SINGLE CRYSTALS OF SILVER

acid. After the action had continued for some time it was noticed that faces had appeared on the metal, and on examination it was found to be an octag...
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W. R. STEACIE AND F. J. TOOLE

[CONTRIBUTION FROM THE

Vol. 51

DEPARTMENT OF CHESIISTRY, MCGILLUNIVERSITY ]

SINGLE CRYSTALS OF SILVER BY E. W. R. STEACIE AND F. J. TOOLE RECEIVED X O V E M B E 13, R 1928

P U B L I S H EAPRIL D 5, 1929

A large number of metallic single crystals have been prepared. Hauser' has obtained symmetrical etch figures on spherical single crystals of copper and silver which show the crystallographic form of the metal. Various other workers have obtained rods or wires which consisted of one crystal. As far as we are aware, however, large single metallic crystals possessing the characteristic external form have not been previously prepared.

Experimental During the course of another investigation2 some very pure silver was prepared. The method of preparation was to dissolve silver nitrate in water and allow the solution to settle. Silver chloride was precipitated from the filtered solution by the addition 65" of duced hydrochloric to the metal acid. by boiling It was with then invert re-

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