Role of Modest Pressure in Chirally Selective Complexation Interactions

Moira C. Ringo and Christine E. Evans*. Department of Chemistry, UniVersity of Michigan, Ann Arbor, Michigan 48109-1055. ReceiVed: March 10, 1997; In ...
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J. Phys. Chem. B 1997, 101, 5525-5530

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Role of Modest Pressure in Chirally Selective Complexation Interactions Moira C. Ringo and Christine E. Evans* Department of Chemistry, UniVersity of Michigan, Ann Arbor, Michigan 48109-1055 ReceiVed: March 10, 1997; In Final Form: May 5, 1997X

In contrast with temperature, pressure is often overlooked as an important parameter in condensed phases primarily due to minimal perturbations in bulk properties. Molecular interactions, however, have been demonstrated to be significantly altered by relatively modest pressure (