Silver Ions Induce Lateral Etching of Gold Nanorods by K2PtCl4

Xia Guo , Xiaotong Li , Shufang Kou , Xianfeng Yang , Xi Hu , Daishun Ling , Jian Yang. Journal of Materials Chemistry A 2018 6 (17), 7364-7369 ...
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Article pubs.acs.org/Langmuir

Silver Ions Induce Lateral Etching of Gold Nanorods by K2PtCl4 Fang Xie,† Wei Ye,† HongYan Sun,† Shufang Kou,† and Xia Guo*,† †

Key Laboratory of Colloid, Interface Chemistry, Ministry of Education, School of Chemistry, Chemical Engineering, Shandong University, Jinan 250100, PR China S Supporting Information *

ABSTRACT: Selective etching is significant for fabrication of novel nanostructures. Here silver ions are introduced to control the lateral etching of gold nanorods by K2PtCl4 in a hot solution, producing a number of dumbbell-like PtAu-Au thin gold nanorods. Silver ions control the selective deposition of the reduced Pt0 atoms, causing the selective etching of the unprotected Au. The middle diameter of the obtained dumbbell-like nanorods can be adjusted from 12 nm to