Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon

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Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection Dmitry N. Dirin,†,‡ Ihor Cherniukh,†,‡ Sergii Yakunin,†,‡ Yevhen Shynkarenko,†,‡,§ and Maksym V. Kovalenko*,†,‡ †

Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland § Department of Photonic Processes, Institute of Physics, National Academy of Sciences of Ukraine, 46 Prospekt Nauky, Kyiv 03680, Ukraine ‡

S Supporting Information *

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Recently, several solution-based approaches to growing centimeter-scale perovskite SCs have been developed. They can be divided into three categories: (i) slow crystallization upon cooling saturated aqueous hydrohalic solutions17,32 or solutions in organic solvent,33 (ii) crystallization due to a change of the solvent polarity by slow antisolvent diffusion14,34 and (iii) inverse temperature crystallization (ITC),16,21,24,35−38 initially proposed by Bakr et al.24,36 In the lattermost method, crystallization is caused by the inverse solubility dependence on temperature in some organic solvents and the overall growth occurs relatively fast, e.g., within several hours. Centimeter-scale SCs of all MAPbX3 and FAPbX3 compositions can be grown by at least one of these three approaches, enabling studies of their intrinsic electronic8,14,39,40 and optical properties, which have been reported within the last year.4,15,41−43 On the contrary, the solution-based growth of fully inorganic CsPbX3 SCs remained elusive. Such all-inorganic analogs could perhaps overcome the known issues of chemical instability of hybrid perovskites.18,31,32 Although known since the 1950s, CsPbX3 perovskites have only recently received their rightful attention in the form of thin-films and nanocrystals, demonstrating promising potential in photovoltaics44 and for bright light emission.27 Thus far, high-quality CsPbBr3 and CsPbCl3 SCs could only be obtained via high-temperature growth from melts using the Bridgman method (at temperatures above 600 °C, in an evacuated quartz tube, using highly pure starting reagents).12,45−47 In this work, we present a simple and fast route to solution growth of CsPbBr3 SCs using the ITC method, under ambient atmosphere and using low-cost precursors. Obtained SCs can be handled in air and can be easily wet-polished using DMSO; all such treatments showed no substantial effect on the electric properties of SCs. We also report the sensitive detection of visible and gamma-photons as evidence of the high electronic quality of this material. We note that during the preparation of this paper, another report on solution-grown CsPbBr3 SCs by Rakita et al. was published,34 wherein a greater focus was placed on the antisolvent diffusion method or growth from

ead halide semiconductors with perovskite crystal structure and APbX3 stoichiometry [A = CH3NH3+ (methylammonium, MA+), CH(NH2)2+ (formamidinium, FA+), or Cs+; X = I−, Br−, Cl− or mixtures thereof] have recently become perhaps the most intensely studied class of inorganic optoelectronic materials. After exhibiting unprecedented performance as solution-processed absorbers in photovoltaics with certified power conversion efficiencies presently exceeding 22%,1 these materials were soon also used in light-emitting diodes,2 lasers,3 ultraviolet-to-infrared photodetectors4−7 as well as in X-ray8−10 gamma-ray (γ-ray) detectors.11−13 In these applications, solution- or Bridgman-grown large single crystals (SCs),4,8,12−18 thin-films or nanocrystalline forms of perovskites are utilized. Such a diversity of applications is to a large extent due to the so-called defect-tolerance19,20 of these semiconductors: a low density of electronic trap states despite a large density of point defects. Several commonly reported parameters exemplify the outstanding photophysical and electronic quality of perovskites: low densities of carriers (10 9 −10 11 cm−3 ),14,21 low densities of traps (109 −10 10 cm−3),14,22 which are lower than in monocrystalline Si,20 high carrier mobilities (2.5−1000 cm2 V−1 s−1),12,14,17,20,23 long charge carrier lifetimes (0.08−450 μs),12,14,16,17,24,25 long electron−hole diffusion lengths (2−175 μm),14,16,24 small carrier effective masses (0.069−0.25 m0),26 high optical absorption coefficients at the absorption edge (1−4.5 × 104 cm−1)20 and high luminescence efficiencies.27,28 The ability to grow semiconductors in the form of large SCs has always been of paramount technological and scientific importance. For instance, state-of-the-art Si solar cells are made from large SC ingots. SCs reflect, as close as possible, the intrinsic physical properties of a semiconductor and usually exhibit better electronic characteristics as compared to nano- or polycrystalline forms of the same compound. In the case of MAPbI3, for example, SCs exhibit carrier mobilities of up to 200 cm2 V−1 s−1 (vs 0.4−40 cm2 V−1 s−1 in thin-films) and lifetimes of up to 500 μs (vs 4.5−1000 ns in films and nanocrystals).17,20 Beyond studies of fundamental physical properties, SCs are required for the structural determination of novel compounds and for structural refinement of known materials.29,30 Perovskite SCs are notably also more chemically stable than their thin-film counterparts.31 © 2016 American Chemical Society

Received: October 8, 2016 Revised: November 20, 2016 Published: November 21, 2016 8470

DOI: 10.1021/acs.chemmater.6b04298 Chem. Mater. 2016, 28, 8470−8474

Communication

Chemistry of Materials antisolvent-containing solutions at rather low temperatures. In our experiments, nucleation and growth of crystals at temperatures higher than 88 °C, at which orthorhombic-totetragonal phase transition takes place,12 resulted in crystals with improved crystallinity and different morphology. In previous studies on hybrid perovskites, the optimal solvents for ITC growth were reported to be dimethylformamide (DMF), dymethylsulfoxide (DMSO), γ-butyrolactone and their mixtures.16,21,24,35−38 We find that the growth of CsPbBr3 is best carried out in dimethyl sulfoxide (DMSO). Specifically, a CsBr:PbBr2 solution (1:2 molar ratio, 1 M concentration of Pb) in a mixture of DMSO with cyclohexanol (CyOH) and DMF, was heated to 90 °C in a vial, leading to the formation of 1−3 nuclei. Subsequent heating to 110 °C led to further growth without additional nucleation. A several-mmlong, flat, orange-colored and optically clear SC was collected within several hours (Figure 1). The powder X-ray diffraction (XRD) pattern of the grounded SC (Figure 1e) is consistent with the orthorhombic modification of CsPbBr3, as previously reported.12 Starting with pristine CsBr and PbBr2, and considering the known phase diagram of the Cs−Pb−Br system,48 there are 3 plausible products of the above synthetic approach: Cs4PbBr6, CsPbBr3 and CsPb2Br5. Figure 1a summarizes the solubility of CsBr and various CsBr:PbBr2 mixtures in DMSO and indicates the identity of any observed precipitation products upon saturation. The limiting factor is the low solubility of pristine CsBr, whereas the solubility of PbBr2 is the highest (2 M at room temperature, not indicated in Figure 1a). The addition of PbBr2 notably increases the solubility of CsBr (Figure 1a,c) due to the formation of PbBrn(2−n) complexes, where n is 3 and above, thus reducing the [Cs+][Br−] product. In aqueous, DMF and other polar solutions, PbXn(2−n) anions (X = Br, I) with n = 3−5 have been commonly reported.31,49 Cs4PbBr6 is observed as the single precipitation product upon saturation of 4:1 CsBr:PbBr2 solutions. For 1:1 CsBr:PbBr2, we still find Cs4PbBr6 as a primary product (with small inclusions of CsPbBr3). Only upon an increase of the PbBr2 fraction (forming 1:2 CsBr:PbBr2 solutions) is the formation of the desired CsPbBr3 product with lower coordination number favored. Intermediate CsBr:PbBr2 ratios of 1:1.2 or 1:1.5 still result in a Cs-rich precipitate. A solution with a 1:2 CsBr:PbBr2 ratio produces pure CsPbBr3 precipitate at any temperature in the range of 25−110 °C (Figure 1a). As expected, the further increase in PbBr2 concentration leads to the precipitation of CsPb2Br5. The solubility of most compounds in Figure 1a is fairly independent of temperature. Only at a 1:2 ratio of CsBr:PbBr2 do we find a significant, ∼40% drop in the solubility between 75 and 90 °C. At these temperatures, such a behavior resembles the rarely observed phenomenon of retrograde solubility. This phenomenal has been generally explained by the negative enthalpy of solubilization,50 and the corresponding temperature coefficient of the solubility is then equal to −ΔH°/T2. Previous studies by Bakr et al.16,21,24,35,36 indicated the relevance of retrograde solubility to all FAPbX3 and MAPbX 3 compositions in DMF, DMSO and γbutyrolactone, and pointed to a complex interplay between the solvation of ions and complexation equilibria of PbXn(2−n). All compounds showed a steady decrease of solubility with increasing temperature, except for MAPbI3 where solubility increased until 60 °C and then decreased.36 A more complex behavior in our case, i.e. the coexistence of the temperatureindependent regions below and above the rather narrow

Figure 1. Temperature dependence of the solubility for CsBr, Cs4PbBr6, CsPbBr3 and CsPb2Br5 in (a) DMSO and (b) a DMSO/ CyOH/DMF mixture. (c) Effect of PbBr2 addition on CsBr solubility in DMSO and a DMSO/CyOH/DMF mixture. (d) Photographs of the obtained CsPbBr3 SCs. (e) Powder XRD patterns of the obtained SCs (brown) in comparison with the reported crystal structure of CsPbBr3 (ICSD card #97851).

retrograde solubility region, calls for additional considerations. One important factor might be an orthorhombic-to-tetragonal phase transition, reported to occur at 88 °C in thermodynamic equilibrium.12 The solubilities of each phase are likely to be different, causing a transition range on a solubility-temperature profile. Although a solubility gradient, such as the one in Figure 1a, in principle allows the growth of SCs, the particularly steep dependence for 1:2 CsBr:PbBr2 solutions in DMSO might also be problematic. Overly fast oversaturation upon heating causes the formation of multiple nuclei and/or polycrystals. We found that the solubility-temperature profile can be smoothened by the addition of CyOH or a CyOH/DMF mixture (Figure 1b). SC growth from such solvent mixtures led to better reproducibility of the results and only 1−3 crystals per vessel. These crystals nucleate at ∼90 °C and continue to grow at temperatures up to 110 °C without further nucleation. The best quality SCs were obtained at an overall growth rate of below 0.2 mm/h. 8471

DOI: 10.1021/acs.chemmater.6b04298 Chem. Mater. 2016, 28, 8470−8474

Communication

Chemistry of Materials Nucleation at 90 °C and above is critical for the formation of CsPbBr3 SCs with high optical clarity. Such SCs have rectangular, plate-like shape and behave as single crystals under polarized light (Figure 2). At growth rates higher than

Figure 2. Photograph of CsPbBr3 SCs in nonpolarized light and 0° and 45° polarized light. The uniform transparency of individual crystals and the change in transparency upon changing light polarization are shown. This indicates the single crystallographic orientation of each entire crystal.

Figure 3. (a) Transformed Kubelka−Munk spectrum of CsPbBr3 SCs. The inset shows the spectrum in a Tauc plot. (b) Photoresponsivity spectrum of CsPbBr3 crystals in the visible range. (c) Energy-resolved gamma-radiation spectrum of 241Am recorded with CsPbBr3 SCs biased at 40 V. (d) Photocurrent dependence on bias (black dots) fitted by a Hecht model (red line).

0.2 mm/h, the crystals have a tendency to grow faster in one direction (such as in prism-like shapes, ∼ 3 × 0.5 × 0.5 mm) and start appearing to have large scattering inclusions (Figure S1). Nucleation at lower temperatures leads to granular, turbid crystals, indicating polycrystallinity. Similar problems were encountered when trying alternative growth methods, e.g., via cooling of hydrohalic aqueous solutions or using slow diffusion of an ethanol:water mixture into DMSO solutions (details can be found in SI, Methods 2 and 3, respectively; photos exemplifying these crystals are shown in Figure S2). In these methods, nucleation and growth occurred at 25−70 °C. The optical absorption spectra of CsPbBr3 SCs is evaluated using diffuse reflectance data, analyzed through the Kubelka− Munk equation, and show step-like behavior at the band edge (Figure 3a). The spectrum can be fitted with a direct-gap Tauc plot (inset in Figure 3a) yielding a bandgap energy of about 2.254 eV. A similar value of 2.25 eV was reported for Bridgmangrown CsPbBr3 SCs.12 The transparency region can be used to calculate the refractive index from the reflectivity spectrum (Figure S3). A normal dispersion of refractive index from 2.3 to 2.2 for the wavelength region of 580−800 nm was observed. For electronic transport and photon detection measurements, we deposited electrodes of Ag paste on opposite facets of the SCs. We then tested CsPbBr3 SCs as detectors in the visible spectral region and, at higher energies, of gammaradiation from a 241Am source. The details of the experiments can be found in Supporting Information and in Figure S4. In the visible region, a 1 order of magnitude increase of the current could be detected under white light illumination with 5 mW·cm−2 power (inset in Figure 3b). The spectral responsivity under 10 V-bias shows a very sharp (∼20 nm fwhm, centered at 550 nm) peak showing a responsivity of 6 A/W. This peak is located near the CsPbBr3 bandgap energy and may indicate a so-called narrow-bandwidth detection regime.4,7 This can be explained by taking into consideration the spectral dependence of the absorbance. The peak photocurrent is seen at the longwavelength tail of the absorption spectrum, at ∼550 nm (compare Figures 3a and 3b). Because of low absorbance at

these wavelengths, such light is primarily absorbed within the bulk of the crystal. Even longer wavelengths correspond to higher and/or complete transmission of light, whereas short wavelength light is absorbed primarily within the surface region. The collection efficiency of the carriers generated at the surface or near-surface region can be poorer than that of carriers in the bulk, presumably due to a higher density of trap states at the surfaces. Overall, the interplay between the trapping at the surface and the wavelength-dependent absorbance leads to the appearance of a narrow photocurrent peak near the band-edge instead of simple cutoff behavior. Efficient photoconductivity in the bulk of a SC is a prerequisite for sensing deeply penetrating X-ray and especially gamma-photons. This inspired us to test our CsPbBr3 SCs for the detection of gamma-photons. We constructed a gammaphoton counting device, as detailed in the SI and in our previous studies on hybrid MAPbI3 and FAPbI3 SCs.11 A high count rate could be detected, similar to the hybrid perovskite SCs tested under identical conditions. We then attempted to perform energy-resolved counting using standard pulse-height analysis. With moderate cooling to −53 °C (220 K), we could detect a broad photopeak from a 241Am source, not seen at room temperature (Figure 3c). We also find that the increase of bias from 20 to 40 V notably shifts the photopeak to higher channels of the same multichannel analyzer and slightly improves the energy resolution, illustrating that chargecollection efficiency remains a strongly limiting factor. For efficient collection of carriers, a high mobility-lifetime product (μτ) is crucial. Together with the applied electric field, E, one can estimate carrier drift lengths as μτE. This drift length must be at least equal to the size of the whole SC for efficient collection of photocarriers. For the evaluation of μτ within the bulk of the crystal using electronic measurement, we have investigated the bias-dependence of the photoconductivity at 550 nm (Figure 3d), the wavelength at which we observed a peak photocurrent due to the prevalence of bulk transport. This dependence was then fitted with a Hecht model,51 yielding a μτ 8472

DOI: 10.1021/acs.chemmater.6b04298 Chem. Mater. 2016, 28, 8470−8474

Communication

Chemistry of Materials product of ∼2 × 10−4 cm2 V−1 which is slightly lower than in Bridgman-grown CsPbBr3 SCs.12 Typical μτ values for Cd1−xZnxTe, the present commercial room-temperature detector material, are close to 1 × 10−3 cm2 V−1. Similarly high values of 1−1.8 × 10−2 cm2 V−1 were also observed for SCs of hybrid perovskites MAPbI3 and FAPbI3 in our previous studies using the same measurement method.11 A smaller μτ product in CsPbBr3 than for hybrid perovskites can be attributed to shorter carrier lifetimes. In hybrid perovskites, asymmetric organic cations form asymmetric electric fields that assist in carrier separation, increasing carrier lifetimes.52 Furthermore, we compared the resistivity of solution-grown CsPbBr3 SCs (2 GΩ cm) with the best values reported for Bridgman-grown SCs (343 GΩ cm).12 Such a difference suggests that solution-grown SCs might incorporate impurities acting as electronic dopants or have higher concentration of defects, thus increasing the carrier density. Further work on the exclusion of these impurities might lead to higher resistances, and hence more closely representative intrinsic behavior, favorable for photon detection. In summary, we have shown that transparent CsPbBr3 SCs can be grown from DMSO solutions using the ITC method. Owing to the low density of traps and low carrier density, along with a moderately high carrier mobility and a high gammaphoton absorptivity due to being a heavy-metal based compound, a high sensitivity to gamma-irradiation can be demonstrated. We find that higher doping levels from impurities, as compared to Bridgman-grown SCs, still limits the energy resolution of gamma-counting. Further optimization of the proposed synthetic protocol may concern increasing the purity to reduce the doping level and also surface engineering to decrease the density of traps.



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ASSOCIATED CONTENT

S Supporting Information *

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.6b04298. Synthetic and characterization details, photos of CsPbBr3 crystals, refractive index (PDF)



AUTHOR INFORMATION

Corresponding Author

*M. V. Kovalenko. E-mail: [email protected]. ORCID

Dmitry N. Dirin: 0000-0002-5187-4555 Maksym V. Kovalenko: 0000-0002-6396-8938 Author Contributions

The paper was written through contributions of all authors. Notes

The authors declare no competing financial interest.



ACKNOWLEDGMENTS We acknowledge financial support from the European Union through the FP7 (ERC Starting Grant NANOSOLID, GA No. 306733) and Dr. Nicholas Stadie for reading the paper.



REFERENCES

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DOI: 10.1021/acs.chemmater.6b04298 Chem. Mater. 2016, 28, 8470−8474