Silicon-Based Polymer Science, Copyright, Advances in Chemistry

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Silicon-Based Polymer Science

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Downloaded by 185.89.101.204 on May 14, 2016 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1990-0224.fw001

ADVANCES

IN C H E M I S T R Y S E R I E S

224

Silicon-Based Polymer Science A Comprehensive Resource Downloaded by 185.89.101.204 on May 14, 2016 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1990-0224.fw001

John M . Zeigler, EDITOR Sandia National Laboratories F. W. Gordon Fearon, EDITOR Dow Corning Japan, Ltd.

Developed from the International Topical Workshop "Advances in Silicon-Based Polymer Science" sponsored by the Division of Polymer Chemistry, Inc., of the American Chemical Society, Makaha, Oahu, Hawaii, November 21-24, 1987

American Chemical Society, Washington, DC 1990

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Downloaded by 185.89.101.204 on May 14, 2016 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1990-0224.fw001

Library of Congress Cataloging-in-Publication Data Silicon-based polymer science: a comprehensive resource. John M. Zeigler, F. W. Gordon Fearon, editors. p. cm.—(Advances in chemistry series, 0065-2393; 224) Developed from a symposium sponsored by the Division of Polymer Chemistry, Inc., of the American Chemical Society. ISBN 0-8412-1546-4 1. Silicon polymers—Congresses. I. Zeigler, John M. (Martin), 1951. II. Fearon, F. W. Gordon. III. American Chemical Society. Division of Polymer Chemistry, Inc. IV. Series. QD1.A355 no. 224 [QD383.S54] 540 s—dc20 [547.7] 89-17843 CIP The paper used in this publication meets the minimum requirements of American National Standard for Information Sciences—Permanence of Paper for Printed Library Materials, ANSI Z39.48-1984.

Copyright © 1990 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of thefirstpage of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per-copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, MA 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means—graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN THE UNITED STATES OF AMERICA

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Advances in Chemistry Series M . Joan Comstock, Series Editor

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1989 ACS Books Advisory Board Paul S. Anderson Merck Sharp & Dohme Research Laboratories

Mary A. Kaiser Ε. I. du Pont de Nemours and Company

Michael R. Ladisch Alexis T. Bell Purdue University University of California—Berkeley Harvey W. Blanch University of California—Berkeley Malcolm H. Chisholm Indiana University Alan Elzerman Clemson University John W. Finley Nabisco Brands, Inc. Natalie Foster Lehigh University Marye Anne Fox The University of Texas—Austin G. Wayne Ivie U.S. Department of Agriculture, Agricultural Research Service

John L. Massingill Dow Chemical Company Daniel M. Quinn University of Iowa James C . Randall Exxon Chemical Company Elsa Reichmanis AT&T Bell Laboratories C. M. Roland U.S. Naval Research Laboratory Stephen A. Szabo Conoco Inc. Wendy A. Warr Imperial Chemical Industries Robert A. Weiss University of Connecticut

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Downloaded by 185.89.101.204 on May 14, 2016 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1990-0224.fw001

FOREWORD The ADVANCES IN CHEMISTRY SERIES was founded in 1949 by the American Chemical Society as an oudet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented because their papers would be distributed among several journals or not published at all. Papers are reviewed critically according to ACS editorial standards and receive the careful attention and processing characteristic of ACS publications. Volumes in the ADVANCES IN CHEMISTRY SERIES maintain the integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

ABOUT THE EDITORS

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J O H N M . Z E I G L E R is supervisor of the Physical

Chemistry and Mechanical Properties of Poly­ mers Division of Sandia National Laboratories in Albuquerque, N M . He received his B.A. in chemistry (summa cum laude) in 1974 from Wa­ bash College and his Ph.D. in organic chem­ istry from the University of Illinois in 1979. After two years with the American Cyanamid Company in Stamford, CT, working on carbocation chemistry in liquid HF, he joined San­ dia in 1981. He assumed his present position in 1985. His research interests center on the design, synthesis, properties, and applications of polymeric inorganic and organic electronic materials. His current research involves polysilanes, con­ ductive polymers, and polymers in microelectronics processing. He has coauthored more than 40 papers and holds seven U.S. and five foreign patents in these areas. He has been a plenary lecturer at a number of international meetings and received an IR-100 award in 1985 for the discovery of self-developing polysilane photoresists. In addition to serving as coorganizer of the International Topical Workshop "Advances in SiliconBased Polymer Science" in 1987, he has organized sessions dealing with σ-conjugated polymers (polysilanes) at several international meetings and has been a member of organizing committees for meetings dealing with microelectronics processing. He is a member of Phi Beta Kappa, the American Chemical Society, the American Physical Society, the American Association for the Advance­ ment of Science, SPIE (Society of Photo-Instrumentation Engineers), Sigma Xi, and Alpha Chi Sigma.

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.

Downloaded by 185.89.101.204 on May 14, 2016 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1990-0224.fw001

F. w. G O R D O N F E A R O N is technical director

and vice president for Dow Corning in Japan. He received his B.S. in chemistry from the University of Leeds and his Ph.D. in chemistry from the University of Wales for research in the silicon field. He carried out postdoctoral research in silicon chemistry at Iowa State University. He joined Dow Corning Corporation in 1968, and since then he has held a wide variety of research, development, and business management positions, with particular emphasis on expanding the scope of useful silicon science and technology.

Zeigler and Fearon; Silicon-Based Polymer Science Advances in Chemistry; American Chemical Society: Washington, DC, 1989.