V O L U M E 28, N O . 4, A P R I L 1 9 5 6 (45) (46) (47) (48)
Harvey, P. G . , Pearson, R. l f . , Analyst 79, 158 (1954). Heusghem, C., S u t u r e 173, 1043 (1954). Holxbecher, Z., Chem. Lis& 47, 680, 1023 (1953). Holxbecher, Z., Collection Czechosloc. Chem. Communs. 20, 193
(1955). (49) Horhammer, L., Hansel, R., Arch. Pharm. Berlin 285, 438 (1952). (50) Ibid.,286, 153, 425, 447 (1953). (51) Horhammer, L.. Xuller, K. II.,Ibid.,287, 310, 376 (1954). (52) Indemans, -4.W.M.,Cheni. Weekblad 50, 236 (1954). (53) Irving, H., Rossotti, H. S.,Analust 80. 245 (1955). Jarrell-Ash Co., Xewtonville, Mass., AIfr, Bull., 1954 JeDson. J . B.. Stevenb. B. J.. S u t u r e 172. 772 (1953). Kacl, K., yecerek, B., T’ecerkova, J., Chundela. B., 6asopis LBkdfzi Ceskkch. 93, 621 (1954). Kelley, AI. T., Heniphill. H. L., Collier, D. AI., U. S. =Itomic Energy Coinm. Rept.. ORNL-1445(1954). Kinser, C. A , , U. S. Geol. Survey Circ. 330 (1954). Konstantinova-Slileziiiger, AI. A , , A c a d . .Yaitk .~fosco~o, ,S.S.,S.X., Otdel. Fiz.-.lfat. S a u k 1954. Kring, J. P., Williams. J. S . .J . Biol. Chem. 212, 751 (1955). Kul’berg, L. AI., Il‘ina, T. S.,L-krain. l i h i m . Zh7rr. 21, 97 (1955). Liebhafsky, H . .I., -%SAL. CHEM.26, 26 (1954). Lynch, F. J., Baumgardner, J . R., Xm. Sei. I n s f r . 26, 435 (1955). lIc.4nally, J. S., .Is.ii..CHEM.26, 1526 (1954). Manger, W.AI.. coworkers, Proc. M a y o Clinic 28, 526 (1953). Alavrodineanu. R . . Sanford, W.B.. Hitchcock, A. E., Contribs. Boyce Thornpsorz I?ist. 18, 1 G i (1955). IIjller, G . D., Johnson, J. A,, Div. Anal. Cliein., 127th meeting .4CS, llinneapolis, Alinn.. 1955. Seu, I\-illbe necessary to take account of them in the theory. Furness (67) has studied the change in potential of the dropping mercury electrode during formation of individual drops. He points out that the potential of the drop is a function of current, and inasmuch as the current varies with the drop life, the potential varies also. A s a consequence it is most reliable to measure both current and potential a t the mauimnm drop size. Limiting Currents Controlled by Reaction Rates. BrdiEka and Kiesner in 1943 were the first to consider the effect of slow chemical reactions a t the surface of the dropping electrode on polarographic limiting currents. During the past few years, there have been very intensive theoretical studies on this and similar problems related to irreversible waves. Inve3tigators in ~1idely separated laboratories, notably II., ANAL.CHEx 24, 1183 (1952). (198) Alenegus-Scarpa, PI.,Ricerca sci. 24, Sup. A (1954). (199) llenegus-Scarpa, AI., Gagliardo, E., Ibid., 23, Sup. -4(1953). (200) 3Ienegus-Srarpa, AI., Tosini, B.. Ibid., 25, Sup. .L (1955). (201) Aliller, 6. L., J . A m . Chem. SOC.74, 4130 (1952). (202) lliller, S. L.. Orlemann, E. F., Ibid.. 75, 2001 (1953). (203) lICiller, 0 . H., -&SAL. CHEM.23, 1175 (1951). (204) 3liiller. 0 . H., Satl. Bur.. Standards Circ. 524 (1953). (205) l l f i l l c r , 0 . H., “Polarographic Method of Analysis.” 2nd ed., C‘hemical Educational Publishing Co., Easton, Pa.. 1951. (206) N u n d y . B. IT., Xllen, N. IF-,,J . Chem. Educ. 30, 143 (1953). (207) Keavadba, O., Collection Czechosloc. Chem. Communs. 15, 751 (1950). (208) Sicholson, 31. JI., ANAL.CHEY.27, 1366 (1955). (209) Sicholson, AI. AI., J . Am. Chem. SOC.76, 2539 (1954). (210) Xicholson, hI. AI., Karchmer, J. H., A s . 4 ~ .CHEM.27, 1095 (1955). (211) Oldham, K. B., J . Ani. Chem. Soc. 77, 4697 (1955). (212) Oldham, K. B., Kivalo, P., Laitinen, H. .4.,Ibid., 75, 5712 (1953). (213) Orlemann, E. F., Kern, D. >I. H., IEid., 75, 3058 (1953). (214) Orlemann. E. F., Kolthoff, I. A I . , Ibid., 64, 833 (1942). (215) Overton, K. C., Lewis, J. A , Chemistry and Industru 1952, 106. (216) PapouGk, D., Collection Czechoslov. Chem. Communs. 20, 251 (1955). (217) Peattie, C. G., Hume, D. X., unpublished experiments, 1951. (218) Pecsok, R. L., Juvet, R. S., ANAL. CHEM.27, 165 (1955). (219) Pesce, AI. R., Knesbach, S. L., Ladisch, R. K., Ibid., 25, 979 (1953). (220) Pliva, J., Collection Czechos7oc. Chem. Communs. 18, 7 (1953). (221) Pliva, J., Smutek. AI., Ibid., 19, 210 (1954). (222) Proske, G. E. O., ASAL. CHEY.24, 1834 (1952).
637 (223) Radin, N., DeVries, T., Ibid., 24, 971 (1952). Cooke, W. D., Furman, K. H., Ibid., 23, 1223 (224) Reilley, C. K,, (1951). (225) Ibid., 23, 1226 (1951). (226) Reilley, C. N., Everett, G. W.,Johns, R . H., Ibid., 27, 4S3 (1955). (227) Reilley, C. N , Scribner, W. G., Ibid., 27, 1211 (1955). (228) Reynolds, G. F., -4nal. Chim. dcta 6 , 567 (1952). (229) Reynolds, G. F., Davis, H. AI., -4nalyst 78, 314 (1953). (230) Reynolds, G. F., Shalgosky, H. I., A n a l . Chim. Acta 10, 3Sti (1954). (231) Riccoboni, L., Papott, P., Biancani, AI., Atti. accad. liricei 350, 1 (1953). (232) Riha, J., Collection Czechoslou. Chem. Comnzuns. 16, 479 (19211. 1233) Roberts. E. R.. Meek. S. S.. Analvst 77. 43 (1952). (234j Rogers, ‘L. B., killer, H. H:, Goodrich,’K. B., Stehney, A. Y., A N A L . CHEM.21, 777 (1949). (235) Rosie, D. J., Cooke, W.D., I b i d . , 27, 1361 (1955). (236) Sargent, E. H., Co., Chicago, “Bibliography of Polarograpliic Literature,” 1945. (237) Sargent, J. W., Clifford, -1.L., Lemmon, W. K.,ASAL.C H Z l f . 25, 1727 (1953). (238) Schaap, W.B., 3Iessner. A. E., Schmidt, F. C.. J . Am. Chew. SOC.77, 2683 (1955). (239) Scheffel, G., Z . Elektrochem. 58, 793 (1954). (240) Seagers, W.S., Frecliani, H. A, A s . 4 ~ CHEM. . 26, 1099 (1954). (241) Semerano, G., Ricerca sci. 19, Sup. A (1949). (242) Senda, hI., Okuda, &I., Tachi, I., Bull. Chem. SOC.Japan 28, 31, 37 (1955). (243) SevLk, L., Collection Csechoslov. Chem. Communs. 18, 439 (1953). (244) Shain, I., Crittenden, a.L., AXAL.CHEM.26, 281 (1954). (245) Simonnin, 31. P., Quintin, AI., Compt. rend. 237, 1409 (1953); 238, 892 (1954). (246) Smith, G. S., Analyst 75, 440 (1950). (247) Smoler, J., Collection Czechoslot. Chem. Comwiuns. 19, 238 (1954). (248) Smutek, I T . , Ibid., 18, 171 (1953). (249) Ibid.. 19. 24 (1954). (250j Ibid., 20; 247(1955). (251) Snowden. F. C., Page, H. T., ASAL. CHEY.24, 1152 (1952). (252j Stackelberg, 11. on, 2 . Elektrochem. 57, 338 (1953). (253) Stackelberg, AI. von, Toome, V., Leybold Pol. Ber. 1, 55 (1953). (254) Stackelberg, 31. von, Toome, V., 2. Elektrochem. 58, 226 (1954). (255) Stankoviansky, E., Collection Czechoslov. Chem. Communs. 15, 734 (1950). (256) Sto11, W.,Berbulk, H., Monatsh. 84, 1179 (1953). (257) Strassner, J. E . , Delahay, P., J . Am. Chem. SOC. 74, 6232 (1952). (258) Etrehlow, H., Midrich, O., Stackelberg, AI. von, Z . Elektrochem. 55, 244 (1951). (259) Streuli, C. A . , Cooke, W.D., ASAL. CHEM.25, 1691 (1953). (260) Ibid., 26, 963 (1954). (261) Streuli, C . A., Cooke, JT. D., J . P h y s . Chem. 57, 824 (1953). (262) Tanford, C., TTawzonek, S.. Ann. Be?. Phys. Chem. 3 , 247 (1952). (263) Tavlor. J. K.. Smith. R. E.. J . Research .Tat!. B u r . Standards 48, 172 (1952). (264) Toekstein, A , , Collection Czechoslov. Chem. Communs. 16, 101 (1951). (265) Valenta. P., I b i d . , 16, 239 (1953). (266) Week. A. A.. Ibid . 16, 230 (1951). (267) Ibid.. p. 465. (268) Ibid., 19, 862 (1954). (269) Ibid., 20, 400 (1955). (270) Ibid., p. 894. (271) Ibid., p 988. (272) W&hlin,E., Radzometer Polaropaphics, 1, 113 (1952). (273) WBhlin, E., Hans, W., 2 . Elektrochem. 56, 130 (1952). (2741 Waweonek. s.. -4iShL. C H E Y . 24. 32 (1952). (275) Ibid., 26, 65 (1954). (276) Kawzonek, S., Runner, M. E., J . Electrochem. SOC. 99, 457 (1952). (277) Weaver, J. R., Parry, R. I\’., J . Am. Chem. SOC.76, 6258 (1954). (278) Weber, 0. A., Archie Kem. 25, 231 (1953). (279) Wiesner, K., ANAL.CHEM.27, 1712 (1955). (280) Wilson, L. D., Smith, R. J., Ibid., 25, 218, 334 (1953). (281) Yashiro, Y., Bull Chem. SOC. J a p a n 27, 564 (1954). (282) Zimmerman, H. K., Jr., Gropp, A. H., J . P h y s . Colloid Chem. 54, 764 (1950). (283) Zuman, P., Collection Czechoslov. Chem. Communa. 15, 1107 (1950). ,
I
