Preparation of Tertiary Amines by the Leuckart Reaction - Journal of

J. Am. Chem. Soc. , 1950, 72 (2), pp 1037–1038. DOI: 10.1021/ja01158a520. Publication Date: February 1950. ACS Legacy Archive. Cite this:J. Am. Chem...
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1037

NOTES

Feb., 1950

MOLEFRACTION

TABLE I MONOMER I N POLYMER TO MONOMER IN MONOMER MIXTURE

O F FLUORINATED

Vinyl acetate

Chlorotrifluoroethylene Unsymmetrical dichlorodifluoroethy lerie Symmetrical dichlorodifluoroethylene 1,1,2-Trichloro-3,3,3-trifluoropropene 2,3-Dichloro-l,1,1,4,4,4-bexafluorobutene-2 Hexafluoroc yclobutene 1,2-Dichloro-3,3,4,4,5,5-hexafluorocyclopentene

0.73

The chlorotrifluoroethylene-vinyl acetate and methyl methacrylate copolymers were completely soluble in ethyl acetate. The vinyl chloride copolymer was completely soluble in ethylene dichloride. Nearly all of the styrene copolymer was soluble in benzene, but 10% was polymeric chlorotrifluoroethylene, which was insoluble in benzene as well as in the previously mentioned solvents. RESEARCH LABORATORY GENERAL ELECTRIC Co. RECEIVED AUGUST 10, 1949 SCHENECTADY, X. Y .

.82 .60 .54 .55

.11 .I8

Vinyl chloride

0 ..71 .65 .29

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