Supporting information Solvent Blends can Control Cationic Reversed Micellar Interdroplet Interactions. The Effect of n-Heptane:Benzene Mixture on BHDC Reversed Micellar Interfacial Properties: Droplet Sizes and Micropolarity
Federico M. Agazzi, R. Dario Falcone, Juana J. Silber, N. Mariano Correa* Departamento de Química. Universidad Nacional de Río Cuarto. Agencia Postal # 3. C.P. X5804BYA Río Cuarto. ARGENTINA
* Author to whom correspondence should be addressed. Email:
[email protected] 0,6
XH p
B2
0 0.13 0.21 0.30 0.38
Absorbance
0,5 0,4 0,3
B1
0,2 0,1 0,0 400
500
600
700
/ nm
Figure S1. QB absorption spectra in the n-heptane:benzene mixture at different XHp values. [QB] = 2x10-4M.
0.30
A
[BHDC] / M 0 -4 1x10 -3 1x10 -3 8x10 3x10-2 0.1 0.15
0.25
Abs
0.20 0.15 0.10 0.05 0.00 400
500
600
700
/ nm 0.45 0.40
[BHDC] / M 0 -4 1x10 -3 1x10 -3 8x10 -2 3x10 0.1 0.15
B
0.35
Abs
0.30 0.25 0.20 0.15 0.10 0.05 0.00 400
500
600
700
/ nm
Figure S2. QB absorption spectra in water/BHDC/n-heptane:benzene reversed micelles media at XHp = 0.30 at different BHDC concentration. (A) W0 = 0; (B) W0 = 5. [QB] = 2x10-4M.
