Preferential Solvation Dynamics in GXLs CH3CN Atoms – Enrichment Factors
DCS
CH3CN
0 .0 0 .5 1 .0 1 .5 2 .0 2 .5 3 .0 3 .5 4 .0 4 .5 5 .0 5 .5 6 .0
1.0
xCO2
08 0.8
0.00 0.46 0.84 0.95 1 00 1.00
0.6 0.4 0.2 0.0 0.1
1
Time / ps
10
Coorrdination N Number
Solvation Respoonse
CO2
4.0 3.0 20 2.0 1.0 0.0 -1.0 -2.0
CH3CN
Total CO2
0 10 20 30 40 • Solvation dynamics in CH3CN+CO2 is biphasic. Time / ps p p
