Role of diffusion in trigger wave propagation in the Belousov

Apr 11, 1980 - which initiate in local centersand propagate owing to diffusion- reaction coupling. The mechanism of the Belousov-Zhabotinskii reaction...
0 downloads 0 Views 1MB Size
J . Am. Chem. SOC.1980, 102, 6196-6198

6196

N(1), NH2(6), and N(7) of A M P adenine rings. The bond distances determined from the ISNinvestigation clearly show that the metal-nucleotide ring interaction is an inner-sphere coordination effect. Evidence for two separate binding sites is presented and serves to explain an anomalously short MnZ+-C(8) bond distance. Extension of these multinuclear studies to ISN-enriched nucleotides will allow investigation of 1:1 metal-nucleotide complexes

at physiologically significant nucleotide concentrations,