3524
J. Phys. Chem. B 1999, 103, 3524-3528
Positive and Negative Contrast Lithography on Silver Quantum Dot Monolayers Sven E. Henrichs, Jennifer L. Sample, Joe J. Shiang, and James R. Heath* UCLA Department of Chemistry and Biochemistry, 405 Hilgard, Los Angeles, California 90095-1569
Charles P. Collier and Richard J. Saykally Department of Chemistry, UniVersity of California, Berkeley, California 94720-1460 ReceiVed: January 6, 1999; In Final Form: March 1, 1999
Scanning nonlinear optical microscopy, at a resolution of ∼2 µm, was utilized to examine monolayers of alkylthiol-passivated silver nanocrystals. Selected regions of the monolayers were irradiated with a pulse train of picosecond 1064 nm laser pulses, and then the second harmonic generation (SHG) response of those monolayers was recorded in a second scan. Two lithographic processessone leading to a negative contrast SHG image (observed for particles
