Recent references on reactions of ACETONE CYANOHYDRIN - C&EN

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Recent references on reactions of

ACETONE CYANOHYDRIN A . Reactions of the C N Group CH 3 I CH3-C-CN I OH

CH 3 H 2 SO, CH2 = C - C 0 N H 2 Methacrylamide

CH 3 I CH3-C-CN I OH

CH 3 I CH3-C-CH2NH2 I OH /sobufano/am/ne

H3

B. Reactions of the O H CH 3 1 CH3-C-CN

J. O r g . Chem., 73,427 ( 7 9 4 8 ;

Brit. 598,984

CH 3 I CH3-C-CN I OH

2,

1948)

Group

CH3 I PCI 5 CICH; CHCN beta-chloroisobutyronitrile

OH

(Mar.

JACS, 70,165

(1948)

CH 3 NH — •

CH3-C-CN 1 NH 2 alpha-aminoisobutyronitrile

JACS, 68,2628

(1946)

Acetone cyanohydrîn is available in commercial quantities from the Rohm & H a a s Company. It is supplied in a technical g r a d e with a purity of 9 7 - 9 8 % , boiling a t 8 2 ° C . at 2 3 mm, and freezing at — 1 9 ° C. In g e n e r a l , its solubility is similar to tert.-butyl alcohol. THE FOLLOWING ACETONE

ESTERS, MANUFACTURED

CYANOHYDRIN,

COMMERCIAL

FROM

ARE ALSO AVAILABLE

QUANTITIES

OTHER ORGANIC CHEMICALS AVAILABLE IN COMMERCIAL QUANTITIES:

IN

.

HYDROXYISOBUTYRATES

CH3-C-COOR

ACRYIATE ESTERS

(R =

OH

! OCTYLPHENOXYETHOXYETHYL CHLORIDE C8H1

CH3

METHACRYLATES

CH 2 Ν Η X 1 C = $ CH2-NH/ CH, = CHCO0R

ETHYLENE THIOUREA

ΓΗ, I

1

CH2 = C-CO0R

7

^

OCTYLPHENOXYETHANOLS C 8 H, 7 1

For samples, prices, and literature

ROHM

SQUARE,

of these chemicals, write

>

(0C2H4)x0H

to Dept.

SP.

COMPANY

PHILADELPHIA

of Chemicals including Plastics · Synthetic Ir Chemicals for the Leather, Textile, Ceramic,

0C2H40C2H4CI

(X = l, 3 and 5)

& HAAS WASHINGTON

Manufacturers Germicides

on any

>

CH3,C2H5)

5,

PA.

» · Fungicides · Enzymes · Detergents Paper-, Petroleum and other» Industries