Reaction of dialkali salts of benzoylacetone with 2-chloroquinoline

Evidence for an SRN1 mechanism in heteroaromatic nucleophilic substitution. James Carson. Greene, James F. Wolfe, and Thomas. Hudlicky. J. Org. Chem...
0 downloads 0 Views 167KB Size
Commzlnicatzbns See Editorial. J . Ora. Chem.. 87. No. 19. 4A (1872)

Reaction of Dialkali Salts of Benzoylacetone with 2-Chloroquinoline. Evidence for a n SRNl RIechanism in Heteroaromatic Nucleophilic Substitution'

Suninzayy: Dialkali metal salts of benzoylacetone have

3

been found t o react with 2-chloroquinoline in liquid ammonia to produce l-phenyl-4-(2-quinolyl)-1,3- 2-chloroquinoline was allowed to react with 2 mol equiv butanedione by a radical-chain mechanism. of dialliali salts 1 (11 = I