Radiation chemistry of aqueous solutions of dicyandiamide - The

Radiation chemistry of an aqueous solution of glycine: compounds of interest to chemical evolution studies. Z. D. Draganić , V. Niketić , S. I. Vujo...
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The Journal of Physical Chemistry, Vol. 83, No.

2, 1979

K. R. Sharma and R. M. Noyes, J. Am. Chem. Soc., 97, 202 (1975). K. R. Sharma and R. M. Noyes, J. Am. Chem. Soc., 98,4345 (1976). B. L. Clarke, private communication. D. Edelson, R. J. Field, and R. M. Noyes, Int. J . Chem. Kinet., 5, 417 (1975). D. Edelson, R. M. Noyes, and R. J. Field, Int. J . Chem. Kinet., in press. Supplemental materials from ref 4. R. M. Noyes and R. J. Field, Acc. Chem. Res., 10, 273 (1977). R. M. Noyes, J . Phys. Chem., 81, 2315 (1977).

Z. D. DraganiS, I. G. DraganiE, and K. Sehested (11) W. M. Latimer, "Oxidation Potentlals", 2nd ed, Prentice-Hall, New York, 1952. (12) J. Zimmerman and R. M. Noyes, J. Chem. Phys., 18, 658 (1950). (13) M. Gazith and R. M. Noyes, J . Am. Chem. Soc., 77, 6091 (1955). (14) R. J. Field and R. M. Noyes, Acc. Chem. Res., 10, 214 (1977). (15) B. L. Clarke, J . Chem. Phys., 64, 4165 (1976). (16) R. J. Field and R. M. Noyes, J . Chem. Phys., 60, 1877 (1974). (17) "EncyclQpediaBritannica" Vol. 18, 1970, p 587. (18) A. C. Zettlernoyer, "Nucleation", Marcel Dekker, New York, 1969.

Radiation Chemistry of Aqueous Solutions of Dicyandiamide 2. D. Dragani6,* I. G. Dragani6, and K. Sehested Boris KidriE Institute of Nuclear Sciences, Beograd 1100 1, Yugoslavia (Received March 2, 1978)

Oxygen-free aqueous solutions of dicyandiamide, DCDA, were exposed to 6oCoy rays or a pulsed 10-MeVelectron beam. Fast kinetic spectrophotometry was used for the study of free-radical intermediates, and computer simulation of the reaction mechanism for evaluation of experimental data. The hydrated electron reacts by addition, k(e,,- + DCDA) = 1.1 X 1O'O M-ls- l; t he anion radical [NH,C(=NH)NHCN]- absorbs in the UV region with, , ,A