Size-Dependent Metamorphosis of Electron Binding Motif in Cluster

Mar 18, 2012 - were studied with photoelectron spectroscopy. For both the amides, two band series due to distinct isomeric species in the multipole-bo...
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Article pubs.acs.org/JPCA

Size-Dependent Metamorphosis of Electron Binding Motif in Cluster Anions of Primary Amide Molecules Toshihiko Maeyama,* Keiji Yoshida, and Asuka Fujii Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan S Supporting Information *

ABSTRACT: Electron binding motifs in cluster anions of primary amides, (acetamide)n− and (propionamide)n−, were studied with photoelectron spectroscopy. For both the amides, two band series due to distinct isomeric species in the multipole-bound states were found in the low electron binding energy region (