PUBLICATION O F F I C E : Easton, P a . EDITORIAL OFFICE:
Industrial
NEWS EDITION
VOL.
12, No. 16
AUGUST
20, 1934
AND ENGINEERING
G h emi str y VOL. 26,
CONSECUTIVE
NO. 28
PUBLISHED BY THE AMERICAN CHEMICAL SOCIETY HARBISON E . H O W E , EDITOR
Room 706, Mills Building, Washington* D. C. ADVERTISING DEPARTMENT:
332 West 42nd St., New York, N. Y . TELEPHONE: Bryant 9-4430 SUBSCRIPTION to nonmembers, Industrial and Engineering* Chemistry, $7.50 per year. Foreign postage $2.10, except t o countries a c cepting mail a t American domestic rates, and to Canada, $0.70. Analytical Edition only, $2.00 per year; foreign postage $0.30, Canada, $0.10. News Edition only, $1.50 address, and claims for lost copies should be referred to Charles L . Parsons, Secretary, Mills Building, Washington, D . C.
Program of the Cleveland Meeting of the American Chemical Society September 10 to 14, 1934 (Eastern Standard Time) 6:30 P . M.—Group Dinners. 8:30 P . M.—Ctomplirnentary Smoker and Entertainment, Ballroom, Hotel Cleveland. Music, floor show, original sketches b y local section, refreshments, and dancing. Only those wearing badges will be admitted. The ladies are invited.
GENERAL PROGRAM SUNDAY, SEPTEMBER 9 4 : 0 0 to 9:00 p. M.—Registration, Mezzanine Floor, Hotel Cleveland. M O N D A Y , SEPTEMBER 10 8 : 0 0 A. M.—Registration, Mezzanine Floor, Hotel Cleveland. 9 : 3 0 A. M.—Council Meeting, Rose Room, Hotel Cleveland. 2 : 0 0 p. M.—General Meeting, Banquet Room, Hotel Cleveland. Four general papers: J. R. Katz, Scheikundig Laboratorium, University of Amsterdam. "X-Ray Spectrography of Swelling." Robert £ . Swain, Stanford University, Calif. "Chemistry during the Depression." N . K. Chaney, V. C. Hamister, and S. W. Glass, National Carbon Co., Inc. "Constants of Carbon at Arc Temperatures." J. C. Hostetter, Corning Glass Works. "The Technic of Making Large Telescope Mirrors." 7 : 0 0 P.M.—Subscription Dinner, informal, for members and guests, $2.50. Music. Ballroom, Hotel Cleveland. Tickets must be purchased in advance at time of registration. After dinner, in the same room, a t approximately the time stated will follow: 8:30 P. M. President's Address, Charles L. R e e s e . "Scientific Idealism." 9 : 0 0 p. M.—AMERICAN C H E M I C A L SOCIETY Award in Pure Chemistry (initiated b y A. C. Langmuir) t o C. Frederick Koelsch. Dr. Koelsch's address will be delivered before the Division of Organic Chemistry. 9 : 3 0 P . M.—Dancing and Cards. 7:30 8:00 9:00 12:30 2:00
WEDNESDAY, SEPTEMBER 1 2 7:30 A . M.—Group Breakfasts. 8 : 0 0 A.M.—Registration, Mezzanine Floor, Hotel Cleveland. 9:00 A . M.—Divisional Meetings, continued. 12:30 P . M.—Group Luncheons. 2:00 P . M.—Divisional Meetings, continued. 6:30 P . M.—Group Dinners. 8:00 P . M.—Concert, Music Hall, Cleveland Public Auditorium. T h e Orpheus M a l e Chorus, Charles D a w e , Conductor. Cleveland Symphonic Ensemble, Walter Logan, Director. Walter Blodgett, Organist. T h e Orpheus Male Chorus, comprising 65 voices, has e s tablished a national reputation and has won highest honors in this country and in Europe. T h e Cleveland Symphonic Ensemble comprises 20 selected players from t h e Cleveland Symphony Orchestra. Complimentary. Admission by ticket issued a t time of registration. Seats are n o t reserved. THURSDAY, SEPTEMBER 13 8:00 A . M.—Registration, Mezzanine Floor, H o t e l Cleveland. 9:00 A . M.—Divisional Meetings, continued. 1:00 P . M. to 5:15 p. M . — P L A N T INSPECTION T R I P S . T w o trips m a y be selected, one o n Thursday a n d one o n Friday. Transportation free except for Trip 1 3 , Akron Day, for which a charge of $1.50 t o cover cost will be made. All trips will leave promptly from the Public Square entrance of Hotel Cleveland. Registration for any trip must be made in advance at the desk designated "Plant InspedionTrips" before 5:00 P. M . , Wednesday, in order that suitable transportation m a y be p r o vided. M o s t of these trips have a definite limitation o n the number which can b e accommodated. I n such cases, registrations will be accepted i n the order in -which they are
TUESDAY, SEPTEMBER 11 A. M.—Group Breakfasts. A. M.—Registration, Mezzanine Floor, Hotel Cleveland. A. M.—Divisional Meetings, Hotel Cleveland. p. M.—Group Luncheons. p. M.—Divisional Meetings, continued.
289
290
NEWS received, a n d registration must b e refused when the respective quotas are reached. Tickets will b e issued t o each registrant a s evidence of reservation. TRIP
1—NATIONAL
AUDITING: H . P. Corson. ENTERTAINMENT: C. G . Schluederberg.
E X H I B I T S : H . S. Booth, Western Reserve University. G O L F : W . J . Harshaw. GROUP D I N N E R S AND LUNCHEONS:
CARBON C O .
Limited t o 250. T h e manufacture of a wide variety of flash lights and dry cells. TRIP
2—THE
FERRO
ENAMEL C O .
T R I P 5 — B A L D W I N FILTRATION P L A N T .
RAYON
CORP.
TRIP 7—OTIS STEEL CO.
Limited t o
20. T h e manufacture of by-produ c t coke, steel, open-hearth furnaces,
Mrs. E .
ENTERTAINMENT:
W.
SECTION:
P L A N T I N S P E C T I O N : C. F . Prutton. P R I N T I N G : H . D . Heiser. P U B L I C I T Y : H . N . Holmes. R E G I S T R A T I O N : M . J. Rentschler. SOCIAL ACTTVITIES: O. F . Tower. TRANSPORTATION: H. P . Corson.
PLANT. Limited t o 30. Cleveland's n e w activated sludge process disposal plant i n process of construction.
6—INDUSTRIAL
LADIES
W . R. Veazey.
Limited
Limited t o 30. T h e manufacture of rayon b y t h e viscose process.
R o o m 1604,
1
CHAIRMAN O P C L E V E L A N D
T R I P 4—EASTERLY SEWAGE DISPOSAL
TRIP
HOTELS: L . C. Drefahl, Terminal Tower.
Furst, Chairman; Miss Marion Cleaveland, Executive Vice Chairman; Mrs. W . A. Harshaw, Vice Chairman.
t o 250. The manufacture of paints, varnishes, and lacquers.
Cleveland's east side water nitration plant employing alum coagulation, chlorination. and mechanical nitration. T h e third largest mechanical t y p e nitration plant in this country, containing t h e l a r g e s t c o v e r e d reservoir in t h e world. Capacity, 165,000,000 gallons per day.
A. C .
Zachlin, Willard Storage Battery Co. LANTERNS: L. M . H u n t . F I N A N C E : L . C. Drefahl.
Limited t o 100. The largest m a n u facturer of porcelain enamel i n this country. Products are used for application t o cast iron and steel products, such as ranges, refrigerators, signs, and cooking utensils. Unusual physical testing equipment. TRIP 3 — T H E GLIDDEN C O .
Vol. 12, N o . 16
E D I T I O N
ALNNOUNCEMENTS
PLACES OF MEETING.
Meetings will be
held in t h e Hotel Cleveland and in t h e adjoining Higbee Building. REGISTRATION A N D REGISTRATION F E B .
T h e registration bureau of t h e convention will open at 4 p. M . , Sunday afternoon, o n the mezzanine floor of t h e Hotel Cleveland. T h e convention registration fee, required The Cleveland Convention
BERT J. H U P P . Small-Scale Studies for t h e Simultaneous Removal of Organic Sulfur and Hydrogen Sulfide from H o t Fuel Gases.
August 20, 1934 11:40—32.
INDUSTRIAL
BERNARD P. MULCAHY.
A N D E N G I N E E R I N G
Gas Analysis.
The A p -
CHEMISTRY
DIVISION OF MEDICINAL CHEMISTRY
plication of Exact Analysis t o Industrial Problems.
P A U L NICHOLAS LEECH,
JOHN H . WALDO, Secretary;
DIVISION OF HISTORY OF CHEMISTRY FRANK BURNETT DAINS,
T E N N E Y L . D A V I S , Secretary;
Chairman
E . D . B U R K E , Local
BOATNER
A N D CLARA
DB MILT.
Certain Unpublished Letters of Lavoisier, Lagrange, and Others to Lakanal. 9:15—2. NORMAN J . HAHRAR. Sulfur from Popocatepetl. 9:36—3.
J O S E P H S A M U E L H E P B U R N A N D ROWLAND RICKETTS.
Treasures i n t h e Library of t h e Hahnemann Medical College of Philadelphia. 9:46-—4. ALBERT P . S T . "AJtkumistica," a Poem b y J o hanne Clajo. 10:00—5.
M A R Y ELVIRA W E E K S .
T h e Scientific Contributions
of D o n Andres Manuel del Rio. 10:15—6.
FRANK
BURNETT
DAINS.
Francis
Galton's
Im-
pressions of Ldebig's Laboratory in 1840. 10:30—7. T E N N E Y L . DAVIS. Primitive Science, the Background of Early Chemistry and Alchemy. 11:00—Business Meeting. DIVISION OP INDUSTRIAL AND ENGINEERING CHEMISTRY W. G. WHITMAN,
E. M . BILLINGS, Secretary;
Chairman
L. R. WESTBROOK, Local
Assistant
R o o m C , 7 t h Floor, Higbee Building WEDNESDAY MORNING SYMPOSIUM ON D I F P U S I O N A L PROCESSES, W .
9: 0 0 — 1. H E R B E R T C. HAMILTON AND DWIGHT J O S L Y N . The Germicidal Effectiveness of Mixed Substances. 9: 2 0 — 2. THEODORE E . FREBDEMANN. Some Chemical and Physiological Properties of Kojic Acid. 9: 4 0 — 3. E M I L BOGEN AND R U S S E L L N . LOOMIS. Comparative Carcinogenic Effects of Common Agents. 9: 5 5 — 4. F. R. GREENBAUM. Calcium Levulinate arid Calcium Levugluconate. N e w Organic Calcium Compounds for Intravenous and Intramuscular Calcium Medication. 10: 1 0 — 5. WALTER H. HARTXJNG. Propiophenone i n IatroChemistry. 10: 3 0 — 6 . C. M. MARBERG. The Granulocytopoietic Fraction of Yellow Bone Marrow. I . 10: 4 5 — 7. C. A. ELVEHJEM. The Effect of Iron and Copper Therapy on the Hemoglobin Content of t h e Blood of Infants. 11: 0 0 — 8. M . X . SULLIVAN. A Colorimetric Test for Free Guanidine. 11: ; 15*— 9. M. X . SULLIVAN, W . C. H E S S , AND F . IRREVERRE. Studies in Muscular Dystrophies. The Presence of Simple Guanidine Derivatives in t h e Urine. (Motion Pictures.) 11: :30—10. W. C. H E S S . Naphthalene Sulfone Guanidine. 11: :40—11. D . L. TABERN AND E . H . VOLWTLER. Some Alkyl and Aryl Ureides and Amides as Hypnotics.
2 :00—12.
2 :40—14.
H.
:05—15.
Diffusion
of Vapors through Gas Films. 10:20—3. L A U R E N B . HITCHCOCK. Effect of Concentration and Viscosity of Caustic Solutions upon Rate of Absorption of Carbon Dioxide. 11:05—4. A L L E N S. SMITH. T h e Kate of Mixing of Gases in Closed Containers.
:35—17.
:55—18.
3:30—7.
M. I t . F E N S K E , C. O. TONGBERG, AND D . QUIGGLB.
A. P . COLBURN AND O. A . H O U G E N .
A Method for
4:05—8.
A. P . COLBURN AND T . H. CHILTON.
T h e Prediction
K A R L BIMBACH A N D T. H . R I D E R .
T h e Volumetric
:25—20. ARTHUR D . HOLMES, M A D E L I N E G. PIGOTT, W M . A L F R E D SAWYER, AND LAURA COMSTOCK. T h e Value of
Moisture
the Design of Cooler-Condensers for Mixtures of Vapors and Inert Gases.
C. N . M Y E R S . FLORENCE GUSTAFSON, A N D BINFORD
Determination of Halides Using Dichlorofluorescein as a n Adsorption Indicator.
PackingMaterial for Fractionating Columns. Movement b y Capillarity i n the Drying of Granular Materials.
C. N . M Y E R S , FLORENCE GTTSTAFSON, A N D BINFORD
THRONE. The Distribution and Diagnostic Significance of Lead i n the Human Body. : 10—19.
E . W . COMINGS A N D T . I t . SHERWOOD.
Effect of
THRONE. Uniform Composition of Serums, Vaccines, and Thyroid Preparations as Measured b y Nitrogen Content.
WEDNESDAY AFTERNOON
2:45—6.
Cinchona Alkaloids in Pneumonia.
ROBERT L. J O N E S AND C. W . GEITER.
Repeated Insulin Injections on the Normal Blood Sugar and Hypoglycemic Response of Rabbits. 20—16. A. RICHARD BLISS, JR. The Absorption of Certain Drugs through t h e Human Skin.
9:00—1. C. C . MONRAD. Applications of the Film Concept in t h e Petroleum-Refining Industry.
2:00—5.
C. L. BUTLER, A L I C E G. R E N F R E W , A N D LEONARD
H. CRETCHER.
MCADAMS,
T. K . SHERWOOD AND E . I t . GILLTLAND.
R. R. R E A D , G. F . REDDISH, A N D E. M . B U R L I N -
GAME. Branch Chain Alkyl Chlororesorcinols. 2 :25—13. RANDOLPH T . MAJOR. 0-Alkylcholines a n d Their Acetyl Esters.
Chairman
9:35—2.
Assistant
TUESDAY MORNING AND AFTERNOON 1
Assistant
TUESDAY M O R N I N G CHARLOTTE H .
Chairman-
C . D . VELLAIRB, Local
Parlors 2 6 to 30
Assembly Boom B 9:00—1.
295
Cod Liver Oil for Building Bodily Resistance of Industrial Workers. 4:40—21. C. G. MACARTHTJR. Chemical Analysis of the Central Nervous System of an Idiot. Business Meeting.
of Mass Transfer (Absorption) Coefficients from D a t a on Heat Transfer and Fluid Friction.
WEDNESDAY MORNING SYMPOSIUM ON MEDICINAL ANALYSIS
THURSDAY M O R N I N G
9:00—22.
GENERAL PAPERS 9 : 0 0 — 9.
C Y R I L S. KIMBALL, H A R R Y J. HOSKING, AND FOSTER
D . SNELL. Persulfate as a Soap Bleach. 9:30—10. CHARLES ALLEN THOMAS. Chemicals Derived from Pentanes. 10:10—11.
C L Y D E Q. SHEELY AND W . H. K I N G .
The Produc-
tion of a Mixture of Aldehydes and Acids Containing from Eight to T e n Carbon Atoms. 10:30—12.
HENRY
H.
BLAU
AND ALEXANDER
SILVERMAN.
The Liberation of Fluorine in t h e Manufacture of Fluoride 10:50—13.
L . A . LOGAN, N . F R A G E N , A N D W. L. BADGER.
Liquid Film Heat-Transfer Coefficients in a Vertical Tube Forced-Circulation Evaporator. 11:10—14.
F R A N K T. B A R R A N D D . B . K E Y E S .
11:45—16.
E . O. HUFFMAN AND F. K . CAMERON.
10:45"—29.
Recovery of
the Values i n Alunite b y Fusion with Certain Alkali R e -
R. NORRIS SHREVE.
(a) U s e of Microscope t o
Save Laborious Moisture Deterniinatioiis. (b) Testing Medicinal Dyes in Groups Chemically and Bacteriologically.
Equilibria in
the Chemical System: Hydrogen Sulfide, Propylene, Isopropyl Mercaptan, and A7-Propyi Mercaptan. 11:30—15. E . P . SCHOCH. T h e Extraction of Potassium Salts from Polyhalite o r from Aqueous Mixtures in Which Calcium Sulfate is Synthesized.
GEORGE D . B E A L AND C H E S T E R R. SZALKOWSKI.
Iodometric Assay of Methylene Blue. 9:15—23. H . V. FARR. Significance of Some Impurities i n Anesthetic Ether. 9:30—24. EDWARD J. HUGHES. Assay of Organic Medicinal Preparations Containing Arsenic. 9:45—25. PAUL NICHOLAS LEECH. Some Simple Short-Cuts in Analysis of Unknown Medicinals. 10:00—26. C. O. MILLER. Analytic Method for Determining Scurvy Based on Cevitamic Acid (Ascorbic Acid). 10:15—27. T . H. R I D E R AND L. D . SEIP. Air-Lift Extractor Applied to the Analysis of Alkaloidal Drug Extracts. 10:30—28. JOSEPH ROSIN. Determination of Halogens i n Organic Medicinals.
11:00—30.
E . H. VOLWILER AND D . L. TABERN.
Volumetric
Determination of Barbituric Acids. 11:15—31. DAVID KLEIN. Inaccuracies of Official Assays. 1
Five minutes allowed for discussion of each paper.
Enzyme
296
NEWS DIVISION OF ORGANIC C L A U D E S. H U D S O N ,
A R T H U R J. HILL, Secretary;
: DITION 3:45—30.
CHEMISTRY Chairman
J. V. VAUGHEN, Local
Assistant
TUESDAY MORNING
Banquet Boom 9:00—Joint Symposium on The Mutual Problems in Physical and Organic Cnemistry with the Division of Physical Chemistry (see page 297). Empire Room
Vol. 12, N o . 16 ROBERT C. ELDBRFIELD- AND WALTER A. JACOBS.
The Dehydrogenation of Strophanthidin with Selenium. 4:00—31. ft. L. MASON. Methyl-o-Hydroxj phenylcarbinol and Some of Its Derivatives. 4:15—32. ROGER W. STOUGHTON. T h e Fries Reaction with Naphthol Esters. 4:30—33.
JOSEPH B. NEBDIRL. A N D RICHARD A. SMITH.
4:45—34.
JOSEPH B. NIEDERL. A N D WILLIAM F. H A R T .
THURSDAY M O R N I N G
2:00—1.
C. FREDERICK KOELSCH.
2 : 3 0 — 2.
E. L. W I T T L E , G. H . FLEMING, AND F . C. WHTTMORE.
3 : 0 0 — 4.
A Cyclic ans-Chlorohy-
drins of Cyclohexene. 10:00—Business Meeting. 10:30—16.
G. BRYANT BACHMAN AND ARTHUR J. H I L L .
The
Chemistry of t h e Acetylenes. I. The Preparation of 1Heptyne by Dehalogenation Methods. 10:45—17. IRVING E . MUSKAT. Reactions of Carbohydrates i n Liquid Ammonia. 11:00—18. IRVING E . MUSKAT. The Mechanism of Walden Inversion in Sugars. T h e Inversion of the p-Toluenesulfonyl Esters of Rhamnose. 11:15—19.
K. G. BUSCH, J. W . CLARK, L . B. G B N U N G , E . F .
SCHROEDER, A N D W. L. EVANS.
The Oxidation of Certain
Sugars with Silver Oxide in the Presence of Potassium Hydroxide. 11:30—20.
D O N A L D R. S W A N AND W. L. E V A N S .
Preparation
o f a-Methyl i-Arabinomethyloside. 11:45—21.
E R N E S T L. JACKSON AND C L A U D E S. H U D S O N .
tain Derivatives of i-a-Rhamnohexonic Acid. Synthesis of Z-a-Rhamnohexonic Lactone. 12:00-—22.
ROBERT
C. HOCKETT.
Cer-
An Improved
The Degradation of
d-
X y l o s e by the Method of Wohl. 2:00—23.
GEORGE E . F E L T O N WITH W E R N E R FREUDENBERG.
T h e Preparation of MErythrose and of T w o Derivatives, Methyl-Z-Erythroside and Monoacetone-Methyl-^Erythroside. 2:15—24.
H. G. LINDWALL AND R. N . D U P U I S .
Dihyd>*o-
quinolines from Phenacyloxindoles. 2:30—25.
R. F .
DUNBROOK
9:15—36.
AND M. H . ZIMMERMANN.
9:30—37.
3:00—27.
EMIL
R.
On the Synthesis of 5,5-AlkylphenylbarREEGEL
AND MELLICENT
HATHAWAY.
T h e Constitution of the Condensation Product of Furfural and Aniline (Scruff's Base). 3:15—28.
L. G. S. BROOKER AND F . L. WHITE.
HSIEH, AND W.
B.
Fox.
SAMUEL L. SILVER A N D A L E X A N D E R LOWY.
Friedel-
FRANK J. SOWA, PAUL A . SAJRTORBTTO, AND J U L I U S
A. NIEUWLAND. T h e Reaction of Sodium i n Liquid Ammonia on Diphenyl Ether and I t s [Derivatives. 9:45—38.
HARRY
F.
MILLER A N D G .
BRYANT
The Higher Benzenoid Hydrocarbons. Aid of Metallo Derivatives. 10:00—39.
BACHMAN.
Synthesis with the
GEORGE H . COLEMAN A N D R O B E R T A. FORRESTER.
Possible Rearrangement Reactions of Monochloroamine and Certain Grignard Reagents. 10:15—40.
L E E IRVIN SMITH A N D J O S E P H H. P A D E N .
on t h e Polymethylbenzenes. matic Diazo Compounds. 10:30—41.
10:45—42.
X.
Reaction
Studies
with
L E E IRVIN SMITH A N D P L I N Y O. T A W N B Y .
on the Polymethylbenzenes. acetate t o Durene.
Aro-
Studies
I X . Addition of Ethyl Diazo-
G. E . P. SMITH, J R . , A N D F. W. BBRGSTROM.
The
Preparation and Reactions o f Some Ammono Ketones. 11:15—43.
L. CHAS. RAIFORD ANI> J O H N E. MILBERY.
Bro-
mination of Certain Acyl Derivatives of Phenolic Compounds.
R O B E R T J. MOORE,
Studies in
t h e Cyanine Dyes. I. A New Method of Preparing Certain Carbocyanine Dyes. 3 : 3 0 — 2 9 . WILLIAM A. N O Y E S . The Reintegration of Science.
Chairman
R O Y H . K I E N L E , Secretary; W . ALEXANDER, Local Room F, 7 t h Floor, Higbee Building
Assistant
WEDNESDAY; MORNENG A N D A F T E R N O O N
9:10— 1. E . C. HOI/TON. N o t e on an Attempt t o Grow SafBower in Ohio. 9:30— 2. C. H. ALLEN. Recent Developments in Natural Gum Varnish Cooking. 10:00— 3 .
P. MARLING AND C . A . HOCHWAI/T.
Effect of H y -
dration of Nitrocellulose oa Orange Peel of Sprayed Lacquer Films. 1 0 : 4 0 — 4.
H. A. BRTJSON AND O T T O S T E I N .
Synthesis of N e w
Organic Acids Giving Oil-Soluble Metallic Salts. Relationship between Structure and Solubility. 11:20— 5. A. C. E L M . Fundamental Studies of Paints. I. Paint Durability a s Affected b y the Colloidal Properties of the Liquid Paint. 2 : 0 0 — 6. • L. T . W O R K , S. B . TXJWINBR, A N D A. J. GLOSTER.
Some Significant Factors in t h e Properties of Titanium Pigments. I. Properties of t h e Solution. 2:30— 7. L. T . WORK AND S. B. TUWINER. Some Significant Factors in the Properties o f Titanium Pigments. I I . * Effect of Precipitation, Calcination, a n d Subsequent Treatment upon Titanium Oxide Pigments. 3:00— 8. J. F. BROEKER. Some Characteristics of Zinc Sulfide and Comparison with Some Other White Pigments in Outside House Paints, 3:40— 9. F . L. BROWNE. T h e Painting Characteristics of Hard Wood. 4:10—10. F . L. BROWNE. Priming Procedures in Painting Soft Wood. 4:35—11. H. A. GARDNER. Primers f o r Wood.
A
J. S. CHAMBERLAIN, J. J, C H A P , J. E . D O Y L E , A N D
L . B. SPAULDING. bituric Acids.
Y.
Crafts Type Reactions on Biphenyl.
THURSDAY M O R N I N G
Method for the Preparation of 2-Mercaptobenzothiazole. 2:45—26.
R. C. H U S T O N , T.
Condensation of Aliphatic Alcohols with Aromatic Compounds in the Presence of Aluminum Chloride.
GEBAUER-FULNEGG.
T h e Action of Liquefied Hydrogen Chloride o n Aldehydes. 9:45—15.
9:00—35.
DIVISION OF PAINT ANI> VARNISH CHEMISTRY
WEDNESDAY M O R N I N G AND AFTERNOON 9:00—12.
The
Synthesis of Phenolic Long-Chain Alcohols. The Preparation of Hydroxyphenyl and Hydroxyalkylphenylstearyl • Alcohols.
T U E S D A Y AFTERNOON
NTeopentyl Halides. 2 : 4 5 — 3. G. ALBERT H I L L . Ivy.
The
Abnormal C-Alkylatiqn of Phenols with Tertiary Alkyl Halides.
9:00—12. • J. D . EDWARDS A N D B O B E R T
L,
WRAT.
Accel-
erated Tests of Paint Finishes o n Aluminum. 9:40—13. J. K. H U N T AND W . ID. LANSING. Physical Properties and Durability of Coating Composition Films. 10:20—14. H. A. NELSON. Inhibiting Qualities of Metal Priming Paints and the Influence o f the Reactions within the Paint Film. 11:00—15.
J. W. I L I F P AND J O H N MARSHALL,.
House Paints.
Effect of Climate. Wood Types, and Priming Practice. 11:40—16. R. H. SAWYER. T h e Use of Incomplete Hiding
August 20, 1934
I N D U S T R I A L
A N D E N G I N E E R I N G
for Measuring the Hiding Power Value of White Paints a n d Pigments. 12:20—Business Meeting.
2 : 1 5 — 7.
F. W. SULLIVAN, J R . ,
2 : 4 0 — 9.
2:50—10.
W H I T E A N D F.
W.
3:05—11.
ROSE,
JR.
The
Isolation of a Nonanaphthene from an Oklahoma Petroleum. 9 : 3 0 — 2. R. T . LESLIE. T h e Critical Solution Temperatures of Some Hydrocarbons in Sulfur Dioxide. 10:00— 3.
WHEELER
T . A. B O Y D . 10:45— 4.
G.
L O V E L L , J O H N M . CAMPBELL, A N D
Knocking Characteristics of Hydrocarbons.
C. G. D R Y E R , J. C . M O R R E L L , GTJSTAV EGLOFF, A N D
C . D . LOWRY, J R . Inhibitors in Cracked Gasoline. H I . Storage Stability a s Belated to Induction Period and Critical Oxidation Potential. 1 1 : 1 5 — 5.
GTJSTAV E G L O F F , J. C. M O R R E L L , W. L . B E N E D I C T ,
AND CHARLES WIRTH, I I I .
T h e Effect of Alkyldlsulfides
on the Color Stability of Gasolines. 2 : 0 0 — 6.
The Deterio-
ration of Absorption Oils i n Service. 2 : 4 0 — 7.
OGDEN
FITZSIMONS
AND E.
W.
TBTELE.
The
Molecular Weight of Cracked Distillates. 3 : 1 0 — 8.
W . B . M C C L U E R AND M . R . F B N S K E .
A Method
for Evaluating the Viscosity Temperature Characteristics of Oils. 3 : 4 0 — 9. L. P. GAUCHER. The Specific Heat of Liquid Pure Hydrocarbons and Petroleum Fractions. WEDNESDAY MORNING 9:00—10.
L.
H.
AND CHARLES
WIRTH,
III.
3:30—13.
AND S A M U E L
GREENBANK AND GEORGE E.
3:40—14.
I.
Chairman
J . W. WILLIAMS,
P . J. G T G I A N D W. H . C H A P I N , Local
Secretary
Assistants
TUESDAY MORNING
Banquet Room
Joint Symposium w i t h Division o f Organic Chemistry. 9 : 0 0 — 1. HOMER ADKJNS. T h e Chemical Reactivity of t h e Simple Alkyl Groups. 9 : 3 0 — 2 . FARRINGTON D A N I E L S . T h e Absorption of R a d i a tion and I t s Interpretation. 1 0 : 0 0 — 3 . M . S. KHARASCH. T h e Collaboration of Physical and Organic Chemists. 10:30— 4 . M A U R I C E L . H U G G I N S . Interatomic Distances in Organic Compounds. 1 1 : 0 0 — 5. GEORGE S. PARKS. T h e Application of Thermodynamics t o Organic Chemistry. 11:30—Discussion.
Banquet R o o m Presiding
Joint Symposium o n T h e Inorganic Chemistry of Water Supply with t h e Division of Water, Sewage, a n a Sanitation Chemistry (see page 299).
4:45—19.
G L E N N D O O L E Y , L O U I S WALDBAUER, AND ARNOLD
J.
L.
SHERESHEFSKY
AND CHARLES
SECTION B
Parlors 34 t o 36 J. W . WILLIAMS,
of Ethyl Iodide.
B.
WEIR.
A . R . C H O P P I N AND L. C . FATJLKENBERRY.
Con-
ductance as a Function of Viscosity and Dielectric Constant. I. Conductance of KC1 in Methyl Alcohol-Water Solutions. 4:55—20.
J.
ANDREWS. tures.
E.
AHLBERG,
W.
0.
LUNDBERG,
AND D.
H.
A Calorimeter for Liquid Helium TemperaWEDNESDAY MORNING SECTION A
Banquet Room SYMPOSIUM O N INDICATORS
Presiding
9 : 0 0 — 2 1 . C . J. BROCKMAN. Introduction t o t h e Symposium. 9:10—22. M A R T I N KILPATRICK. T h e Colorimetric D e t e r mination of Hydrogen-Ion Concentration in Aqueous Solution. 9:40—23. W. F . K . W Y N N E - J O N E S . Indicators i n N o n Aqueous Solution. 10:05—24. LOUTS P . HAMMETT. Acid Catalysis and Indicator Acidity. G.
H.
WALMN
A N D SYLVAN
EDMONDS.
New
Indicators for Oxidimetry. 11:05—26. I . M . KOLTHOFF. Adsorption Indicators. 11:25—27. CHARLES ROSENBLUM. Radioactive Indicators i n Analytical Chemistry. 11:55—28.
G. F R E D E R I C K SMITH A N D C. A . G E T S .
Improved
Synthesis of o-Phenanthroline. WEDNESDAY MORNING SECTION B
Parlors 3 4 to 3 6 D. H. ANDREWS, 9:00^—29.
Presiding
J. C . W A R N E R A N D E A R L L . WARRICK.
Kinetic
Presiding T h e Photochemistry
T H O M A S K. A L E X A N D E R A N D A L B E R T C. B O U C E K .
T h e Mechanism of t h e Arsenite-Tellurate Reaction. 9 : 3 0 — 3 1 . A L L E N S. SMITH. Heat Dissipation in Gases. I . T h e Effect of an Electrical Field in Helium, Oxygen, and Ammonia. 9 : 4 5 — 3 2 . A L L E N S . SMITH. Heat Dissipation in Gases. I I . A Theory of the Effect of a n Electric Field. 10:00—33.
C E C I L V. K I N G A N D S. S. B R O U D Y .
T h e R a t e of
Solution of Benzoic Acid in Dilute Aqueous Alkali. 10:15—34.
T U E S D A Y AFTERNOON
W . W E S T A N D E L I GINSBERG.
Crystal
Adsorption of Oxygen i n a System of Constant Surface and: Variable Capillary Content. 4:30—18. P A U L V. M C K I N N E Y . T h e Reduction of Platinum Oxide b y Carbon Monoxide and t h e Reaction of Carbon Monoxide with Oxygen over Platinum Oxide and Platimim.
9:15—30.
SECTION A
2 : 0 0 — 6.
HOLM.
Systems t o
Medium Effects i n Reactions between Ions of Unlike Sign.
T U E S D A Y AFTERNOON
H A R R Y B. J O R D A N ,
Reduction
P . HOELSCHER. S o m e Properties of Cobalt-Manganese Alloys. 3:50—15. THOMAS A. W I L S O N . T h e Complete Crystal Structure of a-Manganese. 4:05—16. C . A . JACOBSON. Silica Fluff.
10:35—25.
SYMPOSIUM ON T H E M U T U A L PROBLEMS O P O R G A N I C AND P H Y S I CAL CHEMISTRY. D . H. A N D R E W S , Presiding
The
Cobalt-Manganese.
C. J . BROCKMAN,
D . H . ANDREWS,
The
YUSTER.
L o u i s W A L D B A U E R A N D G L E N N DOOLEY.
Apparatus and Conversion Chart for t h e Routine H i g h Vacuum Distillation of Oils. 10:00—Annual Business Meeting. Election of Officers.
N. H . FTJRMAN, Vice Chairman;
REVERSON.
I I . T h e Heterogeneous R e a c -
Structure of Binary Alloys.
An
DIVISION OF PHYSICAL AND INORGANIC CHEMISTRY
H.
The Homogeneous Reaction.
W. J. S V I R B E L Y , J. E . ABLARD, A N D J. C. W A R N E R .
C . O. TONGBERG, D . Q U I G G L E , A N D M . R. F E N S E E . K . M. W A T S O N
REYERSON
GEORGE R .
efficient Small-Scale Fractionating Equipment. 9:30—11.
A N D L.
I.
Dipole Moments of d-Pinene and d-Limonene. 3:15—12. JOHN A. MORROW. Precision Determination of t h e Capacity-Temperature Curve for Benzene between 2 0 ° and 25* C .
4:15—17.
W . E . K U H N AND J. F. COLLINS, J R .
YUSTBR
T h e Relationship of Oxidation Antioxygenic Action.
TUESDAY MORNING A N D AFTERNOON JOSEPH D .
SAMUEL
Chlorination of Propane. tion.
Assistant
Rose Room 9 : 0 0 — 1.
S. E. S H E P P A R D , T.-R. W I L K I N S , E . P . W I G H T M A N ,
Chlorination o f Propane.
Chairman
C . L. JOHNSON, Local
297
A N D R. N . WOLFE. T h e Temperature Coefficient of Photographic Sensitivity. I I . Effect of L o w Temperatures o n t h e Photographic Action of Alpha Particles. 2 : 3 0 — 8.
DIVISION OF PETROLEUM CHEMISTRY C. R. WAGNER, Secretary;
C H E M I S T R Y
M.
H.
BEDFORD,
R.
J.
AUSTIN,
AND WILLIAM
W E B B , J R . Activation Energies i n Reactions of Thiosulfate Ion w i t h the Ions of Brominated Dibasic Acids. 10:30—35. P A U L S. ROLLER. The Physical and Chemical Relations in Fluid Phase Heterogeneous Reaction. 10:45—36. C. A . K R A U S AND F . C. SCHMIDT. H e a t s of Solution a n d Heats of Reaction i n Liquid Ammonia. 11:00—37. A L D E N J D E T B U P . Kinetics of Decomposition of Ammonium Amalgam.
298
NEWS
11:10—38.
H. H . STORCH A N D . C W. MONTGOMERY.
Equation
for Hydrogen-Oxygen Explosion Limits. 11:25—39.
H. L. JOHNSTON A N D E. A . LONG.
Determinations
of t h e Heat Capacities of Carbon Dioxide a n d of Nitrous Oxide between 200° K. and 425° K. b y Precision Measurements of t h e Velocity of Sound. Correlation with the Spectroscopic Data. 11:40—40.
H. L. JOHNSTON A N D C. O. D A V I S .
D IT ION
Vol. 1 2 , No. 16
4:30—65. L E E NUTTING. T h e Conductance of Mixtures of Uni-Univalent Electrolytes. 4:45—66.
H . F . JOHNSTONE AND P. W. LEPPLA.
bility of Sulfur Dioxide at Low Partial Pressures. X h e Ionization Constant and Heat of Ionization of Sulfurous Acid.
Separation of
THURSDAY MORNING
the Hydrogen Isotopes b y the Addition of Metals and Metallic Compounds to Water, Acids, o r Bases. 11:50—41.
P. J. FLORY A N D H . L. JOHNSTON.
Aqueous T h e Solu-
SECTION A
T h e Photo-
Banquet Room
chemical Decomposition of Nitric Oxide.
SYMPOSIUM ON THE CHEMISTRY OP FLUORINE W E D N E S D A Y AFTERNOON
H . S. BOOTH,
SECTION A
Banquet B o o m D. H. ANDREWS, 2:00—42.
Presiding
S. C . L I N D A N D I t . S. LIVINGSTON.
Influence of
Foreign Gases on the Yield i n Polymerization b y a-Rays. 2:15—43.
S. C . L I N D , J. C. JTJNGERS, A N D C. HE. SBTFLETT.
Polymerization of H e a v y Acetylene by «-Rays. 2:30—44. DONALD H . A N D R E W S . A General M e t h o d for the Calculation of Characteristic Vibrational Frequencies in Complex Molecules. 2:45—45.
H.
M. D A V I S A N D GEORGE GLOCKLER.
Effect of Acetylenes. Acetylene. 3:00—46.
CHARLES
I.
MORRELL.
Raman Effect of Acetylenes. 3:15—47.
Raman
Methyl-, Dimethyl-, and VinylA N D GEORGE
GLOCKXER.
I I . Liquid Acetylene.
L O U I S S. K A S S E L A N D C . W. M O N T G O M E R Y .
The
Vibrations of Butane and Pentane a n d a N e w T y p e of Stereoisomerism. 3:30—48.
HENRY EYRING A N D BRYAN TOPLEY.
4:00—50.
SIMON F R E E D A N D HARRY G.
THODB.
A
Study
of t h e Metallic State. T h e Magnetic Susceptibilities of Metals Dissolved i n Liquid Ammonia. 4 : 1 5 — 5 1 . P. W. SELWOOD. Magnetochemicai Properties of Samarium. 4:25—52.
BERNARD
LEWIS
AND GXJENTHER
10:00—71.
10:45—74. ,10:55—75.
SECTION B
D.
Presiding
11:25—77.
THURSDAY MORNING SECTION B
Parlors 34 t o 36 D . H. ANDREWS, 9:00—79.
N E U S S A N D WILLIAM R I E M A N , 3 R D . T h e
A L F R E D S. B R O W N AND D . A . M A C I N N B S .
GEORGE SCATCHARD AND S. S. P R E N T I S S .
The
Freezing
10:20—85.
F.
W I L L I A M M O O R E C R A I G A N D G. WILSONT DRAJKE.
COWPERTHWAITE AND J. S H R A W D B R , J R .
The Activity Coefficients and Partial Molal H e a t of Dilution of Sulfuric Acid from Electromotive F o r c e Measurements. 4 : 0 0 — 6 3 . R A L P H P . SEWARD. Activity Coefficients of Salts in Ethylene Chloride from Solubility Measurements. FREDERICK A. L O W E N H E I M A N D LOUIS P . HAMMETT.
Electrolytic Conductance b y Proton Jumps. The Transference Number of Barium Bisulfate in the Solvent Sulfuric Acid.
W A L T E R SCHOLL A N D R. O. E . D A V I S .
Solubility
W . H . BASKERVILLE A N D F . K . CAMEROON. SoluE . W . CONSTABLE A N D F . K . CAMEROON. S o l u -
bility of Ferric Oxide in Aqueous Sulfuric Acid s t t 26° C Higher Concentrations. 10:30—86.
C . F . P R U T T O N , S. H . M A R O N , A N D E. L>. UNGHBR.
An Improved Method for t h e Study of Hydra-tea T h e Copper Sulfate-Water Isotherm at 2 5 * C. 10:46—87.
C . F . P R U T T O N , S. H . M A R O N , A N D E. L>. UNGHBR.
A Study of Hydrated Alumina b y a N e w Method11:15—89.
F R A N K T . G U C K E R , JR., AND T . RICBTARD R U B I N .
The Apparent Molal Isochoric Heat Capacity of Electrolytes.
4:15—64.
J A M E S B . R E E D WITH B . S. H O P K I N S AJND L.
bility of Ferric Oxide i n Aqueous Sulfuric Acid s t t 25* C Lower Concentrations.
3:30—61.
A.
Reactions
II.
of Urea in Liquid Ammonia.
11:00—88.
I.
Presiding
E . B . T H O M A S A N D L Y M A N J. WOOD.
between D r y Inorganic Salts.
Points of Aqueous Solutions of Salt Mixtures. 3:15—60. M . GALLAGHER A N D D. B . KEYES. T i i e Activities of Ethylene and Ethanol i n Sulfuric Acid.
3:46-r-62.
O. B . W I N T E R , F R A N C E S W. L A M B , A N D E. J- MILLJBR.
A Modification of t h e Fischer-Leopoldi Method for t h e Determination of Lead. 11:35—78. R. E . GIBSON. T h e Influence of the Concentration and Nature of t h e Solute on t h e Compression and Belated Properties of Aqueous Solutions.
10:10—84.
Determination of the Activities of Sodium Cbloride from the Potentials of Concentration Cells w i t h Transference. 3:00—59.
CHITTXJM. T h e
Hunt-Chittum Effect.
10:00—83.
A Vacuum
Application of the Glass Electrode to a Study of Chromic Acid. 2:30—57. L. G. LONGSWORTH. Automatic pH Control with the Glass Electrode. 2:45—58.
H E R S H E L H U N T A N D JOSEPH F .
Preparation a n d Properties of Gallium a n d Gallium T r i chloride.
Tube Titrometer witnout Batteries. J.
The
GENERAL PAPERS 11:15—76.
9:45—82. ELECTROCHEMISTRY
2:15—56.
F R A N K J. SOWA A N D J U L I U S A. N I E U W L A N D .
AUDRIETH. A N e w Method for t h e Preparation of AnJiydrous Rare Earth Salts. 9 : 3 0 — 8 1 . L . F . AUDRIETH. Solid and Fused Oniunci Salts as Acids.
Parlors 3 4 to 3 6 N . H. F U R M A N ,
H . D . H I N T O N A N D J U L I U S A. NIEUWLAIOT. X h e
Condensation of Olefins with Organic Compounds in t h e Presence of Boron Fluoride.
9:15—80. W E D N E S D A Y AFTERNOON
O. B . H A G E R , J R . , A N D H . H. WXLLARD.
N e w Tcchmic
Role of Boron Fluoride in Organic Chemistry.
VON ELBE.
Anomalous Pressures i n Gas Explosions. Determination of the Dissociation Energy of 2 H 2 0 ±z 2 0 H -|- H 2 . 4 : 4 0 — 5 3 . 0 . M A A S S . Discontinuity of Physical and Chemical Properties a t t h e Critical Temperature. 4:50—54. E. O. W I I G . T h e Photo Decomposition of A m monia. 5:00—Business Meeting. Election of Officers.
2:00—55.
H . S. BOOTH A N D A. R. BOZARTH.
in t h e Laboratory Preparation and Purification of Fluoride Gases. 10:15—72. L u c i u s A . BIGELOW. T h e Direct Fluoridation, of Organic Compounds with Elemental Fluorine. 10:30—73. A L B E R T L . H E N N E . T h e Fluorination of Aliphatic Derivatives.
Theoretical
Calculation of t h e Temperature Independent Factor in Reaction Rates. 3:45—49. ALBERT SHERMAN. Calculation of Activation Energies.
Presiding
9:00—67. H . H . WILLARD. The Analytical Determination of Fluorine. 9:15—68. J. H . SIMONS. Liquid Hydrogen Fluoride*. 9:30—69. GEORGE H. CADY. N O S F — A n Explosive Compound. 9:45—70. H . S. BOOTH. N e w Gaseous Chlorofluori
