Regenerative EMF Cells : INDEX

Β. Battery, lithium-chlorine secondary . 194. Bimetallic cell. 136 phase diagram for the regenerative 121. Bimetallic and hydride E M F cell sys tems...
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INDEX A Additives 162, Adsorption AgCl thermocell Allison eutectic Anode composition Anode metal, liquid Antimony chloride cells Auxiliary power plant for spacecraft. Azeotropes pressure vs

168 20 222 73 129 136 200 54 130 131

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Β Battery, lithium-chlorine secondary . Bimetallic cell phase diagram for the regenerative Bimetallic and hydride E M F cell sys­ tems, thermally regenerative Bimetallic regenerative cell Bimetallic systems Binary alloys, thermodynamic studies of Bismuth alloys -chromium melts dynamic corrosion by -iron melts -lead-tin eutectic solubilities of elements in liquid.... static corrosion by Bromides C Carnot cycle efficiency Catalyst poisons Cathode composition Cathode, liquid binary alloy Cell operating cycle Cesium-selenium CGCC Charge/discharge cycle Chemically regenerative E M F cell systems Chloride systems, regenerative Chlorides, corrosion by fused Chromium-bismuth melts Chromium-iron-nickel alloys Colburn-Chilton analogy Compound formation Concentration cell E M F Concentration cells, continuous gas.. Condensation temperature Conductance Continuous gas concentration cells. . Convection-diffusion tube Converting heat to electrical energy. Corrosion by fused chlorides by fused fluorides by fused hydroxides

194 136 121 82 98 84 142 162 163 168 163 164 168 162 253 278 284 128 136 123 138 11 297 277 198 155 163 152 172 122 122 11 128 18 11 171 198 155 151 159

Corrosion (continued) by fused salts and heavy liquid metals by heavy liquid metal

150 149 161

D Differential density cell 74 Discharge curve 195 Dual Membrane Fuel Cell 19 Dye-coated electrode energy conver­ sion 267 Dynamic corrosion by bismuth 168 by lead 175 by tin 178

Ε Efficiency, fuel cell 5 Electrical energy, converting heat to. 198 Electrochemical cell Ill and chemical behavior 30 studies of Na Bi 146 systems, regenerative 1 Electrode cell flowing 38 static 34 Electrode reaction entropy 218 Electrolysis 23 regeneration by low pressure 241 Electrolyte 133 potassium hydroxide 293 Electrolytically regenerative fuel cells 292 Electrothermal regeneration 93 Elements in liquid bismuth, solubili­ ties of 168 EMF 122 E M F cell thermally regenerative bimetallic and hydride 82 regenerative 1 E M F systems theory of regenerative 227 thermodynamics of 8 regenerative 215 Energy conversion efficiency 222 Entropy, electrode reaction 218 3

F Ferric ion, oxidation of coal by 288 Flowing electrode cell 38 Fluorides, corrosion by fused 151 Four-electrode system 197 Fuel cell 1,31,62 efficiency 5 electrolytically regenerative 292 H2/O2 regenerative 302 redox 280 system, solid inorganic electrolyte regenerative 17 Fused salt electrolytes 80

Crouthamel and Recht; Regenerative EMF Cells Advances in Chemistry; American Chemical Society: Washington, DC, 1967.

INDEX

308 Fused salts corrosion by.. . 150 and heavy liquid metals, corrosion by 149 G Galvanic cell systems cells, thermally regenerative systems, photochemically regenera­ tive . systems regenerable by electrolysis Gas concentration cells, continuous.. Gas electrode Gaseous intermediates Graphite loop Grove

Downloaded by 80.82.77.83 on May 17, 2017 | http://pubs.acs.org Publication Date: January 1, 1967 | doi: 10.1021/ba-1967-0064.ix001

m

199 11 258 214 11 188 279 171 178 3

H Heat to electrical energy, converting. Heavy liquid metals corrosion by corrosion by fused salts and Helium-purification High temperature thermal dissocia­ tion, regeneration by :. Ht/O* regenerative fuel cell H2/O2 secondary battery Hydride E M F cell systems, thermally regenerative bimetallic and Hydride regenerative cell, thermody­ namics of the lithium Hydrogen-bromine fuel cell Hydrogen/oxygen Hydrogen permeation Hydroxides, corrosion by fused I Iodides Iodine-lead systems Iodine-lithium systems Inert atmosphere INOR-8 Inorganic electrolyte regenerative fuel cell system, solid Inhibitor of mass transfer Inhibitors Intermetallic cells Intermetallic cell systems, regenera­ tive Intermetallic compound solubility... Iron -bismuth melts -molybdenum alloys -nickel-chromium alloys Irreversibility . . . . Isothermal mass transfer 163,

198 161 149 107 247 302 301 82 105 19 292 108 159 253 234 234 106 153 17 168 175 136 140 144 108 163 108 152 15 168 69 69

L Lead dynamic corrosion by

M Membrane composition 20 Membranes, zirconium phosphate... 17 Mercury galvanic system, thermally regenerative soaium43 nuclear reactor-powered system. .30, 53 Metal cell, thermally regenerative liquid metal62 Metallic intermediates 278 Metals corrosion by fused salts and heavy liquid 149 corrosion by heavy liquid 161 Methanol-nitric aci dcell 287 Molten salt electrolyte 65, 136 Ν

NaF-LiF-KF-UF mixtures 153 Nernst equation 166 Nickel-chromium-iron alloys 152 Niobium 108 Nitric acid cell, methanol 287 Nitric acid redox cathode 285 Nuclear reactor-powered system.... 53 Nuclear reactor, SNAP-8 54 4

Κ Κ amalgam K / H g cell

Lead (continued) -iodine systems 234 static corrosion by 173 -tin-bismuth eutectic 164 LiCl-KCl eutectic 196 Liquid anode metal 136 Liquid binary alloy cathode 136 Liquid metal cell, thermally regenerative 62 electrodes 80 Fuel Reactor 162 Liquid metals, corrosion by fused salts and heavy 149 Liquid-vapor equilibria 125 Liquid zinc alloys 158 Lithium -bismuth system 130 -chloride cell 186 -chlorine secondary battery 194 electrolytes 110 hydride cell 99 system -84 hydride regenerative cell, thermo­ dynamics of the '. 105 -hydride system 63, 89 -iodine systems 234 LMC 78 LMFR 162 Low pressure electrolysis, regenera­ tion by 241

175

Ο Oxidation of coal by ferric ion Oxygen/hydrogen

288 292

Ρ Performance analysis 53 Phase diagram for the regenerative bimetallic cell 121

Crouthamel and Recht; Regenerative EMF Cells Advances in Chemistry; American Chemical Society: Washington, DC, 1967.

309

INDEX

Photochemically regenerative electrochemical systems galvanic systems Photoregenerative electrochemical systems Pitzer method Polarization Potassium hydroxide electrolyte Potentiostat Power plant for spacecraft, auxiliary. Pressure vs. azeotropes Pressure, implications of low Pumped storage

213 258 214 221 141 293 286 54 131 126 7

Downloaded by 80.82.77.83 on May 17, 2017 | http://pubs.acs.org Publication Date: January 1, 1967 | doi: 10.1021/ba-1967-0064.ix001

Κ

Redox fuel cells 278,280 Refractory metals 171 Regeneration 115 cycle 84 efficiencies 87 by high temperature thermal disso­ ciation 247 by low pressure electrolysis 241 temperature 128 Regenerative bimetallic cell, phase diagram for the 121 bimetallic and hydride E M F cell systems, thermally 82 cell, thermodynamics of the lithium hydride 105 chloride systems 198 electrochemical systems 1, 6 thermally and photochemically. 213 E M F systems theory of 227 thermodynamics of 215 fuel cell 19,27 electrolytically 292 H /0 302 galvanic cell 16 galvanic systems, photochemically. 258 intermetallic cell systems . . 140 liquid metal cell, thermally 62 sodium-mercury galvanic system, thermally 43 nuclear reactor-powered system 30, 53 2

2

S

Secondary battery, lithium-chlorine. 194 Selenium-cesium 138 Sickle gauge 203 SN AP-8 nuclear reactor 54 Sodium amalgam cells 31 bismuth system 129 mercury system 31 -mercury galvanic system, ther­ mally regenerative 43 nuclear reactor-powered 30, 53 polyphosphate 161 Sodium/tin cell 67 Solid inorganic electrolyte regenera­ tive fuel cell system 17

Solubilities of elements in liquid bis­ muth Soret equilibrium Spacecraft, auxiliary power plant for Spectra of intermetallic compounds in molten salts Spinning reserve Stannous iodide State of charge Static corrosion by bismuth by lead by tin Static electrode cell Sulfonated polystyrene cation ex­ change membrane Sulfonating phenol formaldehyde polymers

168 221 54 147 7 251 301 162 173 177 34 19 19

Τ

Tellurium chloride cells 200 Temperature condensation 128 regeneration 128 Test loop 46 Theory of regenerative E M F systems 227 Thermal dissociation, regeneration by high temperature 247 efficiencies 96 regeneration of galvanic systems.. 214 regeneration by electrolysis 236 Thermally dissociative regenerative systems.. 214 regenerative bimetallic and hydride E M F cells 82 electrochemical systems— 198, 213 galvanic cells 11 liquid metal cell 62 sodium-mercury galvanic system 43 nuclear reactor-powered... 30, 53 system 2 Thermodynamic studies of binary al­ loys 142 Thermodynamics of E M F systems 8 the lithium hydride regenerative cell 105 rgeenerative E M F systems 215 Tin -bismuth-lead eutectic 164 dynamic corrosion by 178 static corrosion by. . . 177 TRAC 31 system 43, 53 V Vanadium 108 Victoria Blue B-ascorbic acid system. 271 Void formation 152

Ζ Zeolite 18 Zinc-rich alloys 158 Zirconium phosphate membranes— 17 ZrCfilm 164

Crouthamel and Recht; Regenerative EMF Cells Advances in Chemistry; American Chemical Society: Washington, DC, 1967.