Recent Reviews. 59 - American Chemical Society

59 compiled by Veronica M. Cornel. Department of Chemistry, Reedley College, 339 West Carpenter Avenue, Reedley, California 93654 [email protected]...
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J. Org. Chem. 2001, 66, 352-362

Recent Reviews. 59 compiled by Veronica M. Cornel Department of Chemistry, Reedley College, 339 West Carpenter Avenue, Reedley, California 93654 [email protected]

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews that fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index. Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted. This installment of Recent Reviews covers principally the middle part of the 2000 literature. Previous installment: J. Org. Chem. 2000, 65(20), 6798-806. Supporting Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in rtf format. This material is available free of charge via the Internet at http://pubs.acs.org.

Regularly Issued Journals and Series Volumes Accounts of Chemical Research 1. Mikami, K.; Terada, M.; Korenaga, T.; Matsumoto, Y.; Matsukawa, S. Enantiomer-Selective Activation of Racemic Catalysts. 2000, 33(6), 391-401. 2. Ikeda, S.-i. Nickel-Catalyzed Intermolecular Domino Reactions. 2000, 33(8), 511-9. 3. Schlichting, I. Crystallographic Structure Determination of Unstable Species. 2000, 33(8), 532-8. 4. Toy, P. H.; Janda, K. D. Soluble Polymer-Supported Organic Synthesis. 2000, 33(8), 546-54. 5. Bagno, A.; Scorrano, G. Selectivity in Proton Transfer, Hydrogen Bonding, and Solvation. 2000, 33(9), 60916. 6. Hamers, R. J.; Coulter, S. K.; Ellison, M. D.; Hovis, J. S.; Padowitz, D. F.; Schwartz, M. P.; Greenlief, C. M.; Russell, J. N., Jr. Cycloaddition Chemistry of Organic Molecules with Semiconductor Surfaces. 2000, 33(9), 617-24. 7. Okazaki, R.; Tokitoh, N. Heavy Ketones, the Heavier Element Congeners of a Ketone. 2000, 33(9), 625-30. 8. Turro, N. J. From Boiling Stones to Smart Crystals: Supramolecular and Magnetic Isotope Control of Radical-Radical Reactions in Zeolites. 2000, 33(9), 63746. 9. Garcia, J. I.; Mayoral, J. A.; Salvatella, L. Do Secondary Orbital Interactions Really Exist? 2000, 33(10), 658-64. 10. Buncel, E.; Clement, O.; Onyido, I. Metal Ion Effects in Isotopic Hydrogen Exchange in Biologically Important Heterocycles. 2000, 33(10), 672-8. 11. Nishimura, J.; Nakamura, Y.; Hayashida, Y.; Kudo, T. Stereocontrol in Cyclophane Synthesis: A Photochemical Method to Overlap Aromatic Rings. 2000, 33(10), 679-86.

12. Terazima, M. Is the Translational Diffusion of Organic Radicals Different from that of Closed-Shell Molecules? 2000, 33(10), 687-94. 13. Guldi, D. M.; Prato, M. Excited-State Properties of C60 Fullerene Derivatives. 2000, 33(10), 695-703. 14. Haaf, M.; Schmedake, T. A.; West, R. Stable Silylenes. 2000, 33(10), 704-14. 15. Beak, P.; Anderson, D. R.; Curtis, M. D.; Laumer, J. M.; Pippel, D. J.; Weisenburger, G. A. Dynamic Thermodynamic Resolution: Control of Enantioselectivity Through Diastereomeric Equilibration. 2000, 33(10), 715-27. 16. Borden, W. T.; Gritsan, N. P.; Hadad, C. M.; Karney, W. L.; Kemnitz, C. R.; Platz, M. S. The Interplay of Theory and Experiment in the Study of Phenylnitrene. 2000, 33(11), 765-71. 17. Franz, A. K.; Woerpel, K. A. Development of Reactions of Silacyclopropanes as New Methods for Stereoselective Organic Synthesis. 2000, 33(11), 81320. Advances in Heterocyclic Chemistry 18. Elguero, J.; Katritzky, A. R.; Denisko, O. V. Prototropic Tautomerism of Heterocycles: Heteroaromatic TautomerismsGeneral Overview and Methodology. 2000, 76, 1-84. 19. Friedrichsen, W.; Traulsen, T.; Elguero, J.; Katritzky, A. R. Tautomerism of Heterocycles: Five-Membered Rings with One Heteroatom. 2000, 76, 85-156. 20. Minkin, V. I.; Garnovskii, A. D.; Elguero, J.; Katritzky, A. R.; Denisko, O. V. The Tautomerism of Heterocycles: Five-Membered Rings with Two or More Heteroatoms. 2000, 76, 157-323.

10.1021/jo004012e CCC: $20.00 © 2001 American Chemical Society Published on Web 01/05/2001

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21. Claramunt, R. M.; Elguero, J.; Katritzky, A. R. Tautomerism Involving Other Than Five- and SixMembered Rings. 2000, 77, 1-50. 22.S hcherbakova, I.; Elguero, J.; Katritzky, A. R. Tautomerism of Heterocycles: Condensed Five-Six, FiveFive, and Six-Six Ring Systems with Heteroatoms in Both Rings. 2000, 77, 51-113. Aldrichimica Acta 23. Babu, G.; Perumal, P. T. Synthetic Applications of Indium Trichloride Catalyzed Reactions. 2000, 33(1), 1622. 24. Comasseto, J. V.; Barrientos-Astigarraga, R. E. Add a Little Tellurium to Your Synthetic Plans! 2000, 33(2), 66-78. Angewandte Chemie, International Edition in English 25. Machajewski, T. D.; Wong, C.-H.; Lerner, R. A. The Catalytic Asymmetric Aldol Reaction. 2000, 39(8), 135274. 26. Sierra, M. A.; De la Torre, M. C. Dead Ends and Detours en route to Total Syntheses of the 1990s. 2000, 39(9), 1538-59. 27. Lash, T. D. Giant Porphyrinoids: From Figure Eights to Nanomolecular Cavities. 2000, 39(10), 17637. 28. Katz, T. J. Syntheses of Functionalized and Aggregating Helical Conjugated Molecules. 2000, 39(11), 1921-3. 29. Piers, W. E. B-H Bond Activations in the Alkane Analogues H3B‚PR3. 2000, 39(11), 1923-5. 30. Hoffmann, R. W. Conformation Design of OpenChain Compounds. 2000, 39(12), 2055-70. 31. Maier, M. E. Synthesis of Medium-Sized Rings by the Ring-Closing Metathesis Reaction. 2000, 39(12), 2073-7. 32. Zaragoza, F. New Sulfur- and Selenium-Based Traceless Linkers - More Than Just Linkers? 2000, 39(12), 2077-9. 33. Carrea, G.; Riva, S. Properties and Synthetic Applications of Enzymes in Organic Solvents. 2000, 39(13), 2226-54. 34. Siemsen, P.; Livingston, R. C.; Diederich, F. Acetylenic Coupling: A Powerful Tool in Molecular Construction. 2000, 39(15), 2632-57. 35. Gade, L. H. Highly Polar Metal-Metal Bonds in “Early-Late” Heterodimetallic Complexes. 2000, 39(15), 2658-78. 36. Furstner, A. Olefin Metathesis and Beyond. 2000, 39(17), 3012-43. 37. Langer, P. New Strategies for the Development of an Asymmetric Version of the Baylis-Hillman Reaction. 2000, 39(17), 3049-52. Canadian Journal of Chemistry 38. Girard, C.; Kagan, H. B. On Diastereomeric Perturbations. 2000, 78(6), 816-28. 39. Ratovelomanana-Vidal, V.; Genet, J.-P. Synthetic Applications of the Ruthenium-Catalyzed Hydrogenation via Dynamic Kinetic Resolution. 2000, 78(6), 846-51.

40. Franzen, R. The Suzuki, the Heck, and the Stille Reaction; Three Versatile Methods for the Introduction of New C-C Bonds on Solid Support. 2000, 78(7), 95762. Chemical Reviews 41. Chinchilla, R.; Najera, C. Acylvinyl and Vinylogous Synthons. 2000, 100(6), 1891-928. 42. Casiraghi, G.; Zanardi, F.; Appendino, G.; Rassu, G. The Vinylogous Aldol Reaction: A Valuable, Yet Understated Carbon-Carbon Bond-Forming Maneuver. 2000, 100(6), 1929-72. 43. Burgess, K.; Cook, D. Syntheses of Nucleoside Triphosphates. 2000, 100(6), 2047-59. 44. Guillier, F.; Orain, D.; Bradley, M. Linkers and Cleavage Strategies in Solid-Phase Organic Synthesis and Combinatorial Chemistry. 2000, 100(6), 2091-157. 45. Fache, F.; Schulz, E.; Tommasino, M. L.; Lemaire, M. Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis. 2000, 100(6), 2159-231. 46. Faul, M. M.; Huff, B. E. Strategy and Methodology Development for the Total Synthesis of Polyether Ionophore Antibiotics. 2000, 100(6), 2407-73. 47. de Meijere, A. Organometallics in Organic Synthesis: Introduction. 2000, 100(8), 2739-40. 48. van Leeuwen, P. W. N. M.; Kamer, P. C. J.; Reek, J. N. H.; Dierkes, P. Ligand Bite Angle Effects in Metalcatalyzed C-C Bond Formation. 2000, 100(8), 2741-69. 49. Gansaeuer, A.; Bluhm, H. Reagent-Controlled Transition-Metal-Catalyzed Radical Reactions. 2000, 100(8), 2771-88. 50. Kulinkovich, O. G.; de Meijere, A. 1,n-Dicarbanionic Titanium Intermediates from Monocarbanionic Organometallics and Their Application in Organic Synthesis. 2000, 100(8), 2789-834. 51.S ato, F.; Urabe, H.; Okamoto, S. Synthesis of Organotitanium Complexes from Alkenes and Alkynes and Their Synthetic Applications. 2000, 100(8), 283586. 52. Marek, I. Synthesis and Reactivity of sp2 Geminated Organobismetallic Derivatives. 2000, 100(8), 2887900. 53. Saito, S.; Yamamoto, Y. Recent Advances in the Transition-Metal-Catalyzed Regioselective Approaches to Polysubstituted Benzene Derivatives. 2000, 100(8), 290115. 54. Pape, A. R.; Kaliappan, K. P.; Kuendig, E. P. Transition-Metal-Mediated Dearomatization Reactions. 2000, 100(8), 2917-40. 55. Knoelker, H.-J. Efficient Synthesis of Tricarbonyliron-Diene Complexes - Development of an Asymmetric Catalytic Complexation. 2000, 100(8), 2941-61. 56. Yet, L. Metal-Mediated Synthesis of Medium-Sized Rings. 2000, 100(8), 2963-3007. 57. Beletskaya, I. P.; Cheprakov, A. V. The Heck Reaction as a Sharpening Stone of Palladium Catalysis. 2000, 100(8), 3009-66. 58. Zimmer, R.; Dinesh, C. U.; Nandanan, E.; Khan, F. A. Palladium-Catalyzed Reactions of Allenes. 2000, 100(8), 3067-125. 59. Li, C.-L.; Liu, R.-S. Synthesis of Heterocyclic and Carbocyclic Compounds via Alkynyl, Allyl, and Propargyl Organometallics of Cyclopentadienyl Iron, Molybdenum, and Tungsten Complexes. 2000, 100(8), 3127-61.

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60. Marshall, J. A. Synthesis and Reactions of Allylic, Allenic, Vinylic, and Arylmetal Reagents from Halides and Esters via Transient Organopalladium Intermediates. 2000, 100(8), 3163-85. 61. Luh, T.-Y.; Leung, M.-k.; Wong, K.-T. Transition Metal-Catalyzed Activation of Aliphatic C-X Bonds in Carbon-Carbon Bond Formation. 2000, 100(8), 3187204. 62. Kondo, T.; Mitsudo, T.-a. Metal-Catalyzed CarbonSulfur Bond Formation. 2000, 100(8), 3205-20. 63. Suginome, M.; Ito, Y. Transition-Metal-Catalyzed Additions of Silicon-Silicon and Silicon-Heteroatom Bonds to Unsaturated Organic Molecules. 2000, 100(8), 3221-56. 64. Smith, N. D.; Mancuso, J.; Lautens, M. MetalCatalyzed Hydrostannations. 2000, 100(8), 3257-82. 65. An, H.; Cook, P. D. Methodologies for Generating Solution-Phase Combinatorial Libraries. 2000, 100(9), 3311-40. 66. Fritz, G.; Scheer, P. Silylphosphanes: Developments in Phosphorus Chemistry. 2000, 100(9), 3341-401. 67. Bonjoch, J.; Sole, D. Synthesis of Strychnine. 2000, 100(9), 3455-82. 68. Braunstein, P.; Morise, X. Dehydrogenative Coupling of Hydrostannanes Catalyzed by Transition-Metal Complexes. 2000, 100(10), 3541-52. 69. Sierra, M. A. Di- and Polymetallic Heteroatom Stabilized (Fischer) Metal Carbene Complexes. 2000, 100(10), 3591-637. 70. Vespalec, R.; Bocek, P. Chiral Separations in Capillary Electrophoresis. 2000, 100(10), 3715-53. 71. Pogliani, L. From Molecular Connectivity Indices to Semiempirical Connectivity Terms: Recent Trends in Graph Theoretical Descriptors. 2000, 100(10), 3827-58. 72. Brutschy, B. The Structure of Microsolvated Benzene Derivatives and the Role of Aromatic Substituents. 2000, 100(11), 3891-920. Chemistry - A European Journal 73. Dembech, P.; Seconi, G.; Ricci, A. The Electrophilic Amination of Carbanions: an Unconventional New Entry to C-N Bond Formation. 2000, 6(8), 1281-6. 74. Joy, A.; Ramamurthy, V. Chiral Photochemistry within Zeolites. 2000, 6(8), 1287-93. 75. Breit, B. Controlling Stereoselectivity with the Aid of a Reagent-directing Group: Hydroformylation, Cuprate Addition, and Domino Reaction Sequences. 2000, 6(9), 1519-24. 76. Limberg, C. On the Trail of CrO2Cl2 in its Reactions with Organic Compounds. 2000, 6(12), 2083-9. 77. MacLachlan, M. J.; Asefa, T.; Ozin, G. A. Writing on the Wall with a New Synthetic Quill. 2000, 6(14), 2507-11. 78. Rudkevich, D. M. Intramolecular Hydrogen Bonding in Calixarenes. 2000, 6(15), 2679-86. Chemistry in Britain 79. Kee, T. Taming a Chemical Shrew. 2000, 36(8), 25. CHEMTRACTS: Organic Chemistry 80. Franz, D. E.; Fassler, R.; Carreira, E. M.; Am, J. Catalytic in situ Generation of Zn(II)-Alkynilides Under Mild Conditions: A Novel C:N Addition Process Utilizing Terminal Acetylenes. Facile Enantioselective Synthesis

Recent Reviews

of Propargylic Alcohols by Direct Addition of Terminal Alkynes to Aldehydes. 2000, 13(7), 427-30. 81. Yamaguchi, M.; Tsukagoshi, T.; Arisawa, M. Ethenylation of Silyl Enol Ethers with Silylethyne. 2000, 13(7), 431-4. 82. Rosa, J. C.; Galanakis, D.; Piergentili, A.; Bhandhari, R.; Gonellin, C. R.; Dunn, P. M.; Jenkinson, D. H. Synthesis, Molecular Modeling, and Pharmacological Testing of bis-Quinolinium Cyclophanes: Potent, Nonpeptidic Blockers of the Apamin-Sensitive Ca2+-Activated K+ Channel. 2000, 13(7), 439-42. 83. Meutermans, W. D. F.; Golding, S. W.; Bourne, G. T.; Miranda, L. P.; Dooley, M. J.; Alewood, P. F.; Smythe, M. L. Synthesis of Difficult Cyclic Peptides by Inclusion of a Novel Photolabile Auxiliary in a Ring Contraction Strategy. 2000, 13(7), 443-6. 84. Barness-Seeman, D.; Nicolaou, K. C.; Jautelat, R.; Vassilikogiannakis, G.; Boran, P. S.; Simonsen, K. B. The Synthesis of Bisorbicillinoids. An Amazing Self-Assembly of Simple Compounds into Highly Complex Natural Products. 2000, 13(7), 456-63. 85. Lee, W.; Li, Z. H.; Vakulenko, S.; Mosbashery, S. A Light-Inactivated Antibiotic. 2000, 13(7), 464-9. 86. Rozen, S.; Dayan, S. At Last, 1,10-PhenanthrolineN,N′-dioxide, A New Type of Helicene, has been Synthesized using HOF‚MeCN. 2000, 13(7), 475-6. 87. Beier, M.; Hoheisel, J. D. Production by Quantitative Photolithographic Synthesis of Individually Quality Checked DNA Microarrays. 2000, 13(7), 487-90. 88. Jia, C.; Piao, D.; Oyamada, J.; Lu, W.; Kitamura, T.; Fujiwara, Y. Efficient Activation of Aromatic C-H Bonds for Addition to C-C Multiple Bonds. 2000, 13(7), 491-501. Chinese Journal of Chemistry 89. Wang, D. Asymmetric Allylation of Aldehydes and Alkylation using Carbon-Centered Chiral Organosilicon Compounds. 1999, 17(5), 429-37. 90. Li, P.; Xu, J.-C. Highly Efficient Synthesis of Peptides by Rational Utilization of Novel Coupling Reagents. 2000, 18(4), 456-66. Coordination Chemistry Reviews 91. Hubin, T. J.; Busch, D. H. Template Routes to Interlocked Molecular Structures and Orderly Molecular Entanglements. 2000, 200-2, 5-52. 92. Costas, M.; Chen, K.; Que, L. Biomimetic NonHeme Iron Catalysts for Alkane Hydroxylation. 2000, 200-2, 517-44. 93. Carmona, D.; Pilar Lamata, M.; Oro, L. A. Recent Advances in Homogeneous Enantioselective Diels-Alder Reactions Catalyzed by Chiral Transition-Metal Complexes. 2000, 200-2, 717-72. 94. Grimes, R. N. Metallacarboranes in the New Millennium. 2000, 200-2, 773-811. 95. Hubig, S. M.; Lindeman, S. V.; Kochi, J. K. ChargeTransfer Bonding in Metal-Arene Coordination. 2000, 200-2, 831-73. 96. Gray, H. B.; Winkler, J. R.; Wiedenfeld, D. Effects of Driving Force on the Rates of Intramolecular and Bimolecular Electron-Transfer Reactions. 2000, 200-2, 875-86.

Recent Reviews

97. Vogler, A.; Kunkely, H. Excited-State Properties of Organometallic Compounds of Rhenium in High and Low Oxidation States. 2000, 200-2, 991-1008. 98. Gyurcsik, B.; Nagy, L. Carbohydrates as Ligands: Coordination Equilibria and Structure of the Metal Complexes. 2000, 203, 81-149. 99. Abd-El-Aziz, A. S.; Bernardin, S. Synthesis and Reactivity of Arenes Coordinated to Cyclopentadienyliron Cations. 2000, 203, 219-67. 100. Paul, F. Catalytic Synthesis of Isocyanates or Carbamates from Nitroaromatics Using Group VIII Transition Metal Catalysts. 2000, 203, 269-323. 101. Mecking, S. Cationic Nickel and Palladium Complexes with Bidentate Ligands for the C-C Linkage of Olefins. 2000, 203, 325-51. 102. Hegedus, L. S. Transition Metals in Organic Synthesis: Highlights for the Year 1998 (25th Anniversary). 2000, 204, 199-307. 103. Fabbrizzi, L.; Licchelli, M.; Rabaioli, G.; Taglietti, A. The Design of Luminescent Sensors for Anions and Ionisable Analytes. 2000, 205, 85-108. Current Organic Chemistry 104. Martinez, C. A.; Stewart, J. D. Cytochrome P450’s: Potential Catalysts for Asymmetric Olefin Epoxidations. 2000, 4(3), 263-82. 105. Seoane, G. Enzymatic C-C Bond-Forming Reactions in Organic Synthesis. 2000, 4(3), 283-304. 106. Dias, L. C. Chiral Lewis Acid-Catalyzed Ene Reactions. 2000, 4(3), 305-42. 107. Harper, J. B.; Easton, C. J.; Lincoln, S. F. Cyclodextrins to Increase the Utility of Enzymes in Organic Synthesis. 2000, 4(4), 429-54. 108. Vogel, P. Synthesis of Rare Carbohydrates and Analogues Starting from Enantiomerically Pure 7-Oxabicyclo[2.2.1]heptyl Derivatives (“Naked Sugars”). 2000, 4(5), 455-80. 109. Haase, W.-C.; Seeberger, P. H. Recent Progress in Polymer-Supported Synthesis of Oligosaccharides and Carbohydrate Libraries. 2000, 4(5), 481-511. 110. Chretien, F.; Moitessier, N.; Roussel, F.; Mauger, J. P.; Chapleur, Y. Carbohydrate-Based Mimics of D-MyoInositol 1,4,5-Trisphosphate. 2000, 4(5), 513-34. 111. Hansson, J.; Oscarson, S. Complex Bacterial Carbohydrate Surface Antigen Structures: Syntheses of KDO- and Heptose-Containing Lipopolysaccharide Core Structures and Anomerically Phosphodiester-Linked Oligosaccharide Structures. 2000, 4(5), 535-64. 112. Jorgensen, M.; Hadwiger, P.; Madsen, R.; Stutz, A. E.; Wrodnigg, T. M. Olefin Metathesis in Carbohydrate Chemistry. 2000, 4(6), 565-88. 113. Smoliakova, I. P. Synthesis of C-Glycosylic Compounds using Three-Membered Cyclic Intermediates. 2000, 4(6), 589-608. 114. El Ashry, E. S. H.; Rashed, N. Carbohydrate Hydrazones and Osazones as Organic Raw Materials for Nucleosides and Heterocycles. 2000, 4(6), 609-51. 115. Grivas, S. 2,1,3-Benzoselenadiazoles as Valuable Synthetic Intermediates. 2000, 4(7), 707-26. European Journal of Organic Chemistry 116. Karigiannis, G.; Papaioannou, D. Structure, Biological Activity and Synthesis of Polyamine Analogs and Conjugates. 2000, 10, 1841-63.

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117. Sankararaman, S.; Nesakumar, J. E. Highly Selective Synthetic Transformations Catalyzed by Lithium Perchlorate in Organic Media. 2000, 11, 2003-11. 118. Degl’Innocenti, A.; Capperucci, A. Organosilaneinduced Synthesis and Functionalization of Sulfurcontaining Compounds. 2000, 12, 2171-86. 119. Ranu, B. C. Indium Metal and its Halides in Organic Synthesis. 2000, 13, 2347-56. 120. Masse, C. E.; Morgan, A. J.; Adams, J.; Panek, J. S. Syntheses and Biological Evaluation of (+)-Lactacystin and Analogs. 2000, 14, 2513-28. 121. Abellan, T.; Chinchilla, R.; Galindo, N.; Guillena, G.; Najera, C.; Sansano, J. M. Glycine and Alanine Imines as Templates for Asymmetric Synthesis of R-Amino Acids. 2000, 15, 2689-97. 122. Galli, C.; Mandolini, L. The Role of Ring Strain on the Ease of Ring Closure of Bifunctional Chain Molecules. 2000, 18, 3117-25. Heterocycles 123. Csende, F.; Stajer, G. 4- and 5-Oxocarboxylic Acids as Versatile Synthons for the Preparation of Heterocycles. 2000, 53(6), 1379-419. 124. Ostrovskii, V. A.; Koren, A. O. Alkylation and Related Electrophilic Reactions at Endocyclic Nitrogen Atoms in the Chemistry of Tetrazoles. 2000, 53(6), 142148. 125. Sliwa, W.; Dondela, B. Cyclodextrin Host-Guest Systems Containing aza-Aromatic Moieties. 2000, 53(7), 1595-605. 126. Gromov, S. P. Ring Transformation of Pyridines and Benzo Derivatives under the Action of C-Nucleophiles. 2000, 53(7), 1607-30. 127. El-Hiti, G. A. Synthesis of Substituted Quinazolin4(3H)-ones and Quinazolines via Directed Lithiation. 2000, 53(8), 1839-68. Journal of Combinatorial Chemistry 128. Dolle, R. E. Comprehensive Survey of Combinatorial Library Synthesis: 1999. 2000, 2(5), 383-433. Journal of Fluorine Chemistry 129. Hagiwara, R.; Ito, Y. Room-Temperature Ionic Liquids of Alkylimidazolium Cations and Fluoroanions. 2000, 105(2), 221-7. Journal of Heterocyclic Chemistry 130. Van der Plas, H. C. Degenerate Ring Transformations in Heterocyclic Systems. 2000, 37(3), 427-38. 131. Bernath, G.; Stajer, G.; Fulop, F.; Sohar, P. A Retro Diels-Alder Synthetic Method. Fused-Skeleton Isoindolones and Further Saturated Hetero Polycycles. 2000, 37(3), 439-49. 132. Jager, V.; Bierer, L.; Dong, H.-Q.; Palmer, A. M.; Shaw, D.; Frey, W. New Heterocyclic Structures from Unsaturated Aldehyde Derivatives. Inhibition of R-LFucosidases. 2000, 37(3), 455-65. 133. Neier, R. A Novel Synthesis of Porphobilinogen: Synthetic and Biosynthetic Studies. 2000, 37(3), 487508. 134. Liebscher, J.; Jin, S.; Otto, A.; Woydowski, K. Synthetic Application of Chiral Pool Derived Heterocycles. 2000, 37(3), 509-18.

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135. Babaev, E. V. Fused Munchnones in Recyclization Tandems. 2000, 37(3), 519-26. 136. Hudlicky, T. Recent Progress in Efficient Syntheses of Amaryllidaceae and Morphine Alkaloids. 2000, 37(3), 535-9. 137. Schantl, J. G. Diazene-Derived Cyclic Azomethine Imines. 2000, 37(3), 541-50. 138. Fisera, L.; Ondrus, V.; Kuban, J.; Micuch, P.; Blanarikova, I.; Jager, V. Stereoselective 1,3-Dipolar Cycloadditions to Heterocyclic Compounds. 2000, 37(3), 551-66. 139. Nakagawa, M. Enantioselective Total Synthesis of Marine Alkaloids, Manzamine A and Related Compounds. 2000, 37(3), 567-81. 140. Stoller, A. D. Synthesis of New Substituted 1λ41,2,4,6-Thiatriazines. 2000, 37(3), 583-95. 141. Reissig, H.-U.; Hormuth, S.; Schade, W.; Amombo, M. O.; Watanabe, T.; Pulz, R.; Hausherr, A.; Zimmer, R. Stereoselective Syntheses of Heterocycles with Lithiated Methoxyallene. 2000, 37(3), 597-606. 142. De Kimpe, N.; De Smaele, D. Syntheses of Physiologically Active Azaheterocycles by ElectrophileInduced Cyclisation Reactions. 2000, 37(3), 607-14. 143. Queguiner, G. Efficient Synthesis of Organometallics of Pyridines, Quinolines and Diazines: New Synthetic Methodologies for Azaaromatic Biomolecules. 2000, 37(3), 615-21. 144. Mori, M. Synthesis of Heterocycles from Molecular Nitrogen as a Nitrogen Source. 2000, 37(3), 623-30. 145. Prager, R. H.; Baradarani, M. M.; Khalafy, J. Carbene and Radical Pathways in Pyrolysis of Benzisoxazolones and Benzotriazoles. 2000, 37(3), 631-7. 146. Bachi, M. D.; Korshin, E. E.; Hoos, R.; Szpilman, A. M. Synthesis and Reactions of Antimalarial Bicyclic Peroxides. 2000, 37(3), 639-46. 147. Ugi, I.; Domling, A.; Werner, B. Since 1995 the New Chemistry of Multicomponent Reactions and Their Libraries, Including Their Heterocyclic Chemistry. 2000, 37(3), 647-58. 148. Nair, V.; Sheela, K. C.; Radhakrishnan, K. V.; Vinod, A. U.; Nair, J. S.; Rajesh, C.; Treesa, P. M. Novel Heterocyclic Construction via Dipolar Cycloadditions to 1,2-Dicarbonyl Compounds. 2000, 37(3), 659-68. Journal of Physical Organic Chemistry 149. Weissbuch, I.; Kuzmenko, I.; Berfeld, M.; Leiserowitz, L.; Lahav, M. Stereochemical Studies on Chiral Systems in Two Dimensions. 2000, 13(7), 426-34. Natural Product Reports 150. Fernandez, J. J.; Souto, M. L.; Norte, M. Marine Polyether Triterpenes (up to May 1999). 2000, 17(3), 235-46. 151. Bentley, K. W. β-Phenylethylamines and the Isoquinoline Alkaloids (July 1998 to June 1999). 2000, 17(3), 247-68. 152. Scholz, U.; Winterfeldt, E. Biomimetic Synthesis of Alkaloids (1980 to 1999). 2000, 17(4), 349-66. 153. Grayson, D. H. Monoterpenoids (mid-1997 to mid1999). 2000, 17(4), 385-419. Organic Preparations and Procedures International 154. Krow, G. R.; Cannon, K. C. Synthesis of 3-Azabicyclo[3.1.0]hexanes. A Review. 2000, 32(2), 103-22.

Recent Reviews

155. Schrader, S.; Dehmlow, E. V. Hydrogen Peroxide and Air as Inexpensive Oxidants in Phase-Transfer Catalysis. A Review. 2000, 32(2), 123-52. 156. Steinig, A. G.; Spero, D. M. Amines via Nucleophilic 1,2-Addition to Ketimines. Construction of NitrogenSubstituted Quaternary Carbon Atoms. A Review. 2000, 32(3), 205-34. 157. Abele, E.; Lukevics, E. Recent Advances in the Chemistry of Oximes. 2000, 32(3), 235-64. Progress in Nuclear Magnetic Resonance Spectroscopy 158. Oliveira, F. C.; Ferreira, M. J. P.; Nunez, C. V.; Rodriguez, G. V.; Emerenciano, V. P. 13C NMR Spectroscopy of Eudesmane Sesquiterpenes. 2000, 37(1-2), 1-45. 159. Ernst, L. NMR Studies of Cyclophanes. 2000, 37(1-2), 47-190. Progress in the Chemistry of Organic Natural Products 160. Franzyk, H. Synthetic Aspects of Iridoid Chemistry. 2000, 79, 1-114. 161. Leclercq, S.; Braekman, J. C.; Daloze, D.; Pasteels, J. M. The Defensive Chemistry of Ants. 2000, 79, 115229. Pure and Applied Chemistry 162. Braz-Filho, R. Brazilian Phytochemical Diversity: Bioorganic Compounds Produced by Secondary Metabolism as a Source of New Scientific Development, Varied Industrial Applications and to Enhance Human Health and the Quality of Life. 1999, 71(9), 1663-72. 163. Bryce, M. R.; Finn, T.; Moore, A. J.; Batsanov, A. S.; Howard, J. A. K. New Redox Materials Based on Functionalized 9,10-Anthracenediylidenes. 1999, 71(11), 2137-44. 164. Ranganathan, D.; Lakshmi, C.; Haridas, V.; Gopikumar, M. Designer Cyclopeptides for Self-Assembled Tubular Structures. 2000, 72(3), 365-72. Research on Chemical Intermediates 165. Dey, G. R.; Naik, D. B.; Dwibedy, P.; Kishore, K. Pulse Radiolysis Study of Dithio-Oxamide in Aqueous Solutions. 2000, 26(4), 309-18. 166. Song, K.-S.; Liu, L.; Li, X.-S.; Guo, Q.-X. PM3 Calculations on the Complexation of R-Cyclodextrin with the Ground and Excited Quinone. 2000, 26(4), 319-25. 167. Kuzma, M.; Cerveny, L. Cinnamaldehyde Hydrogenation using Ruthenium-Tin Catalyst Type. 2000, 26(4), 347-56. 168. Grabowska, H.; Klimkiewicz, R.; Syper, L.; Wrzyszcz, J. The Catalytic Condensation of β-PhenylSubstituted Alcohols in the Presence of an Iron Oxide. 2000, 26(4), 357-64. 169. Zhao, C. X.; Qu, Y. L.; Chen, G. F. EPR Studies of “Self-Spin-Probing” Reactions Between the Carbanion of Nitroalkanes and β-Hydroperfluorodiacyl Peroxides. 2000, 26(4), 365-74. 170. Li, X.-S.; Liu, L.; Mu, T.-W.; Guo, Q.-X.; Liu, Y.C. A Theoretical Study on the Structure and Properties

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of Phenothiazine Derivatives and Their Radical Cations. 2000, 26(4), 375-84. Russian Chemical Reviews 171. Beletskaya, I. P.; Chuchurjukin, A. V. Synthesis and Properties of Functionalised Dendrimers. 2000, 69(8), 639-60. 172. Gavrilov, K. N.; Polosukhin, A. I. Chiral P,NBidentate Ligands in Coordination Chemistry and Organic Catalysis Involving Rhodium and Palladium. 2000, 69(8), 661-82. 173. Nesterov, S. V. Crown Ethers in Radiochemistry. Advances and Prospects. 2000, 69(9), 769-82. 174. Bochkarev, M. N. Arene Complexes of Rare-earth Metals. 2000, 69(9), 783-94. 175. Kochetkov, N. K. Solid-Phase Synthesis of Oligosaccharides and Glycoconjugates. 2000, 69(9), 795820. 176. Oshovsky, G. V.; Pinchuk, A. M. Heterocyclisations of Trisubstituted Formamidines Containing Aryl or Hetaryl Substituent at the Imine Nitrogen Atom. 2000, 69(10), 924-39. 177. Maksimenko, A. A.; Zakharov, A. V.; Sadekov, I. D. Monoorganyl Derivatives of Tellurium(IV). 2000, 69(10), 940-62. 178. Arslanov, V. V. Polymer Monolayers and Langmuir-Blodgett Films. Polythiophenes. 2000, 69(10), 963-80. 179. Banerjee, A. K.; Laya, M. S. Reagents for the Preparation and Cleavage of 1,3-Dithiolanes. 2000, 69(11), 1032-41. 180. Mykhalichko, B. M.; Temkin, O. N.; Mys'kiv, M. G. Polynuclear Complexes of Copper(I)halides: Coordination Chemistry and Catalytic Transformations of Alkynes. 2000, 69(11), 1042-70. Russian Journal of Organic Chemistry 181. Mokrushina, G. A.; Nosova, E. V.; Lipunova, G. N.; Charushin, V. N. Polycyclic Fluoroquinolinones. 1999, 35(10), 1413-31. 182. Lakhvich, F. A.; Koroleva, E. V. Isoxazole Derivatives in the Synthesis of Prostanoids. 1999, 35(12), 171545. 183. Chernysheva, N. A.; Gusarova, N. K.; Trofimov, B. A. Synthesis of Vinyl Sulfoxides. 2000, 36(1), 1-23. 184. Levchenko, E. S.; Markovskii, L. N.; Shermolovich, Y. G. Chemistry of Sulfonimide Acid Derivatives. 2000, 36(2), 143-57. 185. Borodkin, I.; Shubin, V. G. Structure and Dynamics of Cationic Organic π-Complexes. 2000, 36(4), 45578. Science 186. Kato, T.; Gornitzka, H.; Baceiredo, A.; Schoeller, W. W.; Bertrand, G. A Cyclic Carbanionic Valence Isomer of a Carbocation: Diphosphino Analogs of Diaminocarbocations. 2000, 289(5480), 754-6. Synlett 187. Denat, F.; Brandes, S.; Guilard, R. Strategies for the Regioselective N-Functionalization of Tetraazacycloalkanes. From Cyclam and Cyclen Towards More Sophisticated Molecules. 2000, 5, 561-74.

188. Yamada, N.; Ariga, K. Formation of β-Sheet Assemblage with a View to Developing an Amyloid Model. 2000, 5, 575-86. 189. Sato, F.; Urabe, H.; Okamoto, S. Synthetic Reactions Mediated by a Ti(OiPr)4/2 iPrMgX reagent. 2000, 6, 753-75. 190. Taylor, R. Surprises, Serendipity, and Symmetry in Fullerene Chemistry. 2000, 6, 776-93. 191. Whitcombe, M. J.; Alexander, C.; Vulfson, E. N. Imprinted Polymers: Versatile New Tools in Synthesis. 2000, 6, 911-23. 192. Yamamoto, A.; Kayaki, Y.; Nagayama, K.; Shimizu, I. Chemistry of Monoorganopalladium Complexes Relevant to Catalysis. 2000, 7, 925-37. 193. Kamikawa, K.; Uemura, M. Stereoselective Synthesis of Axially Chiral Biaryls Utilizing Planar Chiral (Arene)Chromium Complexes. 2000, 7, 938-49. 194. Stanovnik, B.; Svete, J. Alkyl 2-Substituted 3-(Dimethylamino)propenoates and Related Compounds - Versatile Reagents in Heterocyclic Chemistry. 2000, 8, 1077-91. 195. Brandt, P.; Andersson, P. G. Exploring the Chemistry of 3-Substituted 2-Azanorbornyls in Asymmetric Catalysis. 2000, 8, 1092-106. Synthesis-Stuttgart 196. Tokoroyama, T. Synthesis of Clerodane Diterpenoids and Related Compounds - Stereoselective Construction of the Decalin Skeleton with Multiple Contiguous Stereogenic Centers. 2000, 5, 611-33. 197. Lombardo, M.; Trombini, C. Nucleophilic Additions to Nitrones. 2000, 6, 759-74. 198.Arjona, O.; Csaky, A. G.; Plumet, J. Regiochemical Aspects in the Ring Opening-Cross Metathesis of Bicyclic Alkenes. 2000, 6, 857-61. 199. Shuttleworth, S. J.; Allin, S. M.; Wilson, R. D.; Nasturica, D. Functionalized Polymers in Organic Chemistry; Part 2. 2000, 8, 1035-74. 200. Kuksa, V.; Buchan, R.; Lin, P. K. T. Synthesis of Polyamines, Their Derivatives, Analogues and Conjugates. 2000, 9, 1189-207. Tetrahedron 201. Theil, F. Enhancement of Selectivity and Reactivity of Lipases by Additives. 2000, 56(19), 2905-19. 202. Baraznenok, I. L.; Nenajdenko, V. G.; Balenkova, E. S. Chemical Transformations Induced by Triflic Anhydride. 2000, 56(20), 3077-119. 203. Brummond, K. M.; Kent, J. L. Recent Advances in the Pauson-Khand Reaction and Related [2+2+1] Cycloadditions. 2000, 56(21), 3263-83. 204. Coltart, D. M. Peptide Segment Coupling by Prior Ligation and Proximity-Induced Intramolecular Acyl Transfer. 2000, 56(22), 3449-91. 205. Lin, P.; Jiang, J. Synthesis of Mono(trifluoromethyl)-Substituted Saturated Cycles. 2000, 56(23), 363571. 206. Speckamp, W. N.; Moolenaar, M. J. New Developments in the Chemistry of N-Acyliminium Ions and Related Intermediates. 2000, 56(24), 3817-56. 207. Kantorowski, E. J.; Kurth, M. J. Expansion to Seven-Membered Rings. 2000, 56(26), 4317-53.

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208. Barluenga, J.; Fananas, F. J. Metalloxy Fischer Carbene Complexes: An Efficient Strategy to Modulate Their Reactivity. 2000, 56(27), 4597-628. 209. Undheim, K.; Efskind, J. Ru(II)-Catalyzed Ring Closing Metathesis in Stereoselective Spiroannulations and Cascade Reactions of Cyclic Dipeptide Substrates. 2000, 56(28), 4847-57. 210. Davies, H. M. L.; Panaro, S. A. Effect of Rhodium Carbenoid Structure on Cyclopropanation Chemoselectivity. 2000, 56(28), 4871-80. 211. Scott Sawyer, J. Recent Advances in Diaryl Ether Synthesis. 2000, 56(29), 5045-65. 212. Behforouz, M.; Ahmadian, M. Diels-Alder Reactions of 1-Azadienes. 2000, 56(30), 5259-88. 213. Smyth, T. P.; O’Donnell, M. E.; O’Connor, M. J.; St Ledger, J. O. β-Lactamase-Dependent Prodrugss Recent Developments. 2000, 56(31), 5699-707. 214. Gomez-Gallego, M.; Mancheno, M. J.; Sierra, M. A. Non-Classical Polycyclic β-Lactams. 2000, 56(32), 5743-74.

215. Poli, G.; Giambastiani, G.; Heumann, A. Palladium in Organic Synthesis: Fundamental Transformations and Domino Processes. 2000, 56(33), 5959-89. 216. Fielding, L. Determination of Association Constants (Ka) from Solution NMR Data. 2000, 56(34), 615170. Tetrahedron: Asymmetry 217. McReynolds, K. D.; Gervay-Hague, J. Examining the Secondary Structures of Unnatural Peptides and Carbohydrate-Based Compounds Utilizing Circular Dichroism. 2000, 11(2), 337-62. 218. Avalos, M.; Babiano, R.; Cintas, P.; Jimenez, J. L.; Palacios, J. C. From Parity to Chirality: Chemical Implications Revisited. 2000, 11(14), 2845-74. Trends in Biotechnology 219. Borgia, J. A.; Fields, G. B. Chemical Synthesis of Proteins. 2000, 18(6), 243-51.

Contributed Volumes Progress in Heterocyclic Chemistry. Volume 12. Gilchrist, T. L., Gribble, G. W., Eds., Elsevier Science: Amsterdam, The Netherlands, 2000. 220. Groziak, M. P. Boron Heterocycles as Platforms for Building New Bioactive Agents. 221. Aitken, R. A.; Massil, T. Heterocyclic Phosphorus Ylides. 222. Li, J. J. Palladium Chemistry in Pyridine Alkaloid Synthesis. Recent Research Developments in Pure & Applied Chemistry. Volume 3 (Part 1). Pandalai, S. G., Ed., Transworld Research Network: India, 1999. 223. Bortolini, O.; Fantin, G.; Fogagnolo, M.; Medici, A.; Pedrini, P. Microbial and Enzymatic Oxidoreductions in the Synthesis of Homochiral Secondary Alcohols. 224. Fukushima, Y. Self-induced Helix-Sheet Conformational Transitions of Designed Amphiphilic Peptides. 225. Hilgeroth, A. Recent Advances in the Solid-State Photochemistry of 1,4-Dihydropyridines. 226. Indig, G., L. Mechanisms of Action of Cationic Dyes in Photodynamic Therapy of Tumors. 227. Ito, K.; Saito, K. Reactivity of 2,4,6-Cycloheptatrien-1-Imines in Cycloaddition Reactions.

228. Nishida, Y. Structure and Function of “Free Iron Ion” in Biological System and Their Model Compounds. 229. Sagawa, T.; Ihara, H.; Ohkubo, K. Catalytic and Stereoselective Activities of Cross-Linked Polymers Imprinted with Reaction Intermediate for Enzyme-like Reactions. 230. Sano, T.; Wang, Z. B. Dealumination and Realumination Behaviors of HZSM-5 Zeolite. 231. Takenaka, S. Oligonucleotides as a Nano Scale Building Block. 232. Tsuge, A. Specific Transannular Interaction in Small-Sized Cyclophane Systems. 233. Yuzo, N. New Insight into Oxidative DNA Cleavage Reaction Catalyzed by Metal Compounds.

The Alkaloids: Chemistry and Biology. Volume 54. Cordell, G. A., Ed., Academic Press: San Diego, CA, 2000. 234. Skaltsounis, A. L.; Mitaku, S.; Tillequin, F. Acridone Alkaloids. 235. Somei, M.; Yokoyama, Y.; Murakami, Y.; Ninomiya, I.; Kiguchi, T.; Naito, T. Recent Synthetic Studies on the Ergot Alkaloids and Related Compounds.

Monographs 236. Allen, D. W.; Tebby, J. C. Organophosphorus Chemistry; Vol. 30. Royal Society of Chemistry: Cambridge, U.K., 2000. 237. Back, T. G., Ed. Organoselenium Chemistry: A Practical Approach. Oxford University Press: Oxford, U.K., 1999.

238. Banks, R. E., Ed. Fluorine Chemistry at the Millennium. Elsevier Science: Amsterdam, The Netherlands, 2000. 239. Barrett, G. C., Ed. Amino Acid Derivatives: A Practical Approach. Oxford University Press: Oxford, U.K., 1999.

Recent Reviews

240. Berova, N.; Nakanishi, K.; Woody, R. W., Eds. Circular Dichroism. Wiley-VCH: New York, 2000. 241. Brown, D. J. The Pyridazines; Vol. 57. Wiley: Chichester, U.K., 2000. 242. Burgess, C., Frost, T., Eds. Standards and Best Practice in Absorption Spectrometry. Blackwell: Oxford, U.K., 1999. 243. Burgess, K., Ed. Solid-Phase Organic Synthesis. Wiley: New York, 2000. 244. Chan, W. C., White, P. D., Eds. FMOC SolidPhase Peptide Synthesis: A Practical Approach. Oxford University Press: Oxford, U.K., 2000. 245. Davies, J. S. Amino Acids, Peptides and Proteins; Vol. 31. Royal Society of Chemistry: Cambridge, U.K., 2000. 246. Diederich, F., Stang, P. J., Eds. Templated Organic Synthesis. Wiley-VCH: Weinheim, Germany, 2000. 247. Dragutan, V. Catalytic Polymerization of Cycloolefins. Ionic, Ziegler-Natta and Ring-Opening Metathesis Polymerization. Elsevier Science: Amsterdam, The Netherlands, 2000. 248. Gielen, M., Willem, R., Wrackmeyer, B., Eds. Solid State Organometallic Chemistry: Methods and Applications. [In: Phys. Organomet. Chem. 1999, 2]. Wiley: Chichester, U.K., 1999. 249. Gooijer, C.; Ariese, F.; Hofstraat, J. W., Eds. Shpol’skii Spectroscopy and Other Site-Selection Methods: Applications in Environmental Analysis, Bioanalytical Chemistry, and Chemical Physics. [In: Chem. Anal. 2000, 156]. Wiley: New York, 2000. 250. Groutas, W. C. Organic Reaction Mechanisms: Selected Problems and Solutions. Wiley: New York, 1999. 251. Gualtieri, F., Ed. New Trends in Synthetic Medicinal Chemistry. [In: Methods Princ. Med. Chem. 2000, 7]. VCH: Weinheim, Germany, 2000. 252. Guirgis, G. A.; Wurrey, C. J.; Barnes, A. J.; Laane, J., Eds. Special Issue on Spectroscopic Studies of Molecular Conformation and Structure. [In: J. Mol. Struct. 2000, 550-1]. Elsevier: Amsterdam, Netherlands, 2000.

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253. Hermann, W., Ed. Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 9: Transition Metals Part 3. Thieme: Stuttgart, Germany, 2000. 254. Kukhar, V. P.; Hudson, H. R., Eds. Aminophosphonic and Aminophosphinic Acids: Chemistry and Biological Activity. Wiley: Chichester, U.K., 2000. 255. Li, J. J.; Gribble, G. W. Palladium in Heterocyclic Chemistry. Elsevier Science: Amsterdam, The Netherlands, 2000. 256. Maskill, H. Structure and Reactivity in Organic Chemistry. Oxford University Press: New York, 2000. 257. Meunier, B., Ed. Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations. [In: Struct. Bonding (Berlin) 2000, 97]. Springer: Berlin, Germany, 2000. 258. Miethchen, R.; Defaye, J., Eds. Special Issue: Fluoro Sugars. [In: Carbohydr. Res. 2000, 327(1-2)]. Elsevier: Oxford, U.K., 2000. 259. Morris, D. G. Stereochemistry. Royal Society of Chemistry: Cambridge, U.K., 2000. 260. Rahman, Atta-ur, Ed. Studies in Natural Products Chemistry, Volume 21: Bioactive Natural Products (Part B). Elsevier: Amsterdam, Netherlands, 2000. 261. Rappoport, Z., Ed. The Chemistry of Dienes and Polyenes, Volume 2. Wiley: Chichester, U.K., 2000. 262. Richey, H. G., Jr., Ed. Grignard Reagents: New Developments. Wiley: Chichester, U.K., 2000. 263. Scrimin, P.; Taddei, M.; Cozzi, F.; Sodano, G., Eds. Seminars in Organic Synthesis; Vol. 10. Royal Society of Chemistry: Cambridge, U.K., 2000. 264. Sokolov, V. I., Ed. Special Issue: Organometallic Chemistry of Fullerenes. [In: J. Organomet. Chem. 2000, 599(1)]. Elsevier: Lausanne, Switzerland, 2000. 265. Tsuji, J. Transition Metal Reagents and Catalysts: Innovations in Organic Synthesis. Wiley: Chichester, U.K., 2000. 266. Valko, K., Ed. Separation Methods in Drug Synthesis and Purification. Elsevier Science: Amsterdam, The Netherlands, 2000.

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Index Absorption spectrometry, book, 242 Acetylenic coupling, 34 Activation parameters, book, 256 Acyliminium ions, N-, 206 Acylvinyl synthons, preparation, 41 Adenophostins, 110 Alanine imines, templates, 121 Alcohols, phenyl, condensation, 168 secondary, homochiral, book, 223 Aldehydes, alkylation, 89 asymmetric allylation, 89 terminal alkyne addition, 80 Aldol reaction, catalyzed, asymmetric, 25 vinylogous, 42 Alkaloids, acridone, 234 Amaryllidaceae, 136 ant defense, 161 biomimetic synthesis, 152 ergot, 235 isoquinoline, 151 manzamine, 139 marine, enantioselective synthesis, 139 morphine, preparation, 136 pyridine, synthesis with Pd, 222 Alkanes, hydroxylation, non-heme iron catalyst, 92 Alkenes, epoxidation, with cytochrome P450, 104 metathesis, 36 Alkylimidazolium cations, ionic liquids, 129 Alkynes, transformations with Cu(I), 180 Allene reaction, Pd catalyst, 58 Allenylmetal reagents, preparation, 60 Allylicmetal reagents, preparation, 60 Amines, preparation, 73, 156 Amino acids, R-, asymmetric synthesis, 121 book, 245 derivatives, book, 239 linked, nonracemic, 209 metal complexes, book, 245 Aminocarbocation, phosphino analog, 186 Aminophosphinic acids, book, 254 Aminophosphonic acids, book, 254 Aminopropenoates, dimethyl, 194 Analytical separations, of drugs, book, 266 Anions, luminescent sensor, 103 Ant defensive chemistry, 161 Anthracenediylidenes, 163 Antibiotics, light inactivated, 85 Antimalarial agents, bicyclic peroxides, 146 Antitumor agents, book, 226 Arenes, cyclopentadienyliron cation complex, 99 Aromatics, C-H bond activation, 88 Aryl ether preparation, 211 Aryldiazoacetates, cyclopropanation, 210 Arylmetal reagents, preparation, 60 Asymmetric catalysis, Pd complex, 172 Rh complex, 172 Asymmetric synthesis, 38 Atropisomers, preparation, 193 Autocatalysis, asymmetric, 218 Aza aromatic biomolecules, 143 Azabicyclohexanes, preparation, 154 Azadienes, Diels-Alder reaction, 212 Azaheterocycles, preparation, 142 Azanorbornyls, asymmetric catalysts, 195

Azazulenones, synthesis, book, 227 Azomethine imines, diazene derived, 137 Baylis-Hillman reaction, asymmetric, 37 Benzannulation, 53 Benzene, polysubstituted, 53 substituted, microsolvation, 72 Benzisoxazolones, pyrolysis, 145 Benzo[b]furans, synthesis with Pd, book, 255 Benzo[b]thiophenes, synthesis with Pd, book, 255 Benzopyridines, ring transformation, 126 Benzoselenadiazoles, intermediates, 115 Benzotriazoles, pyrolysis, 145 Benzoxazoles, synthesis with Pd, book, 255 B-H bond activation, 29 Biaryls, axially chiral, 193 Bicyclic alkenes, cross metathesis, 198 Biomimetics, nonheme iron catalyst, 92 Bioorganic compounds, 162 Bisorbicillinoid synthesis, self-assembly, 84 Bisquinolinium cyclophanes, 82 Bistrifluoromethylphenyl phosphanylcarbene stabilization, 79 Calcium release channel, 110 Calixarenes, intramolecular H-bonding, 78 self-assembly, 78 Capillary electrophoresis, chiral separation, 70 Carbamates, from nitroaromatics, 100 Carbanions, electrophilic amination, 73 Carbene stabilization, 79 Carbocations, cyclic carbanionic valence isomer, 186 Carbohydrates, combinatorial libraries, 109 fluoro sugars, 258 hydrazones, in synthesis, 114 ligands, 98 long chain, 108 olefin metathesis, 112 Catalysts, homogeneous, organosilica with inserts, 77 homogeneous, Ru, 39 indium halides, 119 indium trichloride, 23 lithium perchlorate, 117 mesoporous silica, 77 nitrogen ligands, 45 palladium, allene reaction, 58 palladium, Heck reaction, 57 Catenanes, template preparation, 91 Cationic dyes, book, 226 C-C bond formation, enzymatic, 105 asymmetric, book, 263 metal catalyzed, 48 on solid support, 40 with transition metals, 61 Charge-transfer complexes, 185 Chiral amphiphiles, stereochemistry, 149 Chiral separation, 70 Chirality, axial, biaryls, 193 in nature, 218 without a stereogenic carbon, 259 Chromyl chloride, reactivity, 76 Cinnamaldehyde, hydrogenation, 167 Circular dichroism, 217 book, 240

Combinatorial chemistry, 40, 128 linker cleavage, 44 solution phase, 65 Combinatorial libraries, 4, 128, 147 oligosaccharides, 109 Conjugated molecules, functionalized, 28 helical, 28 Coordination compounds, electron-transfer kinetics, 96 Copper(I)halides, alkyne transformation, 180 Correlation analysis, book, 256 Crown ethers, radiochemistry, 173 Crystallography, unstable species, 3 C-S bond formation, metal catalyzed, 62 Cuprate addition, stereoselective, 75 Cyclization, bifunctional chains, 122 medium size rings, 31 medium-size rings, metal mediated, 56 seven-membered rings, 207 Cycloaddition, [2+2+1], 203 organic semiconductor surface, 6 Pauson-Khand, 203 Cycloalkynyl heterocycles, preparation, 59 Cycloallyl heterocycles, preparation, 59 Cyclodextrins, aza aromatic, inclusion complex, 125 in enzymic reactions, 107 Cycloolefins, catalytic polymerization, book, 247 Cyclopentadienyl heterocycles, preparation, 59 Cyclopeptides, nanotubes, 164 Cyclophanes, book, 232 excimer, 11 NMR, 159 synthesis, stereocontrol, 11 Cyclopropargyl heterocycles, preparation, 59 Cysteine, cyclic, analogs, 209 Cytochrome P450, 104 Dearomatization, 54 Dendrimers, conjugated pi-systems, 171 Diaminocarbocations, diphosphino analogs, 186 Diaryl ether preparation, 211 Diastereomeric equilibrium, 15 Dicarbanionic titanium intermediates, 50 Diels-Alder catalysts, 93 Diels-Alder reaction, retro-, 131 Dienes, book, 261 Dihydropyridines, 1,4-, solid-state photochemistry, book, 225 Dipeptides, cyclic, 209 Disaccharides, imino-C-, 108 Diterpenoids, clerodane, synthesis, 196 Dithiolanes, 1-3, from carbonyl compounds, 179 Dithiooxamide, pulse radiolysis, 165 DNA cleavage, oxidative, book, 233 DNA microarrays, photolithographic synthesis, 87 Domino reactions, intermolecular, Ni catalyzed, 2 stereoselective, 75 Enantioselectivity control, 15 Ene reactions, with chiral Lewis acids, 106 Environmental analysis, book, 249

Recent Reviews Enzyme mimics, book, 229 Enzyme reactions, with cyclodextrin, 107 with inclusion complexes, 107 Enzymes, in organic solvents, 33 ESR studies, of nitroxides, 169 Fischer metal carbenes, 69 Fluorescence, book, 249 Fluoroanions, ionic liquids, 129 Fluoromethyl cyclic hydrocarbons, 205 Fluoroquinolinones, polycyclic, 181 Formamidines, trisubstituted, cyclisation, 176 Fullerenes, 190, 264 derivatives, 13 excited state, 13 Furans, synthesis with Pd, book, 255 Glycine antagonists, book, 263 Glycine imines, templates, 121 Glycoconjugates, solid-phase synthesis, 175 Glycosides, C-, synthesis, 113 Glycosylation, solid-phase synthesis, 109 Grignard reagents, book, 262 Heck reaction, on solid support, 40 Pd catalyst, 57 Helicenes, phenanthroline dioxide, 86 Heterocycles, boron, book, 220 degenerate ring transformation, 130 from hydrazones, 114 from oxocarboxylic acid, 123 from unsaturated aldehydes, 132 glycosidase inhibitor, 132 hydrogen exchange, metal ion effect, 10 nitrogen-containing, 144 optically active, 134 phosphorus ylides, 221 preparation, nitrogen fixation, 144 preparation, with lithiated methoxyallene, 141 selenium, intermediates, 115 stereoselective dipolar cycloaddition, 138 synthesis via dipolar cycloaddition, 148 synthesis, from formamidines, 176 tautomerism, 18-22 Heterodimetallic complexes, polar metal bond, 35 Homochirality, 218 Hormones, book, 245 Hydroformylation, stereoselective, 75 Hydrogen bonding, selective, 5 Hydrogenation, Ru catalyzed, 39 Hydrostannanes, dehydrogenative coupling, 68 Hydrostannations, 64 Imidazoles, synthesis with Pd, book, 255 Indoles, synthesis with Pd, book, 255 Inositol phosphate mimics, 110 Iridoids, 160 Iron ions, biological, book, 228 Isocyanates, from nitroaromatics, 100 Isoindolones, fused, preparation, 131 Isoquinoline alkaloids, 151 Isotope effects, book, 256 Isoxazoles, prostanoid preparation, 182 Ketimines, nucleophilic addition, 156 Ketones, germanium congeners, 7 heavy, 7 silicon congeners, 7 tin congeners, 7 Lactacystin, preparation, 120 proteasome inhibitor, 120 Lactone analogs, preparation, 120

J. Org. Chem., Vol. 66, No. 1, 2001 361 Latamase, β-, prodrugs, 213 Ligands, aromatic, 174 carbohydrates, 98 nitrogen, asymmetric synthesis, 45 π-bonded, 174 Linkers, traceless, selenium, 32 traceless, sulfur, 32 Lipases, with additives, 201 Lipopolysaccharides, heptose-, 111 KDO-, 111 phosphodiester-, 111 Luminescent sensors, ionizable analytes, 103 Macrocyclic compounds, 28 Medicinal chemistry, synthesis, 251 Metal arenes, charge-transfer bonding, 95 Metallacarboranes, 94 Metalloxy Fischer carbenes, 208 Molecular connectivity indices, 71 Molecular structure, spectroscopy, 252 Monoterpenes, 153 oxidation, 146 Multicomponent reactions, 147 Munchnones, fused, tandem recyclization, 135 Natural products, bioactive, book, 260 carbocycles, 31 polyketides, 30 stereoselective synthesis, book, 263 synthesis, dicarbonic titanium intermediates, 50 total synthesis, 26 Nitroalkanes, electron transfer, hydroperfluorodiacyl peroxide, 169 Nitrones, nucleophilic addition, 197 Nucleosides, from hydrazones, 114 from osazones, 114 triphosphates, synthesis, 43 Nucleotides, adenophostin receptor, 110 Olefin metathesis, in carbohydrates, 112 Olefin polymerization, catalysts, 101 Olefins, epoxidation, with cytochrome P450, 104 metathesis, 36 silicon addition, 63 Oligonucleotides, book, 231 Oligosaccharides, combinatorial library, 109 secondary structure, 217 solid-phase synthesis, 109, 175 Optical activity, book, 240 Organisilanes, sulfur compound activation, 118 Organofluorine chemistry, book, 238 Organoiron, tricarbonyl cyclohexadiene complex, 55 Organometallic chemistry, book, 263 solid state, book, 248 Organometallic compounds, in synthesis, 47 in synthesis, book, 253 unsaturated, dimetallic, geminated, 52 Organometallic diazine, 143 Organopalladium, catalysts, 192 intermediates, 60 Organophosphorus compounds, book, 236 Organorhenium compounds, excited state, 97 Organoselenium compounds, book, 237 Organosilica, incorporating organics, 77 Organosilicon compounds, 89 Organotellurium compounds, 24 Organotin compounds, 64

Organotitanium complexes, 51 Oxazoles, synthesis with Pd, book, 255 Oxazolones, fused, 135 Oxidation, with metaloxo catalysts, book, 257 Oxidoreductions, book, 223 Oximes, preparation, 157 Oxocarboxylic acid synthons, 123 Parity violations, 218 Peptides, β-sheet structure, 188 amphiphilic, helix sheets, book, 224 amyloid model, 188 book, 245 conjugated, book, 245 coupling, 204 cyclization, photolabile auxiliary, 83 intramolecular acyl transfer, 204 nanotubes, 164 preparation, book, 244 secondary structure, 217 synthesis, coupling reagents, 90 Pharmaceutically active compounds, book, 263 Phase transfer catalysis, oxidants, hydrogen peroxide, 155 oxidants, air, 155 Phenanthroline dioxide, synthesis, 86 Phenothiazine, derivatives, 170 radical cations, 170 Phenyldiazoacetates, cyclopropanation, 210 Phenylethylamines, 151 Phenylnitrene, 16 Pheromones, from ants, 161 Phosphinoboranes, 29 Phosphinocarbene bistrifluoromethylphenyl stabilization, 79 Photochemistry, with zeolites, 74 Photolysis, chiral inductor, zeolites, 74 in zeolites, 74 Phytochemical, 162 Piperazine, amino acid derivatives, 209 Poly(ethylene glycol), 4 Polyamine analogs, 116 Polyamine conjugates, 116 Polyamines, solid-phase synthesis, 200 synthesis, 200 Polycycloolefins, book, 247 Polyenes, book, 261 Polyether ionophore antibiotics, synthesis, 46 Polyketides, conformation, 30 Polymers, functionalized, 199 imprinted, 191 soluble, supported synthesis, 4 Polyoxyalkylenes, 4 Polythiophenes, Langmuir-Blodgett films, 178 monolayers, 178 Porphobilinogen, synthesis, 133 Porphyrinoids, expanded, 27 Prodrugs, β-lactamase dependent, 213 Propenoates, dimethylamino, 194 Prostanoids, from isoxazoles, 182 Proteins, book, 245 synthesis, 219 Proton transfer, selective, 5 Pyrazines, synthesis with Pd, book, 255 Pyridazines, 241 Pyridine alkaloids, synthesis with Pd, 222 Pyridines, organometallic, 143 ring transformation, 126 synthesis with Pd, book, 255

362

J. Org. Chem., Vol. 66, No. 1, 2001

Pyrimidines, synthesis with Pd, book, 255 Pyrroles, synthesis with Pd, book, 255 Quinazolines, lithiation, 127 Quinazolinones, lithiation, 127 Quinoline, organometallic, 143 Quinolinones, fluoro-, polycyclic, 181 Quinolizidines, polyhydroxylated, 108 Quinones, cyclodextrin inclusion, 166 oligosaccharides inclusion, 166 Quinoxalines, synthesis with Pd, book, 255 Racemic catalysts, 1 Radical reactions, book, 263 with transition metals, 49 Radicals, translational diffusion, 12 Radiochemistry, crown ethers, 173 Reaction mechanisms, book, 250, 256 Reaction rates, book, 256 Receptors, D-inositoltriphosphate, 110 Rhodium carbenoids, 210 Ring closing metathesis, 31, 209 Ring expansion, 207 Ring-opening metathesis, book, 247 Rotaxanes, template preparation, 91 Secondary orbital interactions, 9 Selenium heterocycles, intermediates, 115 Self-assembly, 38 Semiempirical connectivity, 71 Sesquiterpenes, eudesmane, 13C NMR, 158 Shpol’skii spectroscopy, book, 249

Recent Reviews Silacyclopropanes, 17 Silenes, cyclic, 14 Silyl enol ethers, ethenylation, 81 Silylene, stable, 14 Silylphosphines, 66 Solid-phase synthesis, 32, 40, 128 book, 243, 263 linker cleavage, 44 oligosaccharides, 175 peptides, book, 244 Solid-state chemistry, organometallics, book, 248 Solution phase combinatorial library, 65 Solvation, selective, 5 Stereochemistry, book, 259 diastereoisomeric perturbations, 38 Stille coupling reaction, on solid support, 40 Structure/reactivity correlation, book, 256 Strychnine, total synthesis, 67 Sugars, imino, 108 naked, 108 Sulfonimides, acid derivatives, 184 Sulfoxides, vinyl, synthesis, 183 Supramolecular structures, template preparation, 91 Supramolecules, chiral structure, two dimensions, 149 Suzuki coupling reaction, 193 on solid support, 40 Synthons, vinyl-, 41 Telluranes, synthons, 177 Template organic synthesis, book, 246

Tetraazacycloalkanes, functionalization, 187 Tetrazoles, alkylation, 124 Thiatriazines, preparation, 140 Thiazoles, synthesis with Pd, book, 255 Thiophenes, synthesis with Pd, book, 255 Titanium isopropoxide isopropylmagnesium halide, 189 Transition metals, catalysts, book, 265 in synthesis, 102 in synthesis, book, 253, 265 Triflic anhydride reactions, 202 Triterpenes, polyether, marine, 150 Unsaturated compounds, with electrophiles, 185 Vinyl sulfoxides, synthesis, 183 Vinyl tellurides, coupling, 24 Vinyldiazoacetates, cyclopropanation, 210 Vinylmetal reagents, preparation, 60 Vinylogous synthons, preparation, 41 Wheland complexes, 185 X-ray diffraction, grazing incidence, 149 Zeolites, H-ZSM-5, alumination, book, 230 dealumination, book, 230 photolysis, chiral inductor, 74 radical reactions, 8 Ziegler-Natta polymerization of olefins, book, 247 JO004012E