

(4) Hirschfeld, T. Presented at 185th ACS. National .... Solution Chemistry · Pu(IV) Hydrous Polymer. Chemistry ... Rocky Flats · Pyrochemical Proce...
0 downloads 0 Views 2MB Size
Acknowledgment I wish to express my g r a t i t u d e t o m y colleagues, specifically, N . L y n n J a r vis, A r t h u r Snow, J o h n F . Giuliani, William Barger, D a w n Dominguez, a n d J o h n L i n t for s t i m u l a t i n g discus­ sions a n d m a n y significant scientific c o n t r i b u t i o n s t o t h e chemical microsensor research p r o g r a m a t N R L .

References (1) Freiser, H. In "Ion Selective Electrodes in Analytical Chemistry"; Plenum Press: New York, N.Y., 1980; Vol. 2, Chapter 2. (2) Dayton, Μ. Α.; Brown, J. C ; Stutts, K. J.; Wightman, R. M. Anal. Chem. 1980, 52, 946-50. (3) Glaser, A. B.; Subak-Sharpe, G. E. "In­ tegrated Circuit Engineering"; AddisonWesley: Reading, Mass., 1979. (4) Hirschfeld, T. Presented at 185th ACS National Meeting, March 22,1983, Seat­ tle, Wash. (5) Petersen, K. E. Proc. IEEE 1982, 70(5), 420-57. (6) Bergveld, P. IEEE Trans. Biomed. Eng. 1970,17, 70-71. (7) Janata, J.; Huber, R. J. In "Ion Selec­ tive Electrodes in Analytical Chemistry"; Plenum Press: New York, N.Y., 1980; Vol. 2, Chapter 3. (8) "Workshop on Theory, Design and Biomedical Application of Solid State Chemical Sensors"; Cheung, P.; Fleming, D. G.; Ko, W. H.; Neuman, M. R., Eds.; CRC Press: Cleveland, Ohio, 1978. (9) Zemel. J. N. Anal. Chem. 1975,47, 255-68 A. (10) Lundstrom, L; Shivaraman, M. S.; Svensson, C. J. Appl. Phys. 1975, 46, 3876. (11) Zemel, J. N. Sensors and Actuators 1981,2,31-75. (12) Ruths, P. F.; Ashok, S.; Fonash, S. J.; Ruths, J. M. IEEE Trans. Electron De­ vices 1981, ED-28(9), 1003-9. (13) Gutman, F.; Lyons, L. E. "Organic Semiconductors"; Wiley: New York, N.Y., 1967. (14) Young, J. J.; Zemel, J. N. Thin Solid Films 1976, 31, 25. (15) van Ewyk, R. L.; Chadwick, A. V.; Wright, J. D. J. Chem. Soc, Faraday Trans. 1 1980, 76, 2194-2205. (16) Seiyama, T.; Kato, Α.; Fujishi, K.; Nagatani, M. Anal. Chem. 1962,34, 1502. (17) Chang, S. C. IEEE Trans. Electron Devices 1979, ED-26(12), 1875-80. (18) Morrison, S. R. Sensors and Actua­ tors 1982,2,329-41. (19) Clifford, P. K.; Tuma, D. T. Sensors and Actuators 1982/83,3, 233-81. (20) Senturia, S. D.; Sechen, C. M.; Wishneusky, J. A. Appl. Phys. Lett. 1977,30, 106. (21) Sheppard, N. F.; Day, D. R.; Lee, H. R.; Senturia, S. D. Sensors and Actu­ ators 1982, 2, 263-74. (22) Garverick, S. L.; Senturia, S. D. IEEE Trans. Electron Devices 1982, ED-29U ) , 90-94. (23) Wohltjen, H.; Dessy, R. E. Anal. Chem. 1979,52,1458-75. (24) King, W. H. Anal. Chem. 1964, 36, 1735. (25) Hlavay, J.; Guilbault, G. G. Anal. Chem. 1978,49,1890-98. (26) Bryant, Α.; Lee, D. L.; Vetelino, J. F. Proc. 1981 Ultrasonics Symposium, IEEE Cat. 81-CH1689-9, p. 1735. (27) Roederer, J. F.; Bastians, G. J. Pre­ sented at the Pittsburgh Conference, March 8,1983, Atlantic City, N.J.; Paper 274.

(28) Zemel, J. N.; Keramati, B.; Spivak, C. W. Sensors and Actuators 1981,1, 427-73. (29) Rahnamai, H. Anal. Chem. 1982,54, 142-43. (30) Velasico, G.; Schnell, J. Ph.; Croset, M. Sensors and Actuators 1982,2, 37184. (31) Fouletier, J. Sensors and Actuators 1982/83,3,295-314. (32) Terry, S. C ; Jerman, J. H.; Angell, J. B. IEEE Trans. Electron Devices 1979, ED-26U2), 1880-86. (33) Karasek, F. W. U.S. Patent No. 3 538 744,1970. (34) Angell, J. B.; Terry, S. C ; Barth, P. W. Sci. Am. 1983,248(4), 44-55. (35) Wohltjen, H.; Giuliani, J.; Jarvis, N. L., unpublished work, 1980-82. (36) Nylander, C ; Liederberg, B.; Lind, T. Sensors and Actuators 1982/83,3, 7988. (37) Bregman, J. I.; Dravnieks, A. "Surface Effects in Detection"; Spartan Books: Washington, D.C., 1965. (38) Hirschfeld, T.; Wong, F.; Deaton, T. Presented at the Pittsburgh Conference, March 9,1983, Atlantic City, N.J.; Paper 382 (39) Giuliani, J. F.; Wohltjen, H.; Jarvis, N. L. Opt. Lett. 1983,8(7), 54-56. (40) Rùzicka, J. Anal. Chem. 1983,55, 1040 A. (41) Hollman, R.; Little, W. A. Proc. NBS Conf. Refrigeration for Cryogenic Sensors and Electronics Systems, 1980; Special Publication 607, p. 160. (42) Aoki, K.; Osteryoung, J. J. Electroanal. Chem. 1981,122,19-35. (43) Campana, J.; Wohltjen, H., unpublished work, 1981.

Plutonium Chemistry

William T. Carnall, Editor Argonne National Laboratory Gregory R. Choppin, Editor Florida State University Reviews recent progress in plutonium chemistry. Reports on fundamental re­ search as well as applied environmental and process chemical research. Covers physical-inorganic chemistry and spectroscopy, solution chemistry and behavior of plutonium in the aquatic en­ vironment, and separations chemistry. Includes introductory chapter by Glenn T. Seaborg, Nobel laureate and codiscoverer of element 94 and numerous radioactive isotopes. CONTENTS

Hank Wohltjen is a research chemist at the U.S. Naval Research Laboratory (NRL). He received his undergraduate education—a BS in chemistry in 1972 and a BS in engineering science (electrical) in 1974—from the City University of New York, and his PhD (chemistry) from Virginia Polytechnic Institute. From 1978 to 1979 he was an IBM postdoctoral fellow in the Ε-beam lithography group at the T. J. Watson Research Laboratory in Yorktown Heights and was later em­ ployed in the New Devices group at IBM's research laboratory in Zurich, Switzerland, where he worked on mi­ crofabrication of Josephson effect su­ perconducting memory circuits. Since joining NRL in 1981 he has focused on development of new chemical microsensors and microinstrumentation.

Plutonium Chemistry: The Beginnings · Magnetic Properties of Organometallic and Coordination Compounds · Reaction of Pu Metal with Diiodoethane · Bis(M-hydroxo)tetraaquadiplutonium(IV) Sulfate · Superconductivity and Magnetism in Metallic Pu Systems · Pu Halides and Halogeno Complexes · Thermodynamics of Pu-Noble Metal Compounds · Thermodynamic Aspects of Pu-O System · Hypostoichiometric Pu Dioxide · x-Ray Photoemission Spectroscopy · PuFe Gas Photophysics and Photochemistry · Measurement and Interpretation of Pu Spectra · Stability and Electronic Spectrum of CsPuFe · Pu Solution Chemistry · Pu(IV) Hydrous Polymer Chemistry · Pu Ions and Products of H2O Radiolysis · Stability Constants, Enthalpies, and Entropies · Photochemistry of Aqueous Pu Solu­ tions · Behavior of Pu in Natural Waters · Aquatic Chemistry of Pu · Pu(IV) Ion in CarbonateBicarbonate Solutions · Ground-Water Composi­ tion and Pu Transport Processes · Overview of Pu Process Chemistry · Pu Process Chemistry at Rocky Flats · Pyrochemical Processing of Pu · Pu Production and Purification at Los Alamos · Carbamoylmethylphosphoryl Derivatives · Ap­ pendixes: Round Table Discussion; Pu Isotopes Based on a symposium jointly sponsored by the Divisions of Nuclear Chemistry and Technology and Analytical Chemistry of the American Chemical Society ACS Symposium Series No. 216 480 pages (1983) Clothbound LC 83-6057 ISBN 0-8412-0772-0 US & Canada $51.95 Export $62.95 Order from: American Chemical Society Distribution Office Dept. 24 1155 Sixteenth St., N.W. Washington, DC 20036 or CALL TOLL FREE 800-424-6747 and use your VISA or MasterCard.

ANALYTICAL CHEMISTRY, VOL. 56, NO. 1, JANUARY 1984 · 103 A