SINGLY-BRIDGED COMPOUNDS OF THE BORON HALIDES AND

Herbert C. Brown, Peter F. Stehle, Paul A. Tierney. J. Am. Chem. Soc. , 1957, 79 (8) ... S. H. BAUER , J. V. MARTINEZ , D. PRICE , and W. D. JONES. 19...
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gas thermometer was PL-acuated, filled with lieliuiii gas and recalibrated. Siiiootlied values of Cp are given in Table I. plot of C p / Tzlcrsus T 2is presented (Fig. 1). Such a plot is, of course, linear over the region in which thr T3 I:LW is obeycd. TABLE I FIEAT C A P A C I l Y O F O R D E R E D

hfg,Cd

A1

R O T J ~ DTEEIMI P E R A -

IT*RT>

r

I,

4 6

G 7

Lt? J O I I l e i / D h fi atom

CD joules/ "K g atom

i OK

0 008

0 0820

9

0145 .0237 0370 0560

02 1 230 421 633

10 12 I4 1ii

axial ratio in zinc aiid cadmium. It is of interest to note that Xg3Cd also exhibits the niiniriiuin, despitc the fact that i t has n noriiial axial r a t i ~ . ~ , ~ The :tuthors wish to acknowledge tlie assiskuicc. of nlr. Kay F. Sterrett aiid X r , Cuido Gxlli i l l niaking the iiieasureniciits contained it1 this C O I ~ I inunication. (7) D. A . Edw:trds, IV. i C \Vnll.icr. ;m