Principles of geochemistry (Mason, Brian) - Journal of Chemical

Journal of Chemical Education. Oesper. 1967 44 (7), p A611. Abstract | PDF w/ Links | Hi-Res PDF · Introduction to geochemistry (Krauskopf, Konrad). J...
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BOOK REVIEWS in English. To be sure, selections on periodic law, mass action, factors governing equilibrium shift, and catalysis also appear in Leieester and Klickstein's Source Book, hut Farber has made his selections from different papers b y the same authors. He has prefaced each selection with lucid and enjoyable commentary which places it firmly in historical perspective.

that many of the excerpts are too short. Photographs of the authom of each selection would increase the attractiveness of the volume hut undoubtedly also its price as well. Typographical errors are virtually non-existent, and the index is more than adequate for a hook of this length. One admittedly minor feature which I found annoying was the format; in several places it was difficult to distinguish immediately between the editor's comments and the words of the author of the particulat. selection. Among the selections by Dumas, Kirehhoff and Bunsen, Mendeleev, Lecaq de Boisbaudrm, Nilson, Winkler, Rayleigh and Ramsay, Richards, Aston, Bohr and Coster, Berthelat and SainGGilles, Guldberg and Waage, Clausius, Gibbs, Le ChBtelier, Lewis, Nernst, Ostwsld, and Langmuir, the imaginative instructor will find supplementary reading suitable far both general chemistry and advanced

A610 / Journal o f Chemical Education

tion of radioactive disintegrations by MacDonald (1964). The difficult prohlenl of the nature of the Mohorovicic diseoutinuity is handled intelligently in the light oi the recent review of Clark and Ringwood (1964). I n the process of finding room for new material and ideas it was necessary to GEORGEB. K A U F F M ~ N remove some sections which were valuable Ca/(forniaSlale College a2 Fresno in the earlier edition. An example of this is the elimination oi the section entitled E s r t h 3Iodels That Have Been Proposed from Chapter Three. We especially regret the loss of the excellent composite figure in the earlier edition showing fonr theories of the internal structure of the e-artb. This has been Principles of Geochemistry replaced by a single- figure representing the latest ideas only. From the standpoint Brian Mason, US. National Museum, of the teacher the earlier figure was preWashington, D.C. 3rd ed. John ferable since it illustrated the develop \Wey B Sons, Inc., New York, 1066. ment of ideas on the internal stmctnre of vii 329 pp. Figs. and tahles. 16 X the ertrth, whereas the new figure rep23.5 cm. $9.95. resents the present status of the art hIany of us who use Dr. Mason's only. book as a textbook will be grateful to Some sections such as Chapter Four, him for having kept this new third edition Some Thermodynamics and Crystal Chemto the same reasonable size as the earlier ist.ry, are quite similar to the esrlier second edition. This has been aeeomedition. Only one new reference has plished by a judicious selection of new heen added to this chapter, a reference to material and the elimination of nearly the work of Miyashiro (1960) on the free the same amount of old. energies of solid-state reactions and their Thus in a n area in which ideas are significance in the genesis of rocks. Apchanging rapidly, such as that of temperparently no great changes have occurred atures within the earth, the earlier extrapin ibis area in the Inat eight years in Dr. olations of Verhoogen (1956) have been Uason's opinion. Some new work in dropped and replaced by more a recent this general area has been added in other exsminstion of temperatnre variation chapters. For example, the more recent within the ertrth as a resldt n i considemwork of Christie (10.59) on stability I-courses. This attractive, readable volume, t,hen, will not only interest the historian of chemistry but will also be useful as a valuable supplement ior today's texts, most of which unfortunately have little Spare available for the historical dimension of chen~istry.

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hlontreal, where he got the r e d training he needed. On his return to Germany, IIahn was given space in the basement of Emil Fischer's Institut and began the career lations between zaisite and p l a g i o c l s has that constituted his life work. His activireplaced t,he work of Hamsberg (1932) reties were transferred to the Kaiser Wilhelm ferred to in the chaptn. on metamorphism Institut a t Dnhlem (n. slhurh of Berlin) in in the earlier edition. 1912 and after World War I, he relimed The discussion of the composition of t,here until Warkl Wnr I1 brought nhortt its meteorites reflects the current interest destruction hy the Allied bombers. He in composition of rhondrites. The tahle had numerous en-workers bnt the most in the earlier edition on frequency of prominent of these were Lise hIeitner and meteoritic islls showed three classes onl>-, Fritz Strassmann. irons, stony-irons, and atones. I11 the The volume under review is trot very new editiuu thole :are four classes of satisfactory for those who seek to learn the meteorites, irons, ston--irons, achondrites, intimate details of Hahn's long life. and ehondrites. Similarly in the earlier Though of interest to those concerned x-ith edition, the table c r u the composition of the minutiae of his numerous experiments meteoritic mather pave t,he "average on the radioactive elements, their degradacompositiol~ of rneteorit,ic matter," tions, transmutations, etc., and the various whereas in the new rdition, the same table hypotheses and the like, the great hulk of lists the composition of the "average the readers will likely find these details chorrdl.ite" instead. I n this field Dr. somewhat boring. Even the remarkable Mason is most expen nnd we can see that discovery of bhe fission of uranium is not this change in t,ermiaology is much to he dramatized, as it might well have been. .\ preferred. The disrussion of the theory nnmber of Appendixes are devoted tc, that meteorites originated from a distranslations (into English) of some of mpted planet has h e n eliminated, pel; Hahn's papers and R. useful section giver haps significantly. the biographical details concerning some of An addition which will be u s e f d to the main personages who were active in the teachers and students who use this book field of nuclear chemistry. The Introdocas a, textbook ia Appendix IV, Some tion by Glem~Sesborg is a deserved tl.ihute Questions and Problems. from one leader in this field to mrtther. Teachers and s h d e n t s of general Though the publisher states in a Pobchemistry will find this to be a useful lisher's Postscript: "Deeply distressed by sourcehook for material on the chenlical the firat atomic explosions, for which he nature of t,he world a m m d us. felt a personal responsibility, he has hecame a convinced opponent of atomic J. A. SCHI-FLE weaponry," it is unfortunate that Hahn A-rw M a i m Highlands Univn.sity did not include a statement of his sentiI,as 1-egos ments in the .4otobiography. Last hut not least, the translator has done an eseellent jab.

BOOK REVIEWS

Otto Hahn:

A Scientific Autobiography

Otto Hahn, GMtingen, West Germany. T~.anslated and edited by W i l l y Ley. Int~.oduct~iouby Glenn T. Seaborg. Charles Scrihner's Sons, New York, 1066. rxiv 296 pp. Photographs. 15 X 23.5 cm. $7.95,

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Otto Hahn was horn in 1879 and this autobiography appewed in German in 1962, i.e., when he was well over eighty. The Nobel Prize in rhpmistry was awarded to Hahn for the year 1944 and in 1066 along with Meitner and Strasamam he shared the Enrica Fermi Award. Ile sw "visiting professor" st Cornell in 193::. He was deported hy the United States and British forces in 194: and interned near Cambridge, England. After the war he returned to West Germany and served as president of the Max Planck Society from I948 to his retirement in 1960. Ni~mernns honors have been bestowed on him and he is sometimes called "the father of nnrlenr chemistry." Hahn was trained in organic chemistr>and then sent to England by a dyestuff m&n!~facturerto learn English. He %-a. given permission to work in Ramsay's labarittory and the latter suggested that he do some work with radium compound-, even though Hahn knew nothing of thi. field. He became a. convert and decided to go to Canada to work with Rotherford at

RALPHX.OE~PER University 0.1 Cincinnati Cincinnnli. Ohio

Gmelins Handbuch der Anorganirchen Chemie. 8. Auflage, System Nummer 57, Nickel. Teil B, Lieferung 3, Schluss der Verbindungen

Edited by E . H. E. Pielsch and the Gmelin Institute. Verlag Chemie., GMBH, WeinheimlBergslrasse, 1966. xxxvii f 4 i 8 pp. Figs. and tables. 17.5 X 25.5 cm. $111. Compounds of nickel and boron thmugh nickel and manganese (by the Gmelin system) are covered in this volume. Literature evaluation is complete through 1984, and some subjects are covered through 1965. This volume hriugs together ior the first time the data, on nickel double d t s and related systems. Recent studies on the Ni-B, N-C, Xi-P, and Ni-As systems are carefully evaluated and citations are given to establish the existance of Ni(1V). Several other volumen on nickel are projected For puhlicstion in 196i.

JANETB. Yhx DOREK College of Wooaler TFooater, Ohio

Volume 44, Number

7, July 1967

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