Pulse radiolysis of sodium metaphosphate glasses - The Journal of

Jan 1, 1972 - Aaron Barkatt, Michael Ottolenghi, Joseph Rabani. J. Phys. Chem. , 1972, 76 (2), pp 203–213. DOI: 10.1021/j100646a010. Publication Dat...
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PULSE RADIOLYSIS OF SODIUM METAPHOSPHATE GLASSES

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previously been shown that MPP undergoes the analogous “McLafferty rearrangement’’ in the gas phase.28 It is reasonable that biacetyl would not effectively scavenge positive ions of MPP, since the ionization potential of biacetyl (9.25-10.22 eV)29is higher than that

rials Research Center in conjunction with the Advanced Projects Research Agency (Contract No. SD-100).

of MPP (