Selectivity in cycloadditions to vinylheterocumulenes. [2 + 2] and [4 + 2

Anna ChrostowskaClovis DarriganAlain DargelosAlain GraciaaJean-Claude Guillemin. The Journal of Physical Chemistry A 2018 122 (11), 2894-2905...
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J. Org. C h e m . 1982, 47,3994-3998

3994

Table 11. Coupling Constant Data for Various Structural Types of 1,4-Cyclohexadienes u.

R

4 coupling constant J , , 4 (cis1 J , 4,( trans) J c i 1Jtrans JI,SJ3,4 J3.4,

1

planar

rigid boat

(4)=

(5)

8.3 7.5 1.11

3.1 3.0

rigid boat (6)

12.0 4.7 2.55 2.5 5.5

2.6' 4.7