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For comparison purposes, data on the decomposition of some sulfonyl radicals reported by other workers are listed in Table I together with our results...
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Notes 339

Vol. 12, No. 2, March-April 1979 Table I

Activation Energies for the Decomposition of Some Sulfonyl Radicals activation energy, kcal/mol

sulfonyl radical

CH,S0,.9 CH;CH;SO,. I CH,CH(CI)SO,.~ PhCH,SO;lS CH, = CHCH, S O , . ~ S

22.4 * 1.8 19.9 13.4 * 2.0 12.0 f 3.2 8.4 i 3.2

A E , a kcal/mol

20.0

i

A. Good and J. C. J. Thynne, Trans. Faraday SOC.,63, 2720 (1967). W. K. Busfield, K.