Prof. Clemens Burda, Chemistry, Case Western Reserve

380 oC Annealing Electrical conductivity / (S /c m) 50 100 150 200 250 300 10 100 1000 ... Temperature / K Electrical Co nd uctivity / (S /c m) ...
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1000

1000

o

350 C Annealing

100 o

300 C Annealing

Vacuum Dry

10

50

Seebeck / (V/K)

100 150 200 Temperature / K

-100

250

o

400 C Annealing

Bi0.5Sb1.5Te3 NCs o

380 C Annealing

100 350 oC Annealing 300 oC Annealing

Vacuum Dry

10

300

50

350

o

380 C Annealing o 350 C Annealing o 300 C Annealing Vacuum Dry

-120

Tunable plasmonic absorption spectra of Cu2-xS nanocrystals prepared from a sonoelectrochemical approach.

Electrical Conductivity / (S/cm)

Bi2Te3 NCs

Bi2Te3 NCs

-80 -60 -40

100 150 200 Temperature / K

250

300

o

400 C Annealing o 380 C Annealing o 350 C Annealing o 300 C Annealing Vacuum Dry

300

Seebeck / (V/K)

Electrical conductivity / (S/cm)

o

380 C Annealing

250

Bi0.5Sb1.5Te3 NCs

200 150 100

-20

50 0

50

100

150

200

250

0

300

50

Temperature / K

6

6

1.0x10

5

5.0x10

100

150

200

Temperature / K

250

400 C Annealing o 380 C Annealing o 350 C Annealing o 300 C Annealing Vacuum Dry

7

1.5x10

1.5x10

50

High quality tertiary thermoelectric nanocrystals prepared by a wet chemistry approach.

Bi2Te3 NCs Power Factor / (S V2 cm-1 K-2 )

Power Factor / (S V2 cm-1 K-2 )

6

2.0x10

150

200

Temperature / K

250

300

o

o

380 C Annealing o 350 C Annealing o 300 C Annealing Vacuum Dry

6

2.5x10

100

300

Bi0.5Sb1.5Te3 NCs

7

1.0x10

6

5.0x10

0.0 50

100

150

200

250

300

Temperature / K

Effect of annealing temperature on the transport properties of thermoelectric nanocrystals.

Prof. Clemens Burda, Chemistry, Case Western Reserve University