Recyclable, Strong, and Highly Malleable Thermosets Based on

For example at 40% RH there was only a 20% drop in the mechanical properties after ...... Garcia, J. M.; Jones, G. O.; Virwani, K.; McCloskey, B. D.; ...
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Recyclable, strong and highly malleable thermosets based on boroxine networks William A. Ogden, and Zhibin Guan J. Am. Chem. Soc., Just Accepted Manuscript • Publication Date (Web): 07 May 2018 Downloaded from http://pubs.acs.org on May 7, 2018

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a

b



Tensile Stress (MPa)

a 35

BXT BXT/UDP

30 25

20 15 10

a

5 0 0.05 0.1 Tensile Strain (mm/mm)

0.6

b 25 Tensile Stress (MPa)

0.8

0.15

G/Go

0

0.2

15

0 1

Pris tine Reproces sed 1 Reproces sed 2 Reproces sed 3

5

1/e

0.4

20

10

80 °C 75 °C 70 °C 65 °C 60 °C 55 °C

1

100 10000 Relaxation Time (s)

b 7

0

c

0.05

0.1

0.15

0.2

6

Tensile Strain (mm/mm)

ln τ

0

5 y = 11.015x - 27.328 R² = 0.998

4 3 2.8



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2.9 3 1000/T (K-1)

3.1



ASSO CIATED CO NTENT

AUTHO R INFO RMATIO N

5