Positronium Production in Engineered Porous Silica - The Journal of

Nov 28, 2013 - Positronium (Ps) has been the subject of several experimental and theoretical investigations due to its many scientific applications. I...
1 downloads 12 Views 808KB Size
Download PDF
Article pubs.acs.org/JPCC

Positronium Production in Engineered Porous Silica Rafael Ferragut,*,†,‡ Stefano Aghion,†,‡ and Gaia Tosi† †

LNESS and CNISM, Dipartimento di Fisica, Politecnico di Milano, Via Anzani 42, 22100, Como, Italy Istituto Nazionale di Fisica Nucleare, via Celoria 16, 20133 Milano, Italy

‡

Giovanni Consolati‡,§ and Fiorenza Quasso§ §

Department of Aerospace Science and Technology, Politecnico di Milano, via La Masa 34, 20156, Milano, Italy

Mariangela Longhi∥ ∥

Dipartimento di Chimica, Università degli Studi di Milano, via Golgi 19, 20133, Milano, Italy

Anne Galarneau⊥ and Francesco Di Renzo⊥ ⊥

Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM2-ENSCM-UM1, ENSCM, 8 Rue Ecole Normale, 34296, Montpellier, France S Supporting Information *

ABSTRACT: Positronium (Ps) has been the subject of several experimental and theoretical investigations due to its many scientific applications. In this work high positronium yield was found in engineered porous silica. The studied materials were pellets of swollen MCM-41 and of commercial Davicat 1700, obtained by different compression pressures, with mesopores characterized by different structural and chemical features. The measurements were performed with a variable energy positron beam at room temperature. An estimation of the Ps mean diffusion length was obtained by measuring capped samples. A selected swollen MCM-41 sample (0.39 g/cm3) was measured also at cryogenic temperature (8 K). In this material both the Ps yield and the Ps diffusion length are found to be independent of temperature. The pore surface of the swollen MCM-41 samples is very interesting in comparison to commercial silica as it possesses hydrophobic patches to avoid ice formation at low temperature. Positron lifetime measurements show a high Ps survival time inside the mesoporous materials (∼110 ns), which promotes a high Ps mobility during cooling inside the pores favoring diffusion lengths up to 1 μm for swollen MCM-41 materials. Besides, it was possible to estimate the total Ps yield coming up outside the sample at high implantation energies and the time between the implantation of positrons and the Ps release.

■

INTRODUCTION Positronium (Ps) is the lightest element, about 10−3 times lighter than hydrogen, and exists in the ground state in two sublevels: singlet (para-Ps, p-Ps) and triplet (ortho-Ps, o-Ps), according to the spins of the electron and positron (antiparallel or parallel, respectively). In a vacuum, their lifetimes are very different, 0.125 and 142 ns for p-Ps and o-Ps, respectively. Also, annihilation features in a vacuum are different: p-Ps annihilates with emission of two γ rays (511 keV each), while o-Ps annihilates by emitting three γ rays, producing a continuous energy distribution for each photon between 0 and 511 keV, where the energy sum of the three photons of the o-Ps annihilation is 1022 keV. When o-Ps is formed inside a porous material, the three γ annihilation probability is reduced by the pick-off effect, that is, the positron of the o-Ps annihilates with © 2013 American Chemical Society

an electron of the porous surface, rather than the o-Ps electron, in a relative singlet state with emission of two γ rays instead of three. Considerable attention has been given to the production of Ps for scientific applications: as a pathfinder inside porous materials (mesopores, zeolites, low-k insulators or semiconductors, polymers, etc.) to study open or closed porosities, their morphology, size, tortuosity, and so on.1 Another potential use is for high density Ps physics, for instance, to form molecular positronium (Ps2)2 and for creating BoseEinstein condensates of Ps. To this last purpose, the production Received: October 15, 2013 Revised: November 26, 2013 Published: November 28, 2013 26703

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709

The Journal of Physical Chemistry C

Article

of a very high density of positronium (1018 cm−3) is necessary. In this condition the development of a γ ray laser could be possible.3 Another very interesting use is the development of an energy-tunable Ps beam using photodetachment of the positronium negative ion (a bound state of one positron and two electrons) that is expected to be a powerful tool for the investigations of atoms, molecules, and solid surface structures.4 On the other hand, Ps is used for basic studies of antimatter. Indeed, some fundamental questions of modern physics relevant to unification of gravity with the other fundamental interactions, models involving vector and scalar gravitons, matter−antimatter symmetry can be enlightened via experiments with antimatter.5 In this respect, the main goal of the AEgIS (antihydrogen experiment: gravity, interferometry, spectroscopy) collaboration at CERN is to measure for the first time the gravitational interaction between antimatter and matter.6,7 The aim is to produce cold antihydrogen (at about 0.1 K) by means of a charge exchange reaction8 between cold antiprotons and Ps previously excited in a Rydberg state (with 20 ≤ n ≤ 35) by means of two laser pulses.9 Therefore, to obtain a high Ps yield as cold as possible is a critical point for the success of the experiment. Silica-based mesoporous materials are extensively investigated since a high fraction of the implanted positrons form Ps inside them,10 which can be emitted in the pore with kinetic energy of 1−3 eV.11 o-Ps loses its kinetic energy and cools down by means of collisions with the walls of the pore. Another interesting characteristic of porous silica is that, as a consequence of a low pick-off decay rate, o-Ps has a high survival time before annihilation, comparable with the Ps lifetime in vacuum. The long o-Ps lifetime allows a high diffusivity during scattering and ensures o-Ps escape into vacuum, even if it has been produced in depth with positrons implanted at energies higher than 5 keV. In general, for the purposes outlined above it is fundamental to produce cold o-Ps outside a silica porous material; however, only few papers report studies on Ps formation below room temperature.10 The interest of the present work is related mainly to the AEgIS experiment. An efficient formation of cooled positronium atoms is a requisite for the production of antihydrogen (H̅ ) in the AEgIS experiment. The AEgIS experiment will be performed at cryogenic temperatures (∼100 mK). At these temperatures, even in ultrahigh vacuum conditions, water is present among the residual gases inside the chamber, and the formation of ice inside the mesoporous surface of the silica is certain. Indeed, it is known that silica is intrinsically hydrophilic, for this reason, it is extensively used as a liquid sorbent or humidity sensors.12 It is possible to practically eliminate water by means of a baking of the vacuum chamber. However, when delicate electronic instruments are involved in the chamber and when the chamber is connected to an extended line of particles, that is the case of the AEgIS at the antiproton decelerator (AD) facility at CERN, an efficient baking is not feasible. In this context, it is important to test the properties of locally hydrophobic silica porous materials such as MCM-41, able to prevent cryogenic water adsorption. In fact, MCM-41 possesses hydrophobic patches due to the presence of siloxane groups at the corner of the pores13,14 and swollen MCM-41 (obtained by addition of trimethybenzene in the micelles) possesses additional hydrophobic patches on the surface on the pores.15 An advanced characterization of engineered silica porous samples as swollen MCM-41 and Davicat with different

densities by means of positron annihilation techniques and physical adsorption of gas molecules is presented in this work. These materials have a high Ps yield, high survival Ps lifetime, and a high Ps mobility during cooling. Besides, by using a classical diffusion model, in particular for MCM-41 with a density of 0.39 g cm−3, our results and calculations indicate that an important fraction of Ps escapes into the vacuum in tens of nanoseconds also for high positron implantation energies.

■

EXPERIMENTAL SECTION Two swollen MCM-4115−17 samples, named thereafter MCM41, were prepared in autoclave at 388 K by using cetyltrimethylammonium bromide (CTAB), 1,3,5-trimethylbenzene (TMB) as swelling agent, pyrogenic silica (Aerosil 200 Degussa), sodium hydroxide, and deionized water in molar ratios 1 SiO2/0.26 NaOH/0.035 NaAlO2/0.1 CTAB/20 H2O/ 1.3 TMB. The resulting samples were dried at 353 K and calcined in air at 773 K for 8 h. For the sake of comparison, another sample was prepared using commercial silica Davicat SI 1700 (purchased from Grace-Davison). The MCM-41 and Davicat samples were compressed to form pellets with a thickness of 5−6 mm and a diameter of 13 mm. The pressure used to form the pellets is critical for the stability of the material. The mechanical stability of MCM-41 depends on their pore size and the thickness of the silica walls between the pores. In the case of swollen MCM-41, it has been shown that, while the pore size is retained for pressure as high as 160 MPa, 20% of the pore volume is already lost after a compression to 80 MPa.18 The swollen MCM-41 samples used in this work were compressed at 7 and 30 MPa. The densities of the samples were, respectively, 0.21 and 0.39 g cm−3, and both samples presented mesoporous volume of 1.84 cm3 g−1 (Figure S1, Table S1). The Davicat sample was compressed at 73 MPa in order to decrease the macropore volume. It presented a density of 0.60 g cm−3 with a mesoporous volume of 1.32 cm3 g−1 (Figure S1, Table S1). One face of each sample was capped with an Al film having a thickness of about 120 nm. The capping layers were deposited by molecular beam epitaxy. Ps formation measurements were performed by means of a variable energy positron beam, with energy up to 18 keV, using the well-known “3γ method” and detecting the γ rays with a high purity germanium detector.19−21 These measurements were carried out in a high vacuum condition (about 10−8 mbar), at two different temperatures: cryogenic temperature (8 K) and room temperature (295 K). Lifetime measurements were performed with a fast−fast timing coincidence system with a time range of about 800 ns (8192 channels, 0.1 ns by channel) and a resolution (fwhm) of 260 ps. A 10 μCi source of 22NaCl deposited between two thin Kapton foil (7.5 μm each) was sandwiched between one porous sample and a tungsten sheet. For each sample, three measurements were carried out; each spectrum contained about 2 × 106 counts. Each sample was inserted in a glass vial and evacuated by a turbo pump; the measurements started after the vacuum level was better than 2 × 10−5 mbar. Spectra were analyzed using the LT program in four components.22 Surface area, pore volume, and mesopore size were determined from N2 adsorption/desorption isotherms at 77 K using a Tristar II 3020 Micromeritics apparatus. Before each measurement, samples were outgassed under vacuum at 523 K for 12 h. Surface area was calculated by the BET method, the pore volume was calculated at the end of mesopore filling, and mesopore diameter was determined by the Broekhoff and de 26704

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709

The Journal of Physical Chemistry C

Article

Table 1. Lifetimes, Intensities, and Radii Resulting from the Time Annihilation Spectra of the Samples MCM-41 (A and B) and Davicat (C) Measured at Room Temperature sample

τ1 (ns)

I1 (%)

τ2 (ns)

I2 (%)

τ3 (ns)

R3 (nm)

I3 (%)

τ4 (ns)

R4 (nm)

I4 (%)

A (0.21 g cm−3) B (0.39 g cm−3) C (0.60 g cm−3)

0.21(3) 0.22(3) 0.24(3)

43(3) 48(3) 44(3)

0.57(3) 0.60(3) 0.59(3)

41(3) 34(3) 44(3)

2.6(2) 3.1(2) 3.2(2)

0.34(1) 0.37(1) 0.38(1)

4.9(4) 3.9(4) 4.1(4)

109(4) 106(4) 111(4)

6.1(5) 5.8(5) 6.2(5)

11.0(6) 13.3(6) 8.2(6)

Boer method using a cylindrical geometry of pores and demonstrated as one of the more accurate methods to evaluate mesopore size of silica materials.17

■

RESULTS AND DISCUSSION Positron lifetime measurements were carried out in the three mesoporous silica samples with different densities: 0.21 g cm−3 (sample A, MCM-41), 0.39 g cm−3 (sample B, MCM-41), and 0.60 g cm−3 (sample C, Davicat). Since only one sample was available for each density, the positron source was inserted between a sample and a tungsten sheet, where Ps is not formed, in order to annihilate all the emitted positrons. Indeed, the goal was to determine Ps lifetime. The results are shown in Table 1. The two shorter lifetime components are ascribed to free positrons, which annihilate in the bulk and in the defects as well as to p-Ps, whose component, having faint intensity, cannot be distinguished from the others. The lifetime of the third component (a few ns) probably comes from o-Ps annihilating in structural defects of the samples. The fourth component (∼100 ns) is the most interesting one, because it can be attributed to o-Ps annihilations into the pores. It is possible to relate such a lifetime to the pore size through a quantum mechanical model originally proposed by Tao and further worked out by Eldrup et al.23,24 In the case of lifetimes of the order of 100 ns or more, as in our samples, to take into account possible excited states into the pores it is necessary to use the so-called extended Tao−Eldrup model.25,26 The radii shown in Table 1, near the corresponding lifetimes, were obtained by using the Tao−Eldrup model in spherical geometry for the third component, or the extended Tao−Eldrup model in cylindrical geometry for the longest component. Due to the presence of the tungsten layer, it is not significant to discuss the intensity of the various components. In spite of the different densities, the o-Ps lifetimes in the three investigated samples are very similar, within the experimental uncertainties, which means that the pore structures are practically the same. There is only a decrease of the intensity I4 in sample C (Davicat) with respect to the samples A and B (MCM-41), that is correlated to a lower pore density. In particular, mesopore diameters obtained by the extended Tao−Eldrup model in cylindrical geometry (∼12 nm) are in accordance with N2 physisorption measurements, giving average diameters in the range of 9−15 nm, with a surface area of about 830 m2 g−1 for samples A and B and 390 m2 g−1 for sample C (Figure S1, Table S1). These pore diameters are in the range of optimum values for o-Ps thermalization.27,28 Investigation of o-Ps formed in the pores near the surface of MCM-41 and Davicat samples (A−C) was carried out by sending a beam of monoenergetic positrons on each sample; positron implantation energy was variable between 1 and 18 keV. Measurements were performed at 8 and 295 K. Figure 1 shows high o-Ps yield as a function of the implantation energy for the studied samples. The maximum positronium fraction F3γ in Figure 1 is about 55, 53, and 49% in samples A, B, and C, respectively. According to the high survival time, the produced o-Ps thermalizes by means of thousands of collisions with the

Figure 1. Positronium 3γ fraction F3γ as a function of the positron implantation energy in uncapped and capped swollen MCM-41 (samples A, 0.21 g cm−3; and sample B, 0.39 g cm−3) and Davicat (sample C, 0.60 g cm−3) measured at room temperature and at 8 K in the case of sample B. The continuous lines used for capped samples are the result of the VEPFIT model and the dashed lines are only a visual guide. Error bars are only shown for one point in each evolution.

pore walls (see τ4 in Table 1). The comparison between sample B (MCM-41) evolutions taken at 8 and 295 K demonstrates that the positronium yield does not depend on temperature for any implantation energy (see also ref 29), as also previously observed by Crivelli et al. for ordered mesoporous silica films.28 Sferlazzo et al. have shown that in crystalline SiO2 the physisorbed o-Ps emitted from the surface depends on the temperature, but the o-Ps produced in the SiO2 bulk is independent of the temperature.30 The observed temperature independence in MCM-41 samples indicates that o-Ps might be produced only into the silica bulk. Another possibility would be that the MCM-41 surface modification with the introduction of hydrophobic patches might have changed the temperature dependence and the o-Ps surface component still exists. The decrease of F3γ observed at low energy in Figure 1 (uncapped samples) is due to the o-Ps emission into vacuum, which implies a decrease of the o-Ps detection efficiency. In these samples, o-Ps yield is remarkably high for any implantation energy in comparison to the thin mesoporous films where it is possible to obtain high yields only at low energies.27,28 High yield at high implantation energies requires rather thick samples (at least of tens of micrometers), a condition easily met with homogeneous and robust pellets. These results are very promising for further work, which will be performed on these materials in the AEgIS experiment at very low temperatures, around 0.1 K. In fact, as outlined in the introduction water vapor absorption by SiO2 at temperatures below 150 K was ascertained even in ultrahigh vacuum conditions.31,32 However, swollen MCM-41 possesses intrinsically hydrophobic patches on their porous structure.13−15 Our results indicate that the effect of gas adsorption or condensation 26705

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709

The Journal of Physical Chemistry C

Article

at low temperature does not influence the o-Ps yield for MCM41. When the porosity is very high and the pores are interconnected, o-Ps diffuses during cooling. In order to obtain the positronium diffusion length LPs and to prevent o-Ps escape into the vacuum, the mesoporous samples were capped by an Al film. The room temperature results are shown in Figure 1 for MCM-41 and Davicat samples of different densities. Sample B (MCM-41) was measured also at low temperature (8 K) and the results show that the distribution does not depend on temperature. Ps formation is almost zero for implantation energies of about 2 keV; indeed, all the incident positrons annihilate in the metallic layer where no Ps formation is expected. At lower energies (5 keV), independently on the temperature and on the effect of gas adsorption at low temperature, long survival time of Ps inside the pores, and very high Ps mobility. The obtained results and calculations indicate that Ps escape into vacuum is consistent with the literature data in homogeneous silica porous materials where thermalized Ps overcome the interface with the vacuum.35−37 26707

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709

The Journal of Physical Chemistry C

■

Article

(16) Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Ordered mesoporous molecular sieves synthesized by a liquidcrystal template mechanism. Nature 1992, 359, 710−712. (17) Galarneau, A.; Desplantier, D.; Dutartre, R.; Di Renzo, F. Micelle-templated silicates as a test bed for methods of mesopore size evaluation. Microporous Mesoporous Mater. 1999, 27, 297−308. (18) Galarneau, A.; Desplantier-Giscard, D.; Di Renzo, F.; Fajula, F. Thermal and mechanical stability of micelle-templated silica supports for catalysis. Catal. Today 2001, 68, 191−200. (19) Mills, A. P., Jr. Positronium formation at surfaces. Phys. Rev. Lett. 1978, 41, 1828−1831. (20) Ferragut, R.; Calloni, A.; Dupasquier, A.; Consolati, G.; Quasso, F.; Giammarchi, M. G.; Trezzi, D.; Egger, W.; Ravelli, L.; Petkov, M. P.; Jones, S. M.; Wang, B.; Yaghi, O. M.; Jasinska, B.; Chiodini, N.; Paleari, A. Positronium formation in porous materials for antihydrogen production. J. Phys: Conf. Ser. 2010, 225, 012007 (8pp). (21) Canesi, E. V.; Binda, M.; Abate, A.; Guarnera, S.; Moretti, L.; D’Innocenzo, V.; Sai Santosh Kumar, R.; Bertarelli, C.; Abrusci, A.; Snaith, H.; Calloni, A.; Brambilla, A.; Ciccacci, F.; Aghion, S.; Moia, F.; Ferragut, R.; Melis, C.; Malloci, G.; Mattoni, A.; Lanzani, G.; Petrozza, A. The effect of selective interactions at the interface of polymer-oxide hybrid solar cells. Energy Environ. Sci. 2012, 5, 9068−9076. (22) Kansy, J. Microcomputer program for analysis of positron annihilation lifetime spectra. Nucl. Instrum. Methods Phys. Res. A 1996, 374, 235−244. (23) Tao, S. J. Positronium annihilation in molecular substances. J. Chem. Phys. 1972, 56, 5499−5510. (24) Eldrup, M.; Lightbody, D.; Sherwood, N. J. The temperature dependence of positron lifetimes in solid pivalic acid. Chem. Phys. 1981, 63, 51−58. (25) Goworek, T.; Ciesielski, K.; Jasinska, B.; Wawryszczuk, J. Positronium states in the pores of silica gel. Chem. Phys. 1998, 230, 305−315. (26) Gidley, D. W.; Frieze, W. E.; Dull, T. L.; Yee, A. F.; Ryan, E. T.; Ho, H.-M. Positronium annihilation in mesoporous thin films. Phys. Rev. B 1999, 60, R5157−R5160. (27) Mariazzi, S.; Bettotti, P.; Brusa, R. S. Positronium cooling and emission in vacuum from nanochannels at cryogenic temperature. Phys. Rev. Lett. 2010, 104, 243401 (4pp). (28) Crivelli, P.; Gendotti, U.; Rubbia, A.; Liszkay, L.; Perez, P.; Corbel, C. Measurement of the orthopositronium confinement energy in mesoporous thin films. Phys. Rev. A 2010, 81, 052703. (29) Ferragut, R.; Dupasquier, A.; Calloni, A.; Consolati, G.; Quasso, F.; Petkov, M. P.; Jones, S. M.; Galarneau, A.; Di Renzo, F. Homogeneous porous silica for positronium production in AEgIS. J. Phys.: Conf. Ser. 2011, 262, 012020. (30) Sferlazzo, P.; Berko, S.; Canter, K. F. Experimental support for physisorbed positronium at the surface of quartz. Phys. Rev. B 1985, 32, 6067−6070. (31) Moia, F.; Ferragut, R.; Dupasquier, A.; Giammarchi, M. G.; Ding, C. Q. Thermal production of positronium in porous alumina. Eur. Phys. J. D 2012, 66, 124. (32) Sneh, O.; Cameron, M. A.; George, S. M. Adsorption and desorption kinetics of H2O on a fully hydroxylated SiO2 surface. Surf. Sci. 1996, 364, 61−78. (33) van Veen, A.; Schut, H.; de Vries, J.; Hakvoort, R. A.; Ijpma, M. R. Positron beam for solids and surfaces. In AIP Conf. Proc.; Shultz, P. J., Massoumiand, G. R., Simpson, P. J., Ed.; AIP: New York, 1990; Vol. 218, pp 171−196. (34) Cassidy, D.; Hisakado, T. H.; Meligne, V. E.; Tom, H. W. K.; Mills, A. P., Jr. Delayed emission of cold positronium from mesoporous materials. Phys. Rev. A 2010, 82, 052511 (9pp). (35) Tanaka, H. K. M.; Kurihara, T.; Mills, A. P., (Jr) Positronium time of flight measurements of an open-pored spin-on low-k mesoporous film. J. Phys.: Condens. Matter 2006, 18, 8581−8588. (36) Nagashima, Y.; Kakimoto, M.; Hyodo, T.; Fujiwara, K.; Ichimura, A.; Chang, T.; Deng, J.; Akahane, T.; Chiba, T.; Suzuki, K.; McKee, B. T. A.; Stewart, T. Thermalization of free positronium

ASSOCIATED CONTENT

S Supporting Information *

Swollen MCM-41 (samples A and B) compressed at 7 and 30 MPa, respectively, feature the same nitrogen adsorption isotherm (Figure S1) as the uncompressed swollen MCM-41. Similarly Davicat silica sample compressed at 73 MPa (sample C) feature the same nitrogen adsorption isotherm (Figure S1) as the uncompressed Davicat silica. Porosity characteristic determined by nitrogen adsorption−desorption isotherm as given in Table S1. This material is available free of charge via the Internet at http://pubs.acs.org.

■

AUTHOR INFORMATION

Corresponding Author

*E-mail: [email protected]. Tel.: +39 031 332 7338. Fax +39 031 332 7617. Notes

The authors declare no competing financial interest.

■

REFERENCES

(1) Gidley, D. W.; Peng, H. G.; Vallery, R. S. Positron annihilation as a method to characterize porous materials. Annu. Rev. Mater. Res. 2006, 36, 49−79. (2) Cassidy, D. B.; Mills, A. P., Jr. The production of molecular positronium. Nature 2007, 449, 195−197. (3) Mills, A. P., Jr. In Physics with Many Positrons, Dupasquier, A., Mills, A. P., Jr., Brusa, R. S., Ed.; IOS Press: Amsterdam, 2010; pp 77− 187. (4) Nagashima, Y.; Michishio, K.; Tachibana, T.; Terabe, H. Towards the production of an energy-tunable positronium beam using Ps− photodetachment technique. J. Phys.: Conf. Ser. 2011, 262, 012041. (5) Hughes, R. J. Fundamental symmetry tests with antihydrogen. Nucl. Phys. A 1993, 558, 605−624. (6) Testera, G.; et al. (AEgIS Collaboration) formation of a cold antihydrogen beam in AEGIS for gravity measurements. AIP Conf. Proc. 2008, 1037, 5−15. (7) Ferragut, R.; et al. (AEgIS collaboration) Antihydrogen physics: gravitation and spectroscopy in AEgIS. Can. J. Phys. 2011, 89, 17−24. (8) Charlton, M. Antihydrogen production in collisions of antiprotons with excited states of positronium. Phys. Lett. A 1990, 143, 143−146. (9) Castelli, F.; Boscolo, I.; Cialdi, S.; Giammarchi, M. G.; Comparat, D. Efficient positronium laser excitation for antihydrogen production in a magnetic field. Phys. Rev. A 2008, 78, 052512 (7pp). (10) Consolati, G.; Ferragut, R.; Galarneau, A.; Di Renzo, F.; Quasso, F. Mesoporous materials for antihydrogen production. Chem. Soc. Rev. 2013, 42, 3821−3832. (11) Nagashima, Y.; Morinaka, Y.; Kurihara, T.; Nagai, Y.; Hyodo, T.; Shidara, T.; Nakahara, K. Origins of positronium emitted from SiO2. Phys. Rev. B 1998, 58, 12676−12679. (12) Bisi, O.; Ossicini, L.; Pavesi, L. Porous silicon: a quantum sponge structure for silicon based optoelectronics. Surf. Sci. Rep. 2000, 38, 1−126. (13) Cauvel, A.; Brunel, D.; Di Renzo, F.; Fubini, B.; Garrone, E. Hydrophobic and hydrophilic behavior of micelle-templated mesoporous silica. Langmuir 1997, 13, 2773−2778. (14) Ottaviani, M. F.; Galarneau, A.; Desplantier-Giscard, D.; Di Renzo, F.; Fajula, F. EPR investigations on the formation of micelletemplated silica. Microporous Mesoporous Mater. 2001, 44−45, 1−8. (15) Ottaviani, M. F.; Moscatelli, A.; Desplantier-Giscard, D.; Di Renzo, F.; Kooyman, P. J.; Alonso, B.; Galarneau, A. Synthesis of micelle-templated silicas from cetyltrimethylammonium bromide/ 1,3,5-trimethylbenzene micelles. J. Phys. Chem. B 2004, 108, 12123− 12129. 26708

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709

The Journal of Physical Chemistry C

Article

atoms by collisions with silica-powder grains, aerogel grains, and gas molecule. Phys. Rev. A 1995, 52, 258−265. (37) Mills, A. P., Jr.; Shaw, E. D.; Chichester, R. J.; Zuckerman, D. M. Positronium thermalization in SiO2 powder. Phys. Rev. B 1989, 40, 2045−2052.

26709

dx.doi.org/10.1021/jp410221m | J. Phys. Chem. C 2013, 117, 26703−26709