Richter-Anschutz: The Chemistry of the Carbon Compounds. Vol. IV

istrv. The chapter on the liquid state follows the chapters relating to the gaseous and solid states, an arrangement which permits discussion from bot...
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istry. The chaptclr o n thc liquid s t a t e follons t h e chapters relating t o the g s t a t e s . a n arrangeincnt which permits discussion fro:ii both of tlic applicable points of view. T h e chapters o n atomic s t r u c t u r e , m o l c c d a r structure, :tnd radioactivity a n d nuclear reactions a r e particularly good, as arc also t h e nutnerous other discussions throughout from t h e structural point of view. T h e second lan. of therniodynatnics is introduced after a short chapter on solutions, and i j follon-et1 b y a discussion of pliaie equilibria i n oiie-co!iiponent s y s t e x s . T h e n , before introducing tlie stutlcnt t o niorc co:iiplicated phase equilibria in niu1tico:nponnt systems. t h c authors ninlcr a careful unification and extension of concepts in discmssions of cscaping tendcnc,y and t h c propertics of ideal solutions. T h e erc~ellent chapters on cheniicnl cquilibria ; m i lcinet ics contain nuni(’rous exercises n o r k e d out i n detail a n d , subsequently, nunicrous prohlenis for t h e s t u d e n t . T h e chapters on conductance and transference ant1 on electromotive f o r c e are well done: as :ire also t h e final chapters o n interactions of light lvith :nattcr and o n surface phenometm. .is a result of t h e sonicwhat niorc descriptive point of view cven sonie of t h e simple derivations are licit includcd, hut i,cfercnces t o standard norlcs Tvhere they inay be found a r e given, and they may usually easily h e supplied in the lectures. T h e literature references are soincivhat too few, arid very often quite troublesome t o follo\V up n-hen only t h e a u t h o r and year arc given; this tendency detracts someiyhat froin t h e book’s value as a reference n-ork. The first editions of all t echnicnl hooks contain errors, a n d a fctv of t h e important ones prescnt here m a y be \vorth noting. Cerium is not t h e only rare e s r t h i n ( p . lSI)), as is evidenced b y higher valence s t a t e s which t h e 4.f electrons play n c.hcniiral 1.61~ of praseodymium and terhiuw. T h e authors have confused t h e meanings of the terins “lattice” and “structure” in t h c r-hapter on t h e crystalline s t a t e , and have used t h e m interchangeably. A number of tlie rostrictions on thermodynamic variables in statements and equations i n C‘1iaptc.r ST- have, h c n omitted. Thus ( p . 1.56) & = I0 for a reversible process only if I!‘ (as x e l l as T ) is constant. E q u a t i o n (4) on p . 2.57 a n d t h e s t a t e m e n t s regarding AF i n Section 10, belon-. arc, of (’ourse, t r u e with t h e restrictions t h a t both p a n d 7’ a r c cons t a n t . Equation (S) on p . 260 and t h e first equation on p . 267 need the restriction t h a t p is constant. The soc~ontlc,luation on p. 267 is t r u e only \rhen 1’ is c o n s t a n t , and is given correctly on p. 259. T h e publishers have ~ ~ o i ~ i i r r a ?in e i lpresenting this book estremely well, on escellent paper, a n d with very few n i i ~ p r i n t s , 1,-nder t h e guidance of a c*o::ipetent teacher t h e student !Till find this a n escellent beginning t e s t in physical chemistry, and it is most heartily recommended. W I r m . < x S.LIPSCOVB.

X i c h l c , - d , i s c i i ~ t l t : The Che!nislr?/ oj” / h a Corimn COmpOUlkdS. 1’02. Iv. T h e H e t e r o c y c l i c C o m p o u n d s a n d Orgnnir Free Ra(1icnIs. T h i r d English edition, based upon t h e twelfth German edition. Translatetl tiy 11. I-. Ilarlicn a n d A . J . l l e e . s v C 408 pp. S e w York: Elsevier Puhlishing C‘onipmy, 1917. Price: $12.00. This is the fourth. and final, volumc of the literal translation of Richter-rlnschutz. T h e t e s t is t h a t of t h e tn-clfth Gernian etlitiun, published in 1935; t h e material in this translation corresponds t o Volume I11 (hetero:.yclic co:iipountls) and t o a portion of 1-olume 11,p a r t 2 (radicals), of t h e German edition. T h e section on t h e heterocyclic compounds was written h:; F. Reindcl a n d t h e translation is b y 11.F.D a r k e n ; t h e section on radicals was written by Ludn-ig ;inschutz and t h e translation of this is by -4. J . X e e . T h e hook is t h e standard “Richter”, n-ell known t o all chemists. T h e conventional plan of treatment has been follon-ed. The btiok-~iial;ingis good b u t , all in all, i t is difficult t o understand t h e necessity f o r a translation of a book now t n e l v e years old-a book which can hardly be of much more t h a n historical value, and this reviewer feels t h a t t h e energy p u t into the niaking of this book could \vel1 have been expended more profitably on soniething else. The price ($12.00) is excessive. I,EE IRVISSIIITH.