Publications and Patents of Jack H. Freed - The Journal of Physical

Anomalous Alternating Linewidths in ESR Spectra; J. H. Freed and G. K. Fraenkel, .... Dynamic Effects of Pair Correlation Functions on Spin Relaxation...
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J. Phys. Chem. B 2004, 108, 9381-9389

9381

Publications and Patents of Jack H. Freed 1. Anomalous Alternating Linewidths in ESR Spectra; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 37, 11561157 (1962). 2. Alternating Linewidths in the ESR Spectra of Dinitrobenzene Anion Radicals; J. H. Freed, P. H. Rieger, and G. K. Fraenkel, J. Chem. Phys. 37, 1881-1882 (1962). 3. Solvent Effects in Electron Spin Resonance Spectra; J. Gendell, J. H. Freed, and G. K. Fraenkel, J. Chem. Phys. 37, 2832-2841 (1962). 4. Intramolecular Hydrogen Bonding in ESR Spectra; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 38, 20402041 (1963). 5. Theory of Linewidths in Electron Spin Resonance Spectra; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 39, 326348 (1963). 6. Linewidth Studies in Electron-Spin Resonance Spectra: The Para and Ortho Dinitrobenzene Anions; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 40, 1815-1829 (1964). 7. On the Theory of Spin Relaxation of Gas Molecules: The Strong Collision Limit; J. H. Freed, J. Chem. Phys. 41, 7-13 (1964). 8. Alternating Linewidths and Related Phenomena in the Electron-Spin Resonance Spectra of Nitro-substituted Benzene Anions; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 41, 699-716 (1964). 9. Line Shapes in Electron-Spin Resonance Spectra; J. Gendell, J. H. Freed, and G. K. Fraenkel, J. Chem. Phys. 41, 949-959 (1964). 10. Theory of Linewidths in Electron-Spin Resonance Spectra: Motion of Methyl Groups; J. H. Freed and G. K. Fraenkel, J. Am. Chem. Soc. 86, 3477-3484 (1964). 11. Anisotropic Rotational Diffusion and Electron Spin Resonance Line-widths; J. H. Freed, J. Chem. Phys. 41, 2077-2083 (1964). 12. Semi-Classical Theory of the Effects of Internal Motions on the Line-widths in Electron-Spin Resonance Spectra; J. H. Freed and G. K. Fraenkel, J. Chem. Phys. 41, 3623-3638 (1964). 13. ESR Hyperfine Linewidths from Benzene Anion Distortions; J. H. Freed, J. Chem. Phys. 43, 1427-1428 (1965). 14. Quantum Effects of Methyl Group Rotations in Magnetic Resonance: ESR Splittings and Linewidths; J. H. Freed, J. Chem. Phys. 43, 1710-1720 (1965). 15. Theory of Saturation and Double Resonance Effects in ESR Spectra; J. H. Freed, J. Chem. Phys. 43, 23122332 (1965). 16. Theory of Spin Relaxation Via Quantum-Molecular Systems: Resonance Effects; J. H. Freed, J. Chem. Phys. 45, 1251-1257 (1966). 17. On Heisenberg Spin-Exchange in Liquids, J. H. Freed, J. Chem. Phys. 45, 3452-3453 (1966). 18. Theory of Saturation and Double Resonance Effects in ESR Spectra II: Exchange vs. Dipolar Mechanisms; J. H. Freed, J. Phys. Chem. 71, 38-51 (1967). 19. Theory of Saturation and Double Resonance Effects in ESR Spectra III: RF Coherence and Line Shapes; J. H. Freed, D. S. Leniart, and J. S. Hyde, J. Chem Phys. 47, 2762-2773 (1967).

20. Electron-Electron Double Resonance of Free Radicals in Solution; J. S. Hyde, J. C. W. Chien, and J. H. Freed, J. Chem. Phys. 48, 4211-4226 (1968). 21. Generalized Cumulant Expansions and Spin-Relaxation Theory; J. H. Freed, J. Chem. Phys. 49, 376-391 (1968). 22. T1/T2 and Spin Relaxation in the Benzene Anion; J. H. Freed and R. G. Kooser, J. Chem. Phys. 49, 4715-4717 (1968). 23. Theory of Saturation and Double Resonance Effects in ESR Spectra IV: Electron Nuclear Triple Resonance; J. H. Freed, J. Chem. Phys. 50, 2271-2272 (1969). 24. ESR Relaxation Studies on Orbitally Degenerate Free Radicals: I. Benzene Anion and Tropenyl; R. G. Kooser, W. V. Volland, and J. H. Freed, J. Chem. Phys. 50, 5243-5257 (1969). 25. ESR Studies of Heisenberg Spin Exchange I: Linewidth and Saturation Effects; M. P. Eastman, R. G. Kooser, M. R. Das, and J. H. Freed, J. Chem. Phys. 51, 26902709 (1969). 26. ESR Studies of Heisenberg Spin Exchange II: The Effects of Radical Size and Charge; M. P. Eastman, G. V. Bruno, and J. H. Freed, J. Chem. Phys. 52, 2511-2522 (1970). 27. ESR Studies of Heisenberg Spin Exchange III: ELDOR Experiments; M. P. Eastman, G. Bruno, and J. H. Freed, J. Chem. Phys. 52, 321-327 (1970). 28. An Electron Nuclear Double Resonance and Electron Spin Resonance Study of Semiquinones Related to Vitamins K and E; M. R. Das, H. D. Connor, D. S. Leniart, and J. H. Freed, J. Am. Chem. Soc. 92, 2258-2268 (1970). 29. ESR Relaxation Studies on Orbitally Degenerate Free Radicals II; M. R. Das, S. B. Wagner, and J. H. Freed, J. Chem. Phys. 52, 5404-5417 (1970). 30. ESR Lineshapes and Saturation in the Slow Motional Region; J. H. Freed, G. V. Bruno, and C. F. Polnaszek, J. Phys. Chem. 75, 3385-3399 (1971). 31. ESR Lineshapes for Triplets Undergoing Slow Rotational Reorientation; J. H. Freed, G. V. Bruno, and C. Polnaszek, J. Chem. Phys. 55, 5270-5281 (1971). 32. An ESR Study of Anisotropic Rotational Reorientation and Slow Tumbling in Liquid and Frozen Media; S. A. Goldman, G. V. Bruno, C. F. Polnaszek, and J. H. Freed, J. Chem. Phys. 56, 716-735 (1972). 33. An ESR Study of Heisenberg Spin Exchange in a Binary Liquid Solution Near the Critical Point; J. C. Lang, Jr. and J. H. Freed, J. Chem. Phys. 56, 4103-4114 (1972). 34. Ch. VIII: ESR Relaxation and Lineshapes from the Generalized Cumulant and Relaxation Matrix Viewpoint. Ch. IX: Spin Relaxation via Quantum Molecular Systems. Ch. XIV: ESR Lineshapes and Saturation in the Slow Motional Region-The Stochastic Liouville Approach. Ch. XVIII: ESR Saturation and Double Resonance in Liquids; J. H. Freed in Electron-Spin Relaxation in Liquids, L. T. Muus, Ed., Plenum Publishing Co.: New York, 1972. 35. Spin-Rotational Relaxation in One Dimension: Angular Momentum-Orientational Correlation; J. H. Freed, J. Chem. Phys. 56, 1407-1408 (1972).

10.1021/jp040276j CCC: $27.50 © 2004 American Chemical Society Published on Web 07/01/2004

9382 J. Phys. Chem. B, Vol. 108, No. 27, 2004 36. Estimating Slow-Motional Rotational Correlation Times for Nitroxides by ESR; S. A. Goldman, G. V. Bruno, and J. H. Freed, J. Phys. Chem. 76, 1858-1860 (1972). 37. Electron Spin Resonance; J. H. Freed, Annual ReView of Physical Chemistry, 23, 265-310 (1972). 38. Calculation of Magnitudes of Chemically-Induced Dynamic Electron Polarizations; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 57, 1004-1006 (1972). 39. Theory of Saturation and Double Resonance Effects in ESR Spectra V: The Average ENDOR and ELDOR lines; J. H. Freed, D. S. Leniart, and H. D. Connor, J. Chem. Phys. 58, 3089-3105 (1973). 40. Theory of Chemically-Induced Dynamic Electron Polarization I; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 58, 2746-2762 (1973). 41. ESR Lineshapes in the Slow Motional Region: Anisotropic Liquids; C. Polnaszek; G. V. Bruno, and J. H. Freed, J. Chem. Phys. 58, 3185-3199 (1973). 42. Theory of Chemically-Induced Dynamic Electron Polarization II; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 59, 2869-2885 (1973). 43. ESR Studies of Anisotropic Rotational Reorientation and Slow Tumbling in Liquid and Frozen Media II: Saturation and Non-secular Effects; S. A. Goldman, G. V. Bruno,andJ.H.Freed,J.Chem.Phys.59,3071-3091(1973). 44. Estimating Microsecond Rotational Correlation Times from Lifetime Broadening of Nitroxide ESR Spectra; R. P. Mason and J. H. Freed, J. Phys. Chem. 78, 13211323 (1974). 45. Analysis of Inertial Effects on ESR Spectra in the Slow Tumbling Region; G. V. Bruno and J. H. Freed, J. Phys. Chem. 78, 935-940 (1974). 46. ESR Lineshapes and Saturation in the Slow Motional Region: ELDOR; G. V. Bruno and J. H. Freed, Chem. Phys. Lett. 25, 328-332 (1974). 47. Theory of Saturation and Double Resonance in ESR Spectra VI: Saturation Recovery; J. H. Freed, J. Phys. Chem. 78, 1155-1167 (1974). 48. Comments on the Interpretation of ESR Spectra of Spin Labels Undergoing Very Anisotropic Rotational Reorientation; R. P. Mason, C.F. Polnaszek, and J. H. Freed, J. Phys. Chem. 78, 1324-1329 (1974). 49. Theory of Slow Tumbling ESR Spectra for Nitroxides; J. H. Freed, Chapter 3 in Spin Labeling Theory and Applications, L. J. Berliner, Ed., Academic Press: N.Y., 1976; pp. 53-132. 50. Some Theoretical Aspects of Chemically-Induced Dynamic Nuclear Polarization; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 61, 1517-1525 (1974). 51. A Hydrodynamic Effect on Chemically-Induced Dynamic Spin Polarization; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 62, 1790-1795 (1975). 52. ESR Studies of Anisotropic Rotational Reorientation and Slow Tumbling in Liquid and Frozen Media III: PDTempone and an Analysis of Fluctuating Torques; J. S. Hwang, R. P. Mason, L. P. Hwang, and J. H. Freed, J. Phys. Chem. 79, 489-511 (1975). 53. Theory of Chemically-Induced Dynamic Electron Polarization III. Initial Triplet Polarizations; J. B. Pedersen and J. H. Freed, J. Chem. Phys. 62, 1706-1711 (1975). 54. An ESR and ENDOR Study of Spin-Relaxation of Semi Quinones in Liquid Solution; D. S. Leniart, H. D. Connor, and J. H. Freed, J. Chem. Phys. 63, 165-199 (1975).

55. A Comparison of Generalized Cumulant Expansions and Projection Operator Methods in Spin Relaxation Theory; B. Yoon, J. M. Deutch, and J. H. Freed, J. Chem. Phys. 62, 4687-4696 (1975). 56. Generalized Einstein Relations for Rotational and Translational Diffusion of Molecules Including Spin; L. P. Hwang and J. H. Freed, J. Chem. Phys. 63, 118-130 (1975). 57. The Theory of Chemically-Induced Dynamic Spin Polarization; J. H. Freed and J. B. Pedersen, AdV. Mag. Res. 8, 1-84 (1976). 58. ESR Studies of Anisotropic Ordering, Spin Relaxation, and Slow Tumbling in Liquid Crystalline Solvents; C. F. Polnaszek and J. H. Freed, J. Phys. Chem. 79, 22832306 (1975). 59. Dynamic Effects of Pair Correlation Functions on Spin Relaxation by Translational Diffusion in Liquids; L. P. Hwang and J. H. Freed, J. Chem. Phys. 63, 4017-4025 (1975). 60. An ESR Study of the Pressure Dependence of Ordering and Spin Relaxation in a Liquid Crystalline Solvent; J. S. Hwang, K. V. S. Rao, and J. H. Freed, J. Phys. Chem. 80, 1490-1501 (1976). 61. Symmetry of Orientational Order Fluctuations About the Nematic-Isotropic Phase Transition: An ESR Study; K. V. S. Rao, J. S. Hwang, and J. H. Freed, Phys. ReV. Lett. 37, 515-518 (1976). 62. ESR Studies of Spin Probes in Anisotropic Media; J. H. Freed, ACS Symposium Series 34: “Magnetic Resonance in Colloid and Interface Science”, Ch. 1, pp. 1-15 (1976). 63. ESR Studies of Anisotropic Ordering, Spin Relaxation, and Slow Tumbling in Liquid Crystalline Solvents, II; K. V. S. Rao, C. F. Polnaszek, and J. H. Freed, J. Phys. Chem. 81, 449-456 (1977). 64. Stochastic-Molecular Theory of Spin-Relaxation in Liquid Crystals; J. H. Freed, J. Chem. Phys. 66, 4183-4199 (1977). 65. Gyromagnetic Ratio; J. H. Freed in Encyclopedia of Physics; G. L. Trigg and R. Lerner, Eds., AddisonWesley: N.Y., 1980, pp. 376-377. 66. Numerical Methods and Model Dependence in Chemically-Induced Spin Polarization; J. H. Freed in Chemically Induced Magnetic Polarization, L. T. Muus et al., Eds., D. Reidel: Dordrecht-Holland (1977), Ch. 19, pp. 309-355. 67. Electron-Spin Relaxation in Isotropic and Ordered Fluids; J. H. Freed, Proceedings of the XXth International Spectroscopy Colloquium, Prague (1977), Vol. II, pp. 223-236. 68. Dynamic Effects of Pair Correlation Functions on Spin Relaxation by Translational Diffusion in Liquids II: Finite Jumps and Independent T1 Processes; J. Chem. Phys. 68, 4034-4037 (1978). 69. ESR Studies of Anisotropic Ordering, Spin Relaxation, and Slow Tumbling in Liquid Crystalline Solvents III: Smectics; W. J. Lin and J. H. Freed, J. Phys. Chem. 83, 379-401 (1979). 70. Multiple Electron Resonance Spectroscopy; M. Dorio and J. H. Freed, Eds.; Plenum: New York; Ch. 3, Theory of Multiple Resonance and ESR Saturation in Liquids and Related Media, J. H. Freed, 73-142 (1979).

J. Phys. Chem. B, Vol. 108, No. 27, 2004 9383 71. Theory of ESR Saturation Recovery in Liquids and Related Media; J. H. Freed in Time Domain ESR Spectroscopy, L. Kevan and R.N. Schwartz, Eds., Wiley: New York, 1979, Ch. 2. 72. NMR Studies of Very Anisotropic Slow Motion: 31P NMR of Phospholipids; R. F. Campbell, E. Meirovitch, and J. H. Freed, J. Phys. Chem. 83, 525-533 (1979). 73. Theory of Chemically-Induced Dynamic Spin Polarization IV: Low-Field Effects; G. P. Zientara and J. H. Freed, J. Chem. Phys. 70, 1359-1370 (1979). 74. An Explanation of Anomalous Results in the NMR Relaxation of a Probe in Liquid-Crystalline Media; H. A. Lopes Cardozo, J. Bulthuis, J. H. Freed, and W. M. M. J. Bove´e, Chem. Phys. Lett. 60, 335-337 (1979). 75. The Variational Method and the Stochastic-Liouville Equation I. A Finite-Element Solution for CIDNP/ CIDEP; G. P. Zientara and J. H. Freed, J. Chem. Phys. 70, 2587-2598 (1979). 76. ESR Study of Anisotropic Rotational Reorientation of Spin-Labels Attached to the Side Chains of Soluble Polymethacrylamide-Type Co-polymers; J. Pilar, J. Labsky, J. Kalal, and J. H. Freed, J. Phys. Chem. 83, 1907-1914 (1979). 77. Chemically-Induced Dynamic-Spin Polarization in Two Dimensional Systems: Theoretical Predictions; G. P. Zientara and J. H. Freed, J. Chem. Phys. 71, 38613879 (1979). 78. Slow Motional NMR Lineshapes for Very Anisotropic Diffusion: I)1 Nuclei; E. Meirovitch and J. H. Freed, Chem. Phys. Lett. 64, 311-316 (1979). 79. The Variational Method and the Stochastic-Liouville Equation: II. ESR Spectral Simulation Via Finite Elements; A. E. Stillman, G. P. Zientara, and J. H. Freed, J. Chem. Phys. 71, 113-118 (1979). 80. Is Spin-Aligned Hydrogen a Bose Gas?; J. H. Freed, J. Chem. Phys. 72, 1414-1415 (1980). 81. The Variational Method and the Stochastic-Liouville Equation: III. Infinite Elements for CIDN(E)P; G. P. Zientara and J. H. Freed, J. Chem. Phys. 71, 744-749 (1979). 82. Stochastic Modeling of Generalized Fokker-Planck Equations: I; A. E. Stillman and J. H. Freed, J. Chem. Phys. 72, 550-566 (1980). 83. Theory of Chemically-Induced Dynamic Spin Polarization V: Orientation-Dependent Effects; G. P. Zientara and J. H. Freed, J. Phys. Chem. 83, 3333-3344 (1979). 84. Spin-Echoes for Diffusion in Bounded, Heterogeneous Media: A Numerical Study; G. P. Zientara and J. H. Freed, J. Chem. Phys. 72, 1285-1292 (1980). 85. Slow Motional ESR Spectra for Vanadyl Complexes and Their Model Dependence; R. F. Campbell and J. H. Freed, J. Phys. Chem. 84, 2668-2680 (1980). 86. ESR Studies of Anisotropic Ordering, Spin Relaxation, and Slow Tumbling in Liquid Crystalline Solvents, IV. Cholestane Motions and Surface Anchoring in Smectics; E. Meirovitch and J. H. Freed, J. Phys. Chem. 84, 24592472 (1980). 87. ESR Studies of Low Water Content DPPC in Oriented Multilayers: I. Evidence for Long-Range Cooperative Chain Distortions; E. Meirovitch and J. H. Freed, J. Phys. Chem. 84, 3281-3295 (1980).

88. ESR Studies of Low Water Content DPPC in Oriented Multilayers: II. Evidence for Magnetic-Field-Induced Reorientation of the Polar Headgroups; E. Meirovitch and J. H. Freed, J. Phys. Chem. 84, 3295-3303 (1980). 89. Ultra-High Vacuum ESR Studies on Clean Metal Surfaces: NO2 on Copper; M. Nilges, M. Shiotani, C. T. Yu, G. Barkley, Y. Kera, and J. H. Freed, J. Chem. Phys. 73, 588-589 (1980). 90. Spin-Aligned Hydrogen: Some Considerations for ESR vs. NMR Experiments and Preliminary Observations of Hv at Low Temperatures; B. Yurke, D. Igner, E. Smith, B. Johnson, J. Denker, C. Hammel, D. Lee, and J. H. Freed, J. de Phys. 41, C7:177-184 (1980). 91. Diffusion-Controlled Kinetics of Protein Domain Coalescence: Effects of Orientation, Inter-Domain Forces and Hydration; G. P. Zientara, J. A. Nagy, and J. H. Freed, J. Chem. Phys. 73, 5092-5106 (1980). 92. Direct Determination of Rotational Correlation Time by Electron-Spin Echoes; A. E. Stillman, L. J. Schwartz, and J. H. Freed, J. Chem. Phys. 73, 3502-3503 (1980); 76, 5658 (1982). 93. The Efficient Computation of Magnetic Resonance Spectra and Related Correlation Functions from Stochastic Liouville Equations; G. Moro and J. H. Freed, J. Phys. Chem. 84, 2837-2840 (1980). 94. ESR Studies of O2- Adsorbed on Ti Supported Surfaces: Analysis of Motional Dynamics; M. Shiotani, G. Moro, and J. H. Freed, J. Chem. Phys. 74, 2616-2640 (1981). 95. Calculation of ESR Spectra and Related Fokker-Planck Forms by the Use of the Lanczos Algorithm; G. Moro and J. H. Freed, J. Chem. Phys. 74, 3757-3773 (1981). 96. Effects of Defect Annealing on Concentration-Dependent ESR Spectra from Hydrated Dimyristoyl Phosphatidyl Choline (DMPC); E. Meirovitch and J. H. Freed, J. Phys. Chem. 85, 1617-1619 (1981). 97. Rotational Jumps of the Tyrosine Side Chain in Crystalline Enkephalin. 2H NMR Lineshapes for Aromatic Ring Motions in Solids; D. M. Rice, R. J. Wittebort, R. G. Griffin, E. Meirovitch, E. R. Stimson, Y. C. Meinwald, J. H. Freed, and H. A. Scheraga, J. Am. Chem. Soc. 103, 7707-7710 (1981). 98. Classical Time-Correlation Functions and the Lanczos Algorithm; G. Moro and J. H. Freed. J. Chem. Phys. 75, 3157-3159 (1981). 99. A UHV-ESR Study of the Reactions of NO2 Adsorbed on Copper; M. Nilges, G. Barkley, M. Shiotani, and J. H. Freed, J. Chim. Phys. 78, 909-919 (1981). 100. ESR Studies of NO2 Adsorbed on Surfaces: Analysis of Motional Dynamics; M. Shiotani and J. H. Freed, J. Phys. Chem. 85, 3873-3883 (1981). 101. UHV-ESR and CREMSEE: Two Novel Surface Techniques; M. Nilges and J. H. Freed, Chem. Phys. Lett. 82, 203-207 (1981). 102. A Cryostat for Investigating Spin Polarized Hydrogen; B. Yurke, J. S. Denker, B. R. Johnson, J. H. Freed, and D. M. Lee, Physica 107B, 521-522 (1981). 103. Dynamics of Protein Domain Coalescence: II; G. P. Zientara, J. A. Nagy, and J. H. Freed, J. Phys. Chem. 86, 824-832 (1982). 104. Nitroxides and Chemical Physics, Finnish Chemistry 9, 50-51 (1982). 105. A Quantum Stochastic Fokker-Planck Theory for Adiabatic Processes in Condensed Phases; W. A. Wassam, Jr. and J. H. Freed, J. Chem. Phys. 76, 6133-6149 (1982).

9384 J. Phys. Chem. B, Vol. 108, No. 27, 2004 106. A Quantum Stochastic Theory for Non-Adiabatic Processes in Condensed Phases and on Surfaces; W. A. Wassam, Jr. and J. H. Freed, J. Chem. Phys. 76, 61506169 (1982). 107. Photoelectric Determination of Work Function Via CREMSEE Enhancement: Photo-CREMSEE; M. Nilges and J. H. Freed, Chem. Phys. Lett. 85, 499-504 (1982). 108. Electrohydrodynamic Instabilities Observed in a Nematic Phase Under Oblique Boundary Conditions; D. Igner and J. H. Freed, J. Chem. Phys. 76, 6095-6119 (1982). 109. Electron-Spin Relaxation and Ordering in Supercooled Nematic and Smectic Liquid Crystals: Cooperative Chain Distortions; E. Meirovitch, D. Igner, E. Igner, G. Moro,andJ.H.Freed,J.Chem.Phys.77,3915-3938(1982). 110. Electron-Spin Relaxation and Molecular Dynamics in Liquids I. Solvent Dependence; S. A. Zager and J. H. Freed, J. Chem. Phys. 77, 3344-3359 (1982). 111. Electron-Spin Relaxation and Molecular Dynamics in Liquids II. Density Dependence; S. A. Zager and J. H. Freed, J. Chem. Phys. 77, 3360-3375 (1982). 112. Analysis of Electron-Spin Echoes by Spectral Representation of the Stochastic-Liouville Equation; L. J. Schwartz, A. E. Stillman, and J. H. Freed, J. Chem. Phys. 77, 5410-5425 (1982). 113. NMR-Induced Recombination of Spin Polarized Hydrogen Atoms; B. Yurke, J. Denker, B. Johnson, N. Bigelow, L. P. Le´vy, D. M. Lee, and J. H. Freed, Phys. ReV. Lett. 50, 1137-1140 (1983). 114. A Molecular Orbital Study of O2- Adsorbed on Ti Supported Surfaces; M. Shiotani, K. Tatsumi, and J. H. Freed, J. Phys. Chem. 87, 3425-3429 (1983). 115. Cooperative Modes of Reorientation in Liquid Crystals; G. P. Zientara and J. H. Freed, J. Chem. Phys. 79, 30773089 (1983). 116. Quadrupole Echo Study of Internal Motions in Polycrystalline Media; L. J. Schwartz, E. Meirovitch, J. A. Ripmeester, and J. H. Freed, J. Phys. Chem. 87, 44534461 (1983). 117. Anisotropic Molecular Motion of Spin-Labeled Poly(methyl-methacrylate) Detected by ESR; M. Shiotani, J. Sohma, and J. H. Freed, Macromolecules 16, 14951499 (1983). 118. Multi-Pulse Sequences in Electron-Spin Echoes; U. Eliav and J. H. Freed, ReV. Sci. Instrum. 54, 1416-1417 (1983). 119. Stochastic Modeling of Molecular Dynamics, J. H. Freed, in Stochastic Processes-Formalism and Applications; G. S. Agarwal, Ed., Lecture Notes in Physics Vol. 184, 220-225 (Springer-Verlag: Berlin, 1983). 120. Transverse Viscous Forces in Carr Walls and Possible Dynamic Consequences; D. Igner and J. H. Freed, Mol. Cryst. Liq. Cryst. 101, 301-313 (1983). 121. Electron-Spin Echo Studies of Relaxation Times in Lithium-Methylamine Solutions; C. Page, G. Millhauser, P. Edwards, J. H. Freed, and M. J. Sienko, J. Phys. Chem. 88, 3785 (1984). 122. ELDOR Spin Echoes and Slow Motions; J. P. Hornak and J. H. Freed, Chem. Phys. Lett. 101, 115-119 (1983). 123. The Oscillatory Nature of Polarization Evolution in CIDEP; U. Eliav and J. H. Freed, J. Phys. Chem. 88, 1277-1280 (1984). 124. Observation of Nuclear Spin Waves in Spin-Polarized Atomic Hydrogen Gas; B. R. Johnson, J. S. Denker, N. Bigelow, L. P. Le´vy, J. H. Freed, and D. M. Lee, Phys. ReV. Lett. 52, 1508-1511 (1984).

125. Two Dimensional Electron-Spin-Echoes and Slow Motions; G. L. Millhauser and J. H. Freed, J. Chem. Phys. 81, 37-48 (1984). 126. An Analysis of Protein-Lipid Interactions based on Model Simulations of ESR Spectra; E. Meirovitch, A. Nayeem, and J. H. Freed, J. Phys. Chem. 88, 3454-3465 (1984). 127. Analysis of Slow-Motional ESR Spectra in Smectic Phases in Terms of Molecular Configuration, Intermolecular Interactions, and Dynamics; E. Meirovitch and J. H. Freed, J. Phys. Chem. 88, 4995-5004 (1984). 128. Detection of Slow Motions in Oriented Lipid Multilayers by Two Dimensional Electron-Spin Echo Spectroscopy; L. Kar, G. L. Millhauser, and J. H. Freed, J. Phys. Chem. 88, 3951-3956 (1984). 129. Molecular Dynamics at the Nematic-Smectic A Phase Transition: An ESR Study; S. A. Zager and J. H. Freed, Chem. Phys. Lett. 109, 270-275 (1984). 130. Observation of Spin Waves in Spin Polarized Hydrogen; B. R. Johnson, N. Bigelow, J. S. Denker, L. P. Le´vy, J. H. Freed, and D. M. Lee, Proceedings of 17th International. Conference on Low Temperature Physics (NorthHolland: NY 1984), pp. 451-452. 131. Spin Echoes in Spin Polarized Hydrogen; J. S. Denker, N. Bigelow, D. Thompson, J. H. Freed, and D. M. Lee, Proceedings of 17th International Conference on Low Temperature Physics (North-Holland: NY, 1984), pp. 549-550. 132. ESR Studies of Ordering and Rotational Diffusion in Oriented Phosphatidylcholine Multilayers: Evidence for a New Chain-Ordering Transition; H. Tanaka and J. H. Freed, J. Phys. Chem. 88, 6633-6644 (1984). 133. ESR Studies of Lipid-Gramicidin Interactions Utilizing Oriented Multi-bilayers; H. Tanaka and J. H. Freed, J. Phys. Chem. 89, 350-360 (1985). 134. ESR and Electron-Spin Echo Study of Oriented Multilayers of LR-Phosphatidyl-Choline Water Systems; L. Kar, E. Ney-Igner, and J. H. Freed, Biophys. J. 48, 569595 (1985). 135. Spin-Waves in Spin-Polarized Hydrogen; D. M. Lee and J. H. Freed, Physics Today 38, S-18 (Jan 1985). 136. Electron-Spin Echoes with a Loop-Gap Resonator; J. P. Hornak and J. H. Freed, J. Mag. Res. 62, 311-313 (1985). 137. Surface Suppressed Electron Resonance Spectroscopies; P. G. Barkley, J. Hornak, and J. H. Freed, J. Chem. Phys. 84, 1886-1900 (1986). 138. Spin-Waves in Spin-Polarized HV; J. H. Freed, Ann. Phys. 10, 901-921 (1985). 139. Diffusion Coefficients in Anisotropic Fluids by ESR Imaging of Concentration Profiles; J. P. Hornak, J. K. Moscicki, D. J. Schneider, and J. H. Freed, J. Chem. Phys. 84, 3387-3395 (1986). 140. Spectral Rotation in Pulsed ESR Spectroscopy; J. P. Hornak and J. H. Freed, J. Mag. Res. 67, 501-518 (1986). 141. The Lanczos Algorithm in Molecular Dynamics: Calculation of Spectral Densities; G. Moro and J. H. Freed, in Large-Scale EigenValue Problems, J. Cullum and R. Willoughby, Eds.; vol. 127, Mathematics Studies Series, (North-Holland, 1986), 143-160. 142. Two Dimensional Electron Spin Echoes: Magnetization Transfer and Molecular Dynamics; L. J. Schwartz, G. L. Millhauser, and J. H. Freed, Chem. Phys. Lett. 127, 60-66 (1986).

J. Phys. Chem. B, Vol. 108, No. 27, 2004 9385 143. Linear Prediction and Resolution Enhancement of Complex Lineshapes in Two-Dimensional Electron-SpinEcho Spectroscopy; G. L. Millhauser and J. H. Freed, J. Chem. Phys. 85, 63-67 (1986). 144. Two Dimensional Fourier Transform ESR Spectroscopy; J. Gorcester and J. H. Freed, J. Chem. Phys. 85, 53755377 (1986). 145. Calculation of ESR Spectra and Related Fokker-Planck Forms by the Use of the Lanczos Algorithm II. Criteria for Truncation of Basis Sets and Recursive Steps Utilizing Conjugate Gradients; K. V. Vasavada, D. J. Schneider, and J. H. Freed, J. Chem. Phys. 86, 647661 (1987). 146. New Time-Domain ESR Methods for the Study of Slow Motions on Surfaces; G. L. Millhauser, J. Gorcester, and J. H. Freed, in Electron Magnetic Resonance of the Solid State, J. A. Weil, Ed. (Can. Chem. Soc. Publ.) 571598 (1987). 147. Molecular Rotational Dynamics in Isotropic and Ordered Fluids by ESR; J. H. Freed, in Rotational Dynamics of Small and Macromolecules in Liquids, Lecture Notes in Physics, 293, 89-142, T. Dorfmu¨ller and R. Pecora, Eds., Springer-Verlag: Berlin (1987). 148. Comments on the Interpretation of Dynamic 2H NMR Spectra from Solid Inclusion Compounds; E. Meirovitch, S. Rananavare, and J. H. Freed, J. Phys. Chem. 91, 5014-5020 (1987). 149. Dynamic Effects of Pair Correlation Functions on SpinRelaxation by Translational Diffusion in Two-Dimensional Fluids; J. P. Korb, M. Ahadi, G. P. Zientara, and J. H. Freed, J. Chem. Phys. 86, 1125-1130 (1987). 150. DSC Characterization of Nematic-Smectic and SmecticSmectic Phase Transitions in N(p-n-alkoxy benzilidene)p-n-alkylanilines (nO.m), V. G. K. M. Pisipati, S. B. Rananavare, and J. H. Freed, Mol. Cryst. Liq. Cryst. Letters 4, 181-187 (1987). 2 151. H-NMR Study of the Structure and Dynamics of the Side Chains of Several Solid Polyglutamates; E. Meirovitch, E. T. Samulski, A. Leed, H. A. Scheraga, S. Rananavare, G. Nemethy, and J. H. Freed, J. Phys. Chem. 91, 48404851 (1987). 152. The Effects of Spin in Gases; F. Laloe¨ and J. H. Freed, Sci. Am. 258, 94-101 (1988). 153. Spin Relaxation and Motional Dynamics; D. J. Schneider and J. H. Freed, in Lasers, Molecules, and Methods, J. O. Hirschfelder, R. E. Wyatt, and R. D. Coalson, Eds., AdV. Chem. Phys., 73, 387-528 (1989). 154. Nematic Order Near a Tricritical Nematic-Smectic A Phase Transition; S. B. Rananavare, V. G. K. M. Pisipati, and J. H. Freed, Chem. Phys. Lett. 140, 255-262 (1987). 155. Measurement of the Longitudinal Spin Diffusion Coefficient in Spin Polarized Atomic Hydrogen; N. P. Bigelow, J. S. Denker, B. W. Statt, D. M. Lee, and J. H. Freed, Jpn. J. Appl. Phys. 526-3, 233-234 (1987). 156. Studies of Nonlinear Spin Oscillations in a Rarefied Quantum Gas: Spin-Polarized Atomic Hydrogen; N. P. Bigelow, B. W. Statt, D. M. Lee, and J. H. Freed, Jpn. J. Appl. Phys. 526-3, 235-236 (1987). 157. Two-Dimensional Fourier Transform ESR Correlation Spectroscopy; J. Gorcester and J. H. Freed, J. Chem. Phys. 88, 4678-4693 (1988).

158. Linear Prediction and Projection of Pure Absorption Lineshapes in Two-Dimensional FTESR Correlation Spectroscopy; J. Gorcester and J. H. Freed, J. Mag. Res. 78, 292-301 (1988). 159. Rapid Determination of Translational Diffusion Coefficients Using ESR Imaging; D. A. Cleary, Y.-K. Shin, D. J. Schneider, and J. H. Freed, J. Mag. Res. 79, 474492 (1988). 160. ESR and DSC Investigations of Phase Transitions in Polymorphic Benzylidene Anilines; S. B. Rananavare, V. G. K. M. Pisipati, and J. H. Freed, Liq. Cryst. 3, 957-976, (1988). 161. A 1 Millimeter-Wave ESR Spectrometer; B. Lynch, K. Earle, and J. H. Freed, ReV. Sci. Instrum. 59, 13451351 (1988). 162. Microwave Study of YBa2Cu3Ox Single Crystals; A. Dulcic´, R. Crepeau, and J. H. Freed, Phys. ReV. B 38, 5002-5005 (1988). 163. Calculating Slow Motional Magnetic Resonance Spectra: A User’s Guide; D. J. Schneider and J. H. Freed in Spin Labeling: Theory and Applications, Vol. III, Biological Magnetic Resonance 8, 1-76 (1989). (Plenum, NY). 164. Rapid Singular-Value Decomposition for Time-Domain Analysis of Magnetic Resonance Signals by Use of the Lanczos Algorithm; G. L. Millhauser, A. A. Carter, D. J. Schneider, J. H. Freed, and R. E. Oswald, J. Magn. Res. 82, 150-155 (1989). 165. Time Domain Spectroscopy of Linear Spin Wave Modes of Polarized Atomic Hydrogen Using a Linear Least Squares Technique; N. P. Bigelow, J. H. Freed, D. M. Lee, and B. W. Statt, in Spin Polarized Quantum Systems, S. Stringari, Ed., World Scientific: New Jersey, 1989, pp. 227-230. 166. Studies of Non-Linear Spin Dynamics of Polarized Atomic Hydrogen Using NMR Pulses of Finite Duration in an Applied Magnetic Field Gradient; N. P. Bigelow, J. H. Freed, D. M. Lee, and B. W. Statt in Spin-Polarized Quantum Systems, S. Stringari, Ed., World Scientific: New Jersey, 1989, pp. 231-235. 167. Theory for Dynamic Lineshapes of Strongly Correlated Two-Spin Systems; N. P. Benetis, D. J. Schneider, and J. H. Freed, J. Magn. Res. 85, 275-293 (1989). 168. Magnetic-Field Dependent Microwave Properties of YBa2Cu3Ox Single Crystals; A. Dulcic´, R. H. Crepeau, and J. H. Freed, Phys. ReV. B 39, 4249-4257 (1989). 169. Application of Lanczos and Conjugate Gradient Methods to a Class of Computational Problems in Physics; K. V. Vasavada and J. H. Freed, Comput. Phys. 3, 61-64 (1989). 170. Dynamic Imaging of Lateral Diffusion by Electron Spin Resonance and Study of Rotational Dynamics in Model Membranes: Effect of Cholesterol; Y.-K. Shin and J. H. Freed, Biophys. J. 55, 537-550 (1989). 171. Berry’s Geometrical Phases in ESR in the Presence of a Stochastic Process; D. Gamliel and J. H. Freed, Phys. ReV. A, 39, 3238-3255 (1989). 172. Two Dimensional ELDOR and Electron Spin Echo Study of Solute Dynamics in Smectics; J. Gorcester, S. B. Rananavare, and J. H. Freed, J. Chem. Phys. 90, 57645786 (1989). 173. Dynamic Imaging of Diffusion by ESR; J. K. Moscicki, Y.-K Shin, and J. H. Freed, J. Mag. Res. 84, 554-572 (1989).

9386 J. Phys. Chem. B, Vol. 108, No. 27, 2004 174. ESR Study of the Dynamic Molecular Structure of A Reentrant Nematic Liquid Crystal; A. Nayeem and J. H. Freed, J. Phys. Chem. 93, 6539-6550 (1989). 175. Composite Pulses in Time-Domain ESR; R. H. Crepeau, A. Dulcic´, T. R. Saarinen, and J. H. Freed, J. Magn. Res. 84, 184-190 (1989). 176. A Theoretical Model of Phospholipid Dynamics in Membranes; A. Ferrarini, P.-L. Nordio, G. J. Moro, R. H. Crepeau, and J. H. Freed, J. Chem. Phys. 91, 57075721 (1989). 177. Two Dimensional FTESR and Solute Dynamics in Smectics; J. Gorcester, S. B. Rananavare, and J. H. Freed, Bull. Mag. Res. 11, 305-309 (1989). 178. Two Dimensional and Fourier Transform ESR; J. Gorcester, G. L. Millhauser, and J. H. Freed, in AdVanced EPR Applications in Biology and Biochemistry, A. Hoff, Ed., Elsevier: Amsterdam, Ch. 5., pp. 177-242 (1989). 179. Electron Paramagnetic Resonance at 1 Millimeter Wavelengths; D. E. Budil, K. A. Earle, W. B. Lynch, and J. H. Freed, in AdVanced EPR Applications in Biology and Biochemistry, A. Hoff, Ed., Elsevier: Amsterdam, Ch. 8, pp. 307-340 (1989). 180. Discrete Microwave Absorption Lines in YBa2 Cu3O7-δ in Single Crystals; A. Dulcic´, R. H. Crepeau, and J. H. Freed, Physica C 160, 223-226 (1989). 181. Nuclear Spin Waves in Polarized Atomic Hydrogen Gas: Temperature and Density Dependence in the Hydrodynamic and Knudsen Regimes; N. P. Bigelow, J. H. Freed, and D. M. Lee, Phys. ReV. Lett. 63, 1609-1612 (1989). 182. Two-Dimensional Electron-Spin Resonance; J. Gorcester, G. L. Millhauser, and J. H. Freed, in AdVances in Pulsed and Continuous WaVe Electron Spin Resonance, L. Kevan and M. Bowman, Eds., Wiley: NY, Ch. 3, pp. 119-194 (1990). 183. Heisenberg Spin Exchange and Molecular Diffusion in Liquid Crystals; A. Nayeem, S. R. Rananavare, V. S. S. Sastry, and J. H. Freed, J. Chem. Phys. 91, 68876905 (1989). 184. Thermodynamics of Phophatidylcholine-Cholesterol Mixed Model Membranes in the Liquid Crystalline State Studied by the Orientational Order Parameter; Y.-K. Shin and J. H. Freed, Biophys. J. 56, 1093-1100 (1989). 185. Dynamic Imaging of Diffusion in One Dimension by cw ESR; J. K. Moscicki, Y. K. Shin, and J. H. Freed, Physica Medica V, 229-237 (1989). 186. The Method of Dynamic Imaging of Diffusion by EPR; J. K. Moscicki, Y. K. Shin, and J. H. Freed in EPR Imaging and In ViVo EPR, G. Eaton, S. Eaton, and K. Ohno, Eds., CRC Press, Ch. 19, pp. 189-219 (1991). 187. Dynamics of Phosphatidylcholine-Cholesterol Mixed Model Membranes in the Liquid Crystalline State; Y. K. Shin, J. K. Moscicki, and J. H. Freed, Biophys. J., 57, 445-459 (1990). 188. Theory of Two-Dimensional ESR with Nuclear Modulation; D. Gamliel and J. H. Freed, J. Mag. Res. 89, 6093 (1990). 189. ESR and Liquid Crystals: Statistical Mechanics and Generalized Smoluchowski Equations; J. H. Freed, A. Nayeem, and S. B. Rananavare in The Molecular Dynamics of Liquid Crystals, G. Luckhurst and C. Veracini, Eds., Kluwer: Dordrecht, The Netherlands, Ch. 4, pp. 71-84 (1994).

190. ESR and Molecular Motions in Liquid Crystals: Motional Narrowing; J. H. Freed, A. Nayeem, and S. B. Rananavare, in The Molecular Dynamics of Liquid Crystals, G. Luckhurst, C. Veracini, Eds., Kluwer: Dordrecht, The Netherlands, Ch. 12, pp. 271-312 (1994). 191. ESR and Slow Motions in Liquid Crystals; J. H. Freed, A. Nayeem, and S. B. Rananavare, in The Molecular Dynamics of Liquid Crystals, G. Luckhurst and C. Veracini, Eds., Kluwer: Dordrecht, The Netherlands, Ch. 15, pp. 365-402 (1994). 192. ESR Studies of Molecular Dynamics at Phase Transitions in Liquid Crystals, J. H. Freed, A. Nayeem, and S. B. Rananavare, in The Molecular Dynamics of Liquid Crystals, G. Luckhurst and C. Veracini, Eds., Kluwer: Dordrecht, The Netherlands, Ch. 14, pp. 335-364 (1994). 193. Thermodynamics of Liquid Crystals and the Relation to Molecular Dynamics: ESR Studies, J. H. Freed, A. Nayeem, and S. B. Rananavare, in The Molecular Dynamics of Liquid Crystals, G. Luckhurst and C. Veracini, Kluwer: Dordrecht, The Netherlands, Ch. 13, pp. 313-333 (1994). 194. Weak Link Structure in YBa2Cu3O7 Single Crystals: A Microwave Study, A. Dulcic´, R. H. Crepeau, J. H. Freed, L. F. Schneemeyer, and J. V. Waszczak, Phys. ReV. B 42, 2155-2160 (1990). 195. ESR Studies of Binding of Stearic Acid to Bovine Serum Albumin, M.-T. Ge, S. B. Rananavare, J. H. Freed, Biochim. Biophys. Acta 1036, 228-236 (1990). 196. Modern Techniques in Electron Paramagnetic Resonance Spectroscopy, J. H. Freed, J. Chem. Soc., Faraday Trans. 86, 3173-3180 (1990). 197. Non-Resonant Microwave Absorption in High Tc Thin Films, R. Durny, A. Dulcic´, R. H. Crepeau, J. H. Freed, and P. Kus, Physica C 171, 401-405 (1990). 198. A Many-Body Stochastic Approach to Rotational Motions in Liquids: a Reassessment of the Hubbard-Einstein Relation, A. Polimeno and J. H. Freed, Chem. Phys. Lett. 174, 338-346 (1990). 199. A Many-Body Stochastic Approach to Rotational Motions in Liquids: Complex Decay Times in Highly Viscous Fluids, A. Polimeno and J. H. Freed, Chem. Phys. Lett. 174, 481-488 (1990). 200. Microscopic vs. Macroscopic Diffusion in Model Membranes by ESR Spectral-Spatial Imaging, Y. K. Shin, U. Ewert, D. E. Budil, and J. H. Freed, Biophys. J. 59, 950-957 (1991). 201. Two Dimensional Fourier Transform ESR in the Slow Motional and Rigid Limits: SECSY-ESR, B. R. Patyal, R. H. Crepeau, D. Gamliel, J. H. Freed, Chem. Phys. Lett. 175, 445-452 (1990). 202. Two Dimensional Fourier Transform ESR in the Slow Motional and Rigid Limits: 2D-ELDOR, B. R. Patyal, R. H. Crepeau, D. Gamliel, J. H. Freed, Chem. Phys. Lett. 175, 453-460 (1990). 203. Fourier Transform Electron Spin Resonance Imaging, U. Ewert, R. H. Crepeau, C. R. Dunnam, D. Xu, S. Lee, and J. H. Freed, Chem. Phys. Lett. 184, 25-33 (1991). 204. Spatially-Resolved Two Dimensional Fourier Transform Electron Spin-Resonance, U. Ewert, R. H. Crepeau, S. Lee, C. R. Dunnam, D. Xu, and J. H. Freed, Chem. Phys. Lett. 184, 34-40 (1991). 205. A Many-Body Stochastic Approach to Rotational Motions in Liquids, A. Polimeno and J. H. Freed, AdV. Chem. Phys. 83, 89-206 (1993).

J. Phys. Chem. B, Vol. 108, No. 27, 2004 9387 206. Critical Fluctuations and Molecular Dynamics at Liquid Crystalline Phase Transitions I. Theoretical Aspects of the Nematic-Smectic A Phase Transition, J. H. Freed, J. Chem. Phys. 96, 3901-3911 (1992). 207. Critical Fluctuations and Molecular Dynamics at Liquid Crystalline Phase Transitions II. ESR Experiments, A. Nayeem, S. B. Rananavare, V. S. S. Sastry, and J. H. Freed, J. Chem. Phys. 96, 3912-3938 (1992). 208. Spin Diffusion in Doubly Spin-Polarized Atomic Deuterium, K. A. Earle, J. H. Freed, and D. M. Lee, J. Low Temp. Phys., 89, 911-937, (1992). 209. Primary Events in Photosynthesis: Problems, Speculations, Controversies and Future Trends, M. Bixon, G. Feher, J. Fajer, J. H. Freed, D. Gamliel, A. J. Hoff, H. Levanon, K. Mo¨bius, R. Nechushtai, J. R. Norris, A. Scherz, J. L. Sessler, D. Stehlik, Isr. J. Chem., 32, 369-518 (1992). 210. A Two-Dimensional Fourier Transform-ESR Study of Nuclear Modulation and Spin-Relaxation in Irradiated Malonic Acid, S.-Y. Lee, B. R. Patyal, and J. H. Freed, J. Chem. Phys., 98, 3665-3689 (1993). 211. Full Determination of the Rotational Diffusion Tensor by Electron Paramagnetic Resonance at 250 GHz, D. E. Budil, K. A. Earle, and J. H. Freed, J. Phys. Chem. 97, 1294-1303 (1993). 212. 250 GHz and 9.5 GHz EPR Studies of an Electride and Two Alkalides, D. H. Shin, J. L. Dye, D. E. Budil, K. A. Earle, and J. H. Freed, J. Phys. Chem. 97, 12131219 (1993). 213. Thermodynamics and Dynamics of Phosphatidylcholinecholesterol Mixed Model Membranes in the Liquid Crystalline State: Effects of Water, Y.-K. Shin, D. E. Budil, and J. H. Freed, Biophys. J., 65, 1283-1294 (1993). 214. Translational Diffusion in a Smectic-A Phase by ESR Imaging: The Free-Volume Model, J. K. Moscicki, Y.K. Shin, and J. H. Freed, J. Chem. Phys. 99, 634-649 (1993). 215. An ESR Study of Interactions Between Gramicidin A′ and Phosphatidylcholine Bilayers, M. T. Ge and J. H. Freed, Biophys. J. 65, 2106-2123 (1993). 216. A 250 GHz ESR Study of Highly Distorted Manganese Complexes, W. B. Lynch, R. S. Boorse, and J. H. Freed, J. Am. Chem. Soc., 115, 10909-10915 (1993). 217. Field Gradient ESR and Molecular Diffusion in Model Membranes, J. H. Freed, Ann. ReV. Biophys. Biomol. Struct., 23, 1-25 (1994). 218. 250 GHz EPR of Nitroxides in the Slow-Motional Regime: Models of Rotational Diffusion, K. A. Earle, D. E. Budil, and J. H. Freed, J. Phys. Chem., 97, 1328913297 (1993). 219. Studies on Lipid Membranes by Two Dimensional-Fourier Transform ESR: Enhancement of Resolution to Ordering and Dynamics, R. H. Crepeau, S. K. Saxena, S. Lee, B. R. Patyal, and J. H. Freed, Biophys. J. 66, 14891504 (1994). 220. An ESR Study of Interactions Between Phosphatidylcholine and Phosphatidylserine in Oriented Membranes, M. Ge, D. E. Budil, and J. H. Freed, Biophys. J., 66, 15151521 (1994). 221. 250 GHz ESR Studies of Polarity Gradients along the Aliphatic Chains in Phospholipid Membranes, K. A. Earle, J. K. Moscicki, M. Ge, D. E. Budil, and J. H. Freed, Biophys. J., 66, 1213-1221 (1994).

222. Two-Dimensional Fourier Transform ESR in Complex Fluids, S. Lee, B. R. Patyal, S. K. Saxena, R. H. Crepeau, and J. H. Freed, Chem. Phys. Lett., 221, 397406 (1994). 223. ESR Studies of Spin-Labeled Membranes Aligned by Isopotential Spin-Dry Ultracentrifugation: Lipid-Protein Interactions, M. Ge, D. E. Budil, and J. H. Freed, Biophys. J. 67, 2326-2344 (1994). 224. 9.6 GHz and 34 GHz EPR Studies of Chromium-Doped Forsterite, D. E. Budil, D. G. Park, J. M. Burlitch, R. F. Geray, R. Dieckmann, and J. H. Freed, J. Chem. Phys. 101, 3538-3548 (1994). 225. Theory of Two-Dimensional Fourier Transform ESR for Ordered and Viscous Fluids, S. Lee, D. E. Budil, and J. H. Freed, J. Chem. Phys. 101, 5529-5558 (1994). 226. ESR Studies of Molecular Dynamics of a Liquid Crystalline Polyether, D. Xu, J. K. Moscicki, D. E. Budil, J. H. Freed, E. Hall, and C. K. Ober, Polym. Preprints 35, 809-810 (1994). 227. Quenching of the Fluorescence from Chromium (III) Ions in Chromium-doped Forsterite by an Aluminum Codopant, J. L. Mass, J. M. Burlitch, D. E. Budil, J. H. Freed, D. B. Barber, C. R. Pollock, M. Higuchi, and R. Dieckmann, Chem. Mater. 7, 1008-1014 (1995). 228. Nuclear Modulation Effects in “2+1” Electron Spin-Echo Correlation Spectroscopy, A. Raitsimring, R. H. Crepeau, and J. H. Freed, J. Chem. Phys. 102, 8746-8762 (1995). 229. Rotational Dynamics of an Axially Symmetric Solute in Isotropic Solvents I. A Collective Cage Description from Molecular Dynamics Simulations, A. Polimeno, G. J. Moro, J. H. Freed, J. Chem. Phys. 102, 8094-8106 (1995). 230. Rotational Dynamics of an Axially Symmetric Solute in Isotropic Solvents II. The Stochastic Model, A. Polimeno, G. J. Moro, J. H. Freed, J. Chem. Phys. 104, 1090-1104 (1996). 231. Millimeter Wave Electron Spin Resonance Using Quasioptical Techniques, K. A. Earle, D. E. Budil, J. H. Freed, AdV. Magn. Opt. Res. 19, Ch. 3, pp. 253-323 (1996). 232. Non-Linear Least Squares Analysis of Slow-Motion EPR Spectra in One and Two Dimensions Using a Modified Levenberg-Marquardt Algorithm, D. E. Budil, S. Lee, S. Saxena, J. H. Freed, J. Magn. Res. A120, 155-189 (1996). 233. Slow Motional ESR in Complex Fluids: The Slowly Relaxing Local Structure Model of Solvent Cage Effects, A. Polimeno and J. H. Freed, J. Phys. Chem. 99, 1099511006 (1995). 234. ESR Studies of Nitrogen Oxides Adsorbed on Zeolite Catalysts: Analysis of Motional Dynamics; H. Yahiro, M. Shiotani, J. H. Freed, M. Lindgren, and A. Lund, in Catalysis by Microporous Materials, H. K. Beyer et al., Eds., Studies in Surface Science and Catalysis 94, 673680 (1995). 235. Site Selective EPR Study of Photoexcited Chromium Doped Forsterite, A. Regev and J. H. Freed, J. Chem. Phys. 103, 5315-5325 (1995). 236. ESR Spectrometer at 250 GHz, K. A. Earle and J. H. Freed, SPIE International Conference on IR and MM WaVes, Proceedings, M. Afsar, Ed., 2558, 86-97 (1995).

9388 J. Phys. Chem. B, Vol. 108, No. 27, 2004 237. Linewidths, Lineshapes, and Spin-Relaxation in the One and Two-Dimensional ESR of Organic Radicals and Spin-Labels, J. H. Freed in Foundations of Modern EPR, G. and S. Eaton, K. Salikhov, Eds., World Scientific: Singapore, Ch. I.7, 658-683, (1998). 238. Double Quantum Two Dimensional Fourier Transform Electron Spin Resonance: Distance Measurements, S. Saxena and J. H. Freed, Chem. Phys. Lett. 251, 102110 (1996). 239. Translational Diffusion in Polydisperse Polymer Samples Studied by Dynamic Imaging of Diffusion ESR, D. Xu, E. Hall, C. K. Ober, J. K. Moscicki, J. H. Freed, J. Phys. Chem., 100, 15856-15866 (1996). 240. Rotational Diffusion and Order Parameters of A Liquid Crystalline Polymer Studied by ESR: Molecular Weight Dependence, D. Xu, D. E. Budil, C. K. Ober, J. H. Freed, J. Phys. Chem., 100, 15867-15872 (1996). 241. Molecular Dynamics of a Liquid Crystalline Polymer Studied by Two-Dimensional Fourier Transform and cwESR, D. Xu, R. H. Crepeau, C. K. Ober, J. H. Freed, J. Phys. Chem., 100, 15873-15885 (1996). 242. The High Frequency EPR Spectra of Polyaniline: Line Narrowing due to Spin Exchange, D. S. Tipikin, K. A. Earle, J. H. Freed, Polym. Sci., Ser. B 41, 1043-1047 (1999). 243. Far Infrared EPR Spectrometer Utilizing a Quasi-Optical Reflection Bridge, K. A. Earle, D. S. Tipikin, J. H. Freed, ReV. Sci. Instrum. 67, 2502-2513 (1996). 244. Studies of Spin Relaxation and Molecular Dynamics in Liquid Crystals by Two Dimensional Fourier Transform ESR: I. Cholestane in Butoxy Benzylidene-Octylaniline and Dynamic Cage Effects, V. S. S. Sastry, A. Polimeno, R. H. Crepeau, and J. H. Freed, J. Chem. Phys. 105, 5753-5772 (1996). 245. Studies of Spin Relaxation and Molecular Dynamics in Liquid Crystals by Two Dimensional Fourier Transform ESR: II PD-Tempone in Butoxy Benzylidene-octylaniline and Dynamic Cage Effects, V. S. S. Sastry, A. Polimeno, R. H. Crepeau and J. H. Freed, J. Chem. Phys. 105, 5773-5791 (1996). 246. A Theoretical Approach to the Analysis of Arbitrary Pulses in Magnetic Resonance, K. M. Salikhov, D. J. Schneider, S. Saxena, and J. H. Freed, Chem. Phys. Lett. 262, 1726 (1996). 247. Absorption Lineshapes in Two Dimensional Electron Spin Resonance; Slow Motions in Complex Fluids, S. Saxena and J. H. Freed, J. Magn. Res. 124, 439-454 (1997). 248. An EPR Study of Some Highly Distorted Tetrahedral Manganese (II) Complexes at 250 GHz, R. M. Wood, D. M. Stucker, W. B. Lynch, S. K. Misra, and J. H. Freed, Inorg. Chem. 38, 5384-5388 (1999). 249. Chain Dynamics and the Simulation of ESR Spectra from Oriented Phospholipid Membranes, R. Cassol, M. Ge, A. Ferrarini, and J. H. Freed, J. Phys. Chem. B 101, 8782-8789, (1997). 250. Lipid-Gramicidin Interactions Using Two-Dimensional Fourier-Transform Electron Spin Resonance, B. Patyal, R. H. Crepeau, and J. H. Freed, Biophys. J. 73, 22012220, (1997). 251. A 250 GHz ESR Study of o-terphenyl: Dynamic Cage Effects above Tc, K. A. Earle, J. Moscicki, A. Polimeno, and J. H. Freed, J. Chem. Phys. 106, 9996-10015, (1997).

252. Aqueous Sample Holders for High-Frequency ESR, J. P. Barnes and J. H. Freed, ReV. Sci. Instrum. 68, 28382846 (1997). 253. Theory of Double Quantum Two-Dimensional ESR with Application to Distance Measurements, S. Saxena and J. H. Freed, J. Chem. Phys. 107, 1317-1340 (1997). 254. Multifrequency Two-Dimensional Fourier Transform ESR: An X/Ku-Band Spectrometer, P. B. Borbat, R. H. Crepeau, and J. H. Freed, J. Magn. Res. 127, 155167 (1997). 255. Two Dimensional ESR and Slow Motions, S. Saxena and J. H. Freed, J. Phys. Chem. A 101, 7998-8008 (1997). 256. Polarity Profiles in Oriented and Dispersed Phosphatidylcholine Bilayers are Different. An ESR Study, M. Ge and J. H. Freed, Biophys. J. 74, 910-917 (1998). 257. A Shunt Fabry-Perot Resonator for High Frequency ESR Using a Variable Coupling Scheme, J. P. Barnes and J. H. Freed, ReV. Sci. Instrum. 69, 3022-3027 (1998). 258. Dynamics and Ordering in Mixed Model Membranes of DMPC and DMPS: A 250 GHz ESR Study, J. P. Barnes and J. H. Freed, Biophys. J. 75, 2532-2546 (1998). 259. Electron-Spin Resonance Study of Aggregation of Gramicidin in DPPC Bilayers and Hydrophobic Mismatch, M. Ge and J. H. Freed, Biophys. J. 76, 264-280 (1999). 260. Response to “Comment on ‘A 250 GHz ESR Study of o-terphenyl Dynamic Cage Effects above Tc”, K. A. Earle, J. K. Moscicki, A. Polimeno, and J. H. Freed, J. Chem. Phys. 109, 10525-10526, (1998). 261. Multi-Frequency EPR Determination of Zero-Field Splitting of High-Spin Species in Liquids: Gd (III) Chelates in Water, R. B. Clarkson, A. I. Smirnov, T. I. Smirnova, H. Kang, R. L. Belford, K. A. Earle, and J. H. Freed, Mol. Phys. 95, 1325-1332 (1998). 262. A Multi-Frequency ESR Study of T4 Lysozyme Dynamics, J. Barnes, Z. Liang, H. Mchaourab, J. H. Freed, and W. Hubbell, Biophys. J. 76, 3298-3306, (1999). 263. Study of Motional Dynamics in Complex Fluids by Very High-Field, Very High-Frequency EPR (VHF-EPR), A. K. Hassan, J. van Tol, A. L. Maniero, L. C. Brunel, K. A. Earle, and J. H. Freed, Physical Phenomena at High Magnetic Fields -III. Z. Fisk, L. Gor’kov, J. R. Schrieffer, Eds., World Scientific: NJ, 453-456 (1999). 264. Quasioptical Hardware for a Flexible FIR-EPR Spectrometer, K. A. Earle and J. H. Freed, Appl. Magn. Res. 16, 247-272 (1999). 265. ESR Characterization of Liquid Ordered Phase of Detergent Resistant Membranes from RBL-2H3 Cells, M. Ge, K. A. Field, R. Aneja, D. Holowka, B. A. Baird, J. H. Freed, Biophys. J. 77, 925-933 (1999). 266. An Assessment of the Applicability of Multifrequency ESR to Study the Complex Dynamics of Biomolecules, Z. Liang and J. H. Freed, J. Phys. Chem. B, 103, 63846396 (1999). 267. Multiple-Quantum ESR and Distance Measurements, P. P. Borbat and J. H. Freed, Chem. Phys. Lett. 313, 145154 (1999). 268. Spin Relaxation by Dipolar Coupling: From Motional Narrowing to the Rigid Limit, A. A. Nevzorov and J. H. Freed, J. Chem. Phys. 112, 1413-1424 (2000). 269. Dipolar Relaxation in a Many-Body System of Spins of 1/2, A. A. Nevzorov and J. H. Freed J. Chem. Phys. 112, 1425-1443 (2000).

J. Phys. Chem. B, Vol. 108, No. 27, 2004 9389 270. An Electron Spin Resonance Study of DNA Dynamics Using the Slowly Relaxing Local Structure Model, Z. Liang, J. H. Freed, R. S. Keyes, A. M. Bobst, J. Phys. Chem. B 104, 5372-5381 (2000). 271. Double Quantum ESR and Distance Measurements, P. P. Borbat and J. H. Freed, Biol. Magn. Res. 19, Ch. 9, 383459 (2000). 272. New Technologies in Electron Spin Resonance, J. H. Freed, Annu. ReV. Phys. Chem. 51, 655-689 (2000). 273. Segmental Rotational Diffusion of Spin Labeled Polystyrene in Dilute Toluene Solution by 9 and 250 GHz ESR, J. Pilar, J. Labsky, A. Marek, D. E. Budil, K. A. Earle, and J. H. Freed, Macromolecules 33, 4438-4444 (2000). 274. Electron Spin Resonance in Studies of Membranes and Proteins, P. P. Borbat, A. J. Costa-Filho, K. A. Earle, J. K. Moscicki, and J. H. Freed, Science 291, 266-269, (2001). 275. ADP Ribosylation Factor 6 Binding to Phosphatidylinositol 4,5-Bisphosphate-Containing Vesicles Creates Defects in the Bilayer Structure: An Electron Spin Resonance Study, M. Ge, J. S. Cohen, H. A. Brown, and J. H. Freed, Biophys. J. 81, 994-105 (2001). 276. A Structural Mode-Coupling Approach to 15N NMR Relaxation in Proteins, V. Tugarinov, Z. Liang, Y. E. Shapiro, J. H. Freed, E. Meirovitch, J. Am. Chem. Soc. 123, 3055-3063 (2001). 277. Direct Product Formalism for Calculating Magnetic Resonance Relaxation in Many-Body Systems of Interacting Spins, A. A. Nevzorov and J. H. Freed, J. Chem. Phys. 115, 2401-2415 (2001). 278. A Many-Body Analysis of the Effects of the Matrix Protons and their Diffusional Motion on ESR Lineshapes and Electron Spin Echoes, A. A. Nevzorov and J. H. Freed, J. Chem. Phys. 115, 2416-2429 (2001). 279. A Multifrequency ESR Study of the Complex Dynamics of Membranes, Y. Lou, M. Ge, and J. H. Freed, J. Phys. Chem. B 105, 11053-11056 (2001). 280. Single-Crystal EPR Studies of Transition-Metal Ions in Inorganic Crystals at Very High Frequencies, S. K. Misra, S. A. Andronenko, K. A. Earle, J. H. Freed, Appl. Magn. Res. 21, 549-561 (2001). 281. A Novel View of Domain Flexibility in E. coli Adenylate Kinase Based on a Structural Mode-Coupling Approach to 15N NMR Relaxation, V. Tugarinov, Y. E. Shapiro, Z. Liang, J. H. Freed, E. Meirovitch, J. Mol. Biol. 315, 155-170 (2002). 282. Protein Structure Determination Using Long-Distance Constraints from Double-Quantum Coherence ESR: Study of T4-Lysozyme, P. P. Borbat, H. S. Mchaourab, and J. H. Freed, J. Am. Chem. Soc. 124, 19, 5304-5314 (2002). 283. Domain Flexibility in Ligand-Free and Inhibitor-Bound E. coli Adenylate Kinase Based on a Mode-Coupling Analysis of 15N Spin Relaxation, Y. E. Shapiro, E. Kahana, V. Tugarinov, Z. Liang, J. H. Freed, and E. Meirovitch, Biochemistry 41, 6271-6281 (2002). 284. Phase Relaxation in a Many-Body System of Diffusing Spins: Slow Motional Limit, A. A. Nevzorov and J. H. Freed, J. Chem. Phys. 117, 282-287 (2002). 285. Modern ESR Methods in Studies of the Dynamic Structure of Proteins and Membranes, J. H. Freed, EPR in the 2lst. Century, A. Kawamori, J. Yamauchi, and H. Ohta, Eds., Elsevier Science: Amsterdam, Netherlands, 719730 (2002).

286. Variable-Frequency EPR Study of Mn2+-doped NH4Cl0.9I0.1 Single Crystal at 9.6, 36, and 249.9 GHz: Structural Phase Transition, S. K. Misra, S. I. Andronenko, G. Rinaldi, P. Chand, K. A. Earle, and J. H. Freed, J. Magn. Res. 160, 131-138, (2003). 287. A 2D-ELDOR Study of the Liquid Ordered Phase in Multilamellar Vesicle Membranes, A. J. Costa-Filho, Y. Shimoyama, and J. H. Freed, Biophys. J. 84, 26192633, (2003). 288. Lipid-Gramicidin Interactions: Dynamic Structure of the Boundary Lipid by 2D-ELDOR, A. J. Costa-Filho, R. H. Crepeau, P. P. Borbat, M. Ge, and J. H. Freed, Biophys. J. 84, 3364-3378 (2003). 289. End to End Correlation for a C12 Hydrocarbon Chain, S. Wagner, A. Nevzorov, J. H. Freed, R. G. Bryant, J. Magn. Res. 160, 161-165 (2003). 290. Ordered and Disordered Phases Coexist in Plasma Membrane Vesicles of RBL-2H3 Mast Cells. An ESR Study, M. Ge, A. Gidwani, H. Alex Brown, D. Holowka, B. Baird, and J. H. Freed, Biophys. J. 85, 1278-1288 (2003). 291. ESR and Molecular Dynamics. J. H. Freed, in Biomedical ESR, S. S. Eaton, G. R. Eaton, and L. J. Berliner, Eds., Kluwer: New York, in press. 292. Hydration, Structure, and Molecular Interactions in the Headgroup Region of Dioleoylphosphatidylcholine Bilayers: An ESR Study. M. Ge and J. H. Freed, Biophys. J. 85, 4023-4044 (2003). 293. Mode-coupling Analysis of 15N CSA-15N-1H Dipolar Cross-correlated Relaxation in Proteins, E. Meirovitch, Y. E. Shapiro, V. Tugarinov, Z. Liang, and J. H. Freed, J. Phys. Chem. B 107, 9883-9897 (2003). 294. Mode-coupling N-H Bond Dynamics: Mode-mixing, Renormalization and Rhombic Potentials. Implications for Data Analysis, E. Meirovitch, Y. E. Shapiro, Z. Liang, and J. H. Freed, J. Phys. Chem. B 107, 98989904 (2003). 295. High Resolution Electron Spin Resonance Microscopy, A. Blank, C. Dunnam, P. Borbat, and J. H. Freed, J. Magn. Res. 165, 116-127 (2003). 296. The Development of High Field/High Frequency ESR: Historical Overview, J. H. Freed in Very High Frequency ESR, Biological Magnetic Resonance Vol. 22, O. Grinberg and L. J. Berliner, Eds., Kluwer: New York (in press 2004). 297. A high-power 95 GHz pulsed ESR spectrometer, W. Hofbauer, K. A. Earle, C. R. Dunnam, J. K. Moscicki, and J. H. Freed, ReV. Sci. Instrum. 75, 1194-1208 (2004). 298. A 3D Electron Spin Resonance Microscope, A. Blank, C. R. Dunnam, P. P. Borbat, and J. H. Freed, ReV. Sci. Instrum. (submitted 2004). 299. Measurement of Large Distances in Biomolecules Using Double-Quantum-Filtered Refocused Electron-SpinEchoes, P. P. Borbat, J. H. Davis, S. E. Butcher, and J. H. Freed, J. Am. Chem. Soc. (submitted 2004). Patents 1. Aminoxyl-Containing Radical Spin Labeling in Polymers and Copolymers, Keun-Ho Lee; Chih-Chang Chu; Jack H. Freed, U.S. Patent #5,516,881; May 14, 1996. 2. Variable-Coupling Quasioptical Electron Resonance Apparatus, David E. Budil, Keith A. Earle, Jack H. Freed, James R. Anderson, U.S. Patent #6,101,0l5; August 8, 2000.