Sonochemical Preparation and Characterization of Europium Oxide

Jul 11, 2000 - Sonochemical Preparation and Characterization of Europium Oxide Doped In and Coated On ZrO2 and Yttrium-Stabilized Zirconium (YSZ)...
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J. Phys. Chem. B 2000, 104, 7057-7065

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Sonochemical Preparation and Characterization of Europium Oxide Doped In and Coated On ZrO2 and Yttrium-Stabilized Zirconium (YSZ) A. Gedanken,*,† R. Reisfeld,‡ E. Sominski,† O. Palchik,† Yu. Koltypin,† G. Panczer,§ M. Gaft,| and H. Minti‡ Department of Chemistry, Bar-Ilan UniVersity, Ramat-Gan, 52900, Israel, Department of Inorganic and Analytical Chemistry, The Hebrew UniVersity of Jerusalem, 91940, Israel, Laboratoire de Physico-Chimie des Materiaux Luminescents, UniVersite´ Claude Bernard-Lyon 1, UMR 5620 CNRS, France, and Physics and Geology Groups, The Open UniVersity of Israel, 16 Klausner Street, Tel-AViV, 61392, Israel ReceiVed: February 18, 2000

Ultrasound radiation was used to prepare Eu2O3 dd in zirconia and yttrium-stabilized zirconium (YSZ) nanoparticles. Europium oxide was also coated on the surface of submicron spherical zirconia and YSZ, which were fabricated by wet chemical methods. The coating process also used ultrasonic waves. Time decay measurements of the doped and coated materials were conducted using a pulsed laser source. Lifetimes