Self-passivation of 2D Ruddlesden–Popper perovskite by polytypic

11 hours ago - ... under electron irradiation elucidates how the outer PbI2 self-passivation can protect inner 2D RP causing longer operando stability...
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Self-passivation of 2D Ruddlesden–Popper perovskite by polytypic surface PbI encapsulation 2

Hee Joon Jung, Constantinos C. Stoumpos, Mercouri G. Kanatzidis, and Vinayak P. Dravid Nano Lett., Just Accepted Manuscript • DOI: 10.1021/acs.nanolett.9b02069 • Publication Date (Web): 19 Aug 2019 Downloaded from pubs.acs.org on August 19, 2019

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Nano Letters

Self-passivation of 2D Ruddlesden–Popper perovskite by polytypic surface PbI2 encapsulation Hee Joon Jung1, Constantinos C. Stompus2,3, Mercouri G. Kanatzidis2,3 and Vinayak P. Dravid1,*

1Department

of Materials Science and Engineering, Northwestern University, Evanston, Illinois

60208, USA 2Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA 3Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA *Corresponding Author: [email protected] Abstract Two-dimensional Ruddlesden-Popper (2D RP) halide perovskites, C2MAn-1PbnI3n+1 (C=bulky ammonium cation; MA=methyl-ammonium) with low n-members (n