Solvolytic acceleration accompanying (trimethylsilyl)methyl migration

Mar 1, 1990 - Mizue Fujio , Tohru Nakashima , Ryoji Fujiyama , Hyun-Joong Kim , Yuho Tsuno. Journal of Physical Organic Chemistry 2000,612 ...
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J . Am. Chem. Soc. 1990, 112, 2834-2835

2834

provide an attractive general strategy for the incorporation of COz into useful organic molecules, and further experiments along these lines are being pursued in our laboratory. Acknowledgment. This work was supported in part by the Office of Naval Research. Registry No. 12-2K+, 1 13303-46-1; 22-2K+, 125666-44-6; 22-2K+ ( T O 2 labeled), 125666-48-0; 3-K+, 1 13303-48-3; 4-K+, 125666-45-7; 5, 125666-46-8; 6-K+. 125666-47-9; 6-K+ ("CO, labeled), 125666-49-1; [Cr(9S-C6H6C02SiMe2Bu-t)(CO),11