SCIENTECH, INC. - Analytical Chemistry (ACS Publications)

May 25, 2012 - SCIENTECH, INC. Anal. Chem. , 1978, 50 (7), pp 658A–658A. DOI: 10.1021/ac50029a745. Publication Date: June 1978. ACS Legacy Archive...
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References

(2) ASTM D19 Committee, "New Stan­ dard Practice for Preparation of Sample for Identification of Waterborne Oils", ASTM Method D3326 (Revised), P a r t 31, ASTM Annual Standards, 1978. (3) G. M. Frame, G. A. Flanigan, and C. P. Chamberlain, "Cleanup Procedure for Contaminated Oils Prior to Fingerprint­ ing by GC and IR Spectroscopy", 1978 Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Abstracts, Paper 554, Mar. 1978. (4) J. W. Frankenfeld, "Weathering of Oil at Sea", Final Report, U.S. Coast Guard Contract DOT-CG-23035-A, N T I S Ac­ cession No. AD787789, Sept. 1973. (5) C. W. Brown, P. F. Lynch, and M. Ahmadjian, "Identification of Oil Slicks by Infrared Spectroscopy", Final Report, U.S. Coast Guard Contract DOT-CG81-74-1099, N T I S Accession No. ADA040975, Aug. 1976. (6) G. A. Flanigan, "Ratioing Methods Ap­ plied to GC Data for Oil Identification", Proceedings of Workshop on P a t t e r n Recognition Applied to Oil Identifica­ tion, Coronado, Calif., Nov. 1976, P u b ­ lished by I E E E 1977, Cat No. 76CH1247-6C. (7) C. P. Anderson, T. J. Killeen, and A. P. Bentz, "Weighting Factors for Infrared Data Points in Pattern Recognition for Oil Identification", 1978 Pittsburgh Con­ ference on Analytical Chemistry and Ap­ plied Spectroscopy, Abstracts, Paper 397, Mar. 1978.

(1) U.S. Coast Guard, Dept. of Transpor­ tation, "Polluting Incidents in and Around U.S. Waters, Calendar Year 1976", CG-487, 6 Dec. 1977.

The opinions or assertions contained herein are the private ones of the writer and are not to be construed as official or reflecting the views of the Commandant or the Coast Guard at large.

Χ = SUSPECT S = SIMULATED Y = SPILL

NO. 6

FUEL

WX

OIL

WAVENUMBER CRECIPROCAL CENTIMETERSD Figure 5. Computer plot of normalized absorbances for 18 data points taken in oil spectra Plot shows differences between unweathered oil (suspect "X") and weathered oil (spill "Y"). It also shows how closely computer-simulated weathering of "X" lies relative to spill (curve "S"). Note that the simulation even shows slope reversal between 744 and 722 c m - 1

pled. It proved to be the same as the cargo of the Grand Zenith, the first concrete evidence of the location of that vessel's disappearance in the Jan­ uary storm.

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CIRCLE 190 ON READER SERVICE CARD 658 A · ANALYTICAL CHEMISTRY, VOL. 50, NO. 7, JUNE 1978