Covestro shows off a prototype polyurethane blade in front of its research center in Shanghai.
RENEWABLES
Covestro promotes polyurethane, not epoxy, as the polymer needed to make blades bigger and lighter ALEX SCOTT, C&EN LONDON
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limate change skeptics have pointed to wind turbines as subsidy-dependent folly for decades. But that scenario is rapidly being blown away. Thanks in part to novel polymer chemistry, turbines are on track to leave the cost of electricity from fossil fuels in their shadows. Onshore wind turbines already compete with coal and gas in Europe, generating electricity at a cost between $59 and $125 per MWh, according to the European Commission. And turbines should get even more competitive as polymer chemists work to improve them by developing lighter and stronger materials that make for longer and more efficient blades. Most turbine blades are fabricated by combining epoxy resin with fiberglass in a giant mold. Typically, sheets of fiberglass are laid over a balsa wood frame to create top and bottom halves of the blade. The halves are sealed together like a clamshell and then impregnated with epoxy and its hardening agent at about 70 °C to aid the reaction. But Covestro, the former plastics business of Bayer and the inventor of polyurethane, claims its polyurethane resin is stronger than epoxy and thus more suitable for manufacturing large turbine blades. Not surprisingly, epoxy resin makers beg to differ. Thanks partly to the continual develop-
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C&EN | CEN.ACS.ORG | JULY 24, 2017
ment of epoxy materials, blades have doubled in size since the 1980s, extending to a length today of about 95 meters. This blade growth significantly increased turbine output and efficiency. For example, extending the length of a blade from 60 to 80 meters more than doubles power output from 4.1 to about 9.5 MW. A single large turbine can power about 2,400 homes compared with a 60-meter-blade turbine’s 900 homes. Making a blade out of polyurethane requires 10% less material than for a blade of the same strength made from epoxy, claims Covestro’s chief executive officer, Patrick Thomas. Less material can mean lighter blades that are more efficient because they need less wind to turn them. The polyurethane blades are also cheaper, Thomas says, which is important given that blades constitute about 30% of total wind turbine manufacturing cost. And the sales potential is huge. Covestro estimates that 300,000 metric tons of polymer are used to make wind turbine blades every year. Today, estimates market research firm MarketsandMarkets, about 82% of blades are made with epoxy resin
composites, with polyester composites taking 14% and vinyl ester 2%. Polyurethane and all other resins account for the rest. The polymer market for turbine blades is set to rise by more than 9% annually, MarketsandMarkets forecasts. Kim Klausen, who heads Covestro’s wind energy program and runs the firm’s wind technology center in Denmark, argues that over the next five years, polyurethane—not epoxy—will be the better option to enable the turbine industry to make longer blades. Today, the longest blades are 95 meters, but soon they will be 120 meters, Klausen says. “The superior mechanical and fatigue properties of polyurethane will make it easier to design and produce such long blades,” he says. In addition to proposing polyurethane as the main structural material for turbine blades, Covestro has developed a polyurethane elastomer coating that can protect blades against damage caused by raindrops, which can hit the windward edge of the blades at almost the speed of sound. In a testing chamber in Denmark, Covestro has determined that its new elastomeric polyurethane coating can withstand 20 hours of simulated high-speed raindrops, compared with two hours for a standard coating. Twenty hours in the simulator equate to about 20 years of life on large offshore turbines. Current blades have to be repaired every couple of years, Klausen says. Another benefit of polyurethane, Covestro claims, is that the resin can significantly increase productivity at blade factories. Covestro says the viscosity of its poly-
C R E D I T: COV EST RO
Pushing wind turbine blades toward 200 meters
Although Covestro contends that urethane is one-sixth that of standard polyurethane is the most cost-effective epoxy, meaning that the resin can be inmaterial with which to make wind turbine fused faster in giant turbine molds. The blades, epoxy producers such as Dow resin also cures faster than epoxy and at a Chemical and Huntsman Corp. are not significantly lower temperature. All in all, about to roll over. polyurethane provides a notable reduction in production time, Klausen “The customer feedback says, a major advantage givwe are hearing, in particThe ratio of electricity en the vast amount of space ular with regard to large generated to length of needed to mold each blade. blades of between 50 and blade increases with A challenge for Coves80 meters in length, is that rotor diameter, making tro, though, is that with ◼ 9.5 large turbines more lower resin viscosity and ◼ 165 ◼ 4.1 eicient. Diameters faster curing time, turbine ◼ 119 are now approaching production processes also ◼ 2.9 190 meters. ◼ 94 have to change. European ◼ 3.0 turbine producers are loath ◼ 90 to move away from their ◼ 1.6 existing systems, Klausen ◼ 69 laments. “Here we see a big difference in Chinese culture, as Chinese firms are far more open to new thinking,” says Klausen, who has been working with Chinese turbine manufacturers. Luckily for Covestro, China is the world’s biggest market, accounting for 43% ◼ Capacity, MW ◼ Rotor diameter, meters of the world’s new turbines last year. Sources: Ars Technica, Windpower Monthly
Turbine evolution
epoxy is the best material for the job,” says Dietmar Leibrock, Huntsman’s European sales leader for the wind industry. “If demand for large blades continues, then we believe epoxy will remain an important material of choice.” MarketsandMarkets also predicts that epoxy will continue to be the blade material of choice. Even from its small base level, polyurethane use in wind turbines will grow more slowly than the overall market through 2021, it forecasts. While Covestro tries to carve out a place for polyurethane in the wind turbine market, it’s also looking a decade or more ahead when turbine blades approach 200 meters in length and will likely require a whole new set of materials. At this scale, carbon fiber will need to replace fiberglass to attain the stiffness necessary to keep blades from bending and hitting the turbine tower, Klausen observes. And much research will be required into how resins—be they polyurethane or epoxy—interact with the new fiber. Covestro, Klausen says, is already working on it. ◾
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JULY 24, 2017 | CEN.ACS.ORG | C&EN
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