J. Org. C h e m . 1982, 47,3994-3998
3994
Table 11. Coupling Constant Data for Various Structural Types of 1,4-Cyclohexadienes u.
R
4 coupling constant J , , 4 (cis1 J , 4,( trans) J c i 1Jtrans JI,SJ3,4 J3.4,
1
planar
rigid boat
(4)=
(5)
8.3 7.5 1.11
3.1 3.0
rigid boat (6)
12.0 4.7 2.55 2.5 5.5
2.6' 4.7