J. Phys. Chem. B, Vol. 112, No. 1, 2008 187
ADDITIONS AND CORRECTIONS
2007, Volume 111B Priscilla L. Silva, Erick L. Bastos, and Omar A. El Seoud*: Solvation in Binary Mixtures of Water and Polar Aprotic Solvents: Theoretical Calculations of the Concentrations of Solvent-Water Hydrogen-Bonded Species and Application to Thermosolvatochromism of Polarity Probes Page 6178. Table 4 was printed incorrectly in the version of this Article published on Articles ASAP on May 16, 2007, and printed in the June 7, 2007 issue (Vol. 111, No. 22, pp 6173-6180). The correct version of the table is printed below. TABLE 4: Analysis of Thermosolvatochromic Data in Aprotic Solvent Mixtures probe
solvent acetone
WB DMSO acetone RB DMSO
temperature (°C)
m
φW/S
φS-W/S
φS-W/W
ET(S)
ET(W)
ET(S-W)
chi2
r2
10 25 40 25 40 60 10 25 40 25 40 60
0.997 0.975 0.953 1.070 1.047 1.029 1.209 1.143 1.128 1.321 1.289 1.236
2.907 2.969 3.067 0.412 0.452 0.476 2.475 2.516 2.547 0.490 0.519 0.545
20.098 18.488 16.729 2.417 2.358 2.284 41.697 39.455 35.168 3.285 3.160 2.968
6.913 6.277 5.455 5.869 5.219 4.798 16.847 15.681 13.808 6.704 6.089 5.442
51.80 [( 0.12] 51.34 [( 0.09] 50.56 [( 0.10] 54.28 [( 0.08] 53.97 [( 0.18] 53.66 [( 0.18] 42.62 [( 0.19] 42.13 [( 0.22] 41.71 [( 0.15] 45.35 [( 0.08] 44.94 [( 0.14] 44.62 [( 0.07]
70.72 [( 0.12] 70.26 [( 0.09] 69.77 [( 0.10] 70.27 [( 0.09] 69.91 [( 0.19] 69.35 [( 0.19] 63.69 [( 0.18] 63.17 [( 0.21] 62.65 [( 0.15] 63.08 [( 0.11] 62.65 [( 0.18] 62.24 [( 0.09]
58.37 [( 0.53] 57.08 [( 0.52] 55.59 [( 0.78] 61.83 [( 0.58] 61.25 [( 1.39] 60.60 [( 1.59] 51.02 [( 0.41] 50.38 [( 0.54] 49.53 [( 0.50] 49.13 [( 0.15] 48.41 [( 1.68] 48.41 [( 0.93]
0.0170 0.0094 0.0129 0.0101 0.0424 0.0417 0.0405 0.0539 0.0270 0.0295 0.0394 0.0097
0.9996 0.9997 0.9997 0.9998 0.9990 0.9990 0.9992 0.9988 0.9994 0.9994 0.9993 0.9998
10.1021/jp0795560 Published on Web 12/08/2007
