Apr 1, 1980 - Force-field calculations for abnormally large bond angles. Frank A. L. Anet, Mehran Ghiaci. J. Am. Chem. Soc. , 1980, 102 (8), pp 2528â...
In the p.m.r. spectrum9 the four aromatic protons, the ethylidene group and the N-methyl were identifiable. The alkaloid recovered from the p.m.r. measurement ...
[(5V -. S3) + (S3 -. 53)IK]'K/16. 4.31 ± 0.69. 3.18 ± 0.50 a St' is the chemical shift of the i th n.m.r. line, in radians/sec., relative to the average chemical shift, », of ...
line, in radians/sec., relative to the average chemical shift, », of all /3-C(CH3)2 protons. That is,. S(' = ... for ring inversion at â164° is 45 seer1 and the nature of.
5 6f' is the chemical shift of the i th n m r . line, in radians/sec., relative to the average chemical shift, 60, of all P-C(CH& protons. That is, are negative, those of 6,' ...
Conformational inversion of pyranoid ring sugars. Conformational equilibrium of .beta.-D-ribopyranose tetraacetate. Norman S. Bhacca, and Derek. Horton.
for ordering and Internet access instructions. JA9714898. (16) Paliwal, S.; Geib, S.; Wilcox, C. S. J. Am. Chem. Soc. 1994, 116,. 4497-4498. (17) Castellano, R. K. ...
Conformational inversion of pyranoid ring sugars. Conformational equilibrium of .beta.-D-ribopyranose tetraacetate. Norman S. Bhacca, and Derek. Horton.
Margit Hölbling , Michaela Flock , Judith Baumgartner , Karl Hassler. European Journal of ... Günter Tekautz , Alexandra Binter , Karl Hassler , Michaela Flock.
This is consistent with the low-energy mechanism, where the ring inversion is not prevented by crystal packing ... Ramachandra S. Hosmane , Joel F. Liebman.
Conformational Study of Cyclodecane and Substituted Cyclodecanes by Dynamic NMR Spectroscopy and Computational Methods. Diwakar M. Pawar, Sumona ...