Sources and Fates of Aquatic Pollutants - ACS Publications

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Downloaded by KAOHSIUNG MEDICAL UNIV on June 10, 2018 | https://pubs.acs.org Publication Date: June 15, 1987 | doi: 10.1021/ba-1987-0216.fw001

Sources and Fates of Aquatic Pollutants

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

Downloaded by KAOHSIUNG MEDICAL UNIV on June 10, 2018 | https://pubs.acs.org Publication Date: June 15, 1987 | doi: 10.1021/ba-1987-0216.fw001

ADVANCES IN CHEMISTRY SERIES

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Sources and Fates of Aquatic Pollutants Ronald A. Hites,

EDITOR

Indiana University S. J. Eisenreich, E D I T O R University of Minnesota

Developed from a symposium sponsored by the Division of Environmental Chemistry at the 190th Meeting of the American Chemical Society, Chicago, Illinois, September 8-13, 1985

American Chemical Society, Washington, DC 1987

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

216

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Library of Congress Cataloging-in-Publication Data Sources and fates of aquatic pollutants. (Advances in chemistry series, ISSN 0065-2393; 216) "Developed from a symposium sponsored by the Division of Environmental Chemistry at the 190th Meeting of the American Chemical Society, Chicago, Illinois, September 8-13, 1985." Includes bibliographies and indexes. 1. Water—Pollution—Congresses. 2. Organic water pollutants—Congresses. 3. Water chemistry— Congresses. 4. Hydrodynamics—Congresses. 5. Chemical reaction, Rate of—Congresses. I. Hites, Ronald Α. II. Eisenreich, S. J. III. American Chemical Society. Division of Environmental Chemistry. IV. American Chemical Society. Meeting (190th: Chicago, Ill.) V. Series. QD1.A355 no. 216 [TD425] ISBN 0-8412-0983-9

540 s

[628.1'68]

87-1290

Copyright © 1987 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, M A 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means— graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN THE UNITED STATES OF AMERICA

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

Advances in Chemistry Series Downloaded by KAOHSIUNG MEDICAL UNIV on June 10, 2018 | https://pubs.acs.org Publication Date: June 15, 1987 | doi: 10.1021/ba-1987-0216.fw001

M. Joan Comstock, Series Editor 1987 Advisory Board Harvey W. Blanch University of California—Berkeley

Vincent D. McGinniss Battelle Columbus Laboratories

Alan Elzerman Clemson University

W. H . Norton J. T. Baker Chemical Company

John W. Finley Nabisco Brands, Inc.

James C . Randall Exxon Chemical Company

Marye Anne Fox The University of Texas—Austin

E . Reichmanis A T & T Bell Laboratories

Martin L. Gorbaty Exxon Research and Engineering Co.

C . M . Roland U.S. Naval Research Laboratory

Roland F. Hirsch U.S. Department of Energy

W. D. Shults Oak Ridge National Laboratory

G . Wayne Ivie USDA, Agricultural Research Service

Geoffrey K. Smith Rohm & Haas Co.

Rudolph J. Marcus Consultant, Computers & Chemistry Research

Douglas B. Walters National Institute of Environmental Health

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

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FOREWORD The A D V A N C E S I N C H E M I S T R Y S E R I E S was

founded in 1 9 4 9 by

the American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented because their papers would be distributed among several journals or not published at all. Papers are reviewed critically according to ACS editorial standards and receive the careful attention and processing characteristic of ACS publications. Volumes in the A D V A N C E S I N C H E M I S T R Y S E R I E S maintain the

integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.

Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

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ABOUT T H E EDITORS R O N A L D A. HITES is Professor of Public and Environmental Affairs and Professor of Chemistry at Indiana University. He received a B.A. in chemistry in 1964 from Oakland University and a Ph.D. in analytical chemistry in 1968 from the Massachusetts Institute of Technology. He began his academic career as an Assistant Professor of Chemical Engineering at the Massachusetts Institute of Technology. Since 1979, he has been at Indiana University. Professor Hites is an editor of Biomedical and Environmental

Mass

Spectrometry

and Chemosphere

and has been

a member of numerous review committees at various national laboratories. He has been a member of two National Academy of Sciences committees and is a member of the American Chemical Society, the American Society for Mass Spectrometry, Sigma Xi, the Geochemical Society, and the International Association for Great Lakes Research. He is currently president-elect of the American Society for Mass Spectrometry. Professor Hites created a 1-week intensive course on "Environmental Applications of Gas Chromatographic Mass Spectrometry". This course has been offered since 1979 and has been taken by more than 250 people. Professor Hites is the author of more than 100 papers on mass spectrometry and organic environmental chemistry.

S. J. E l S E N R E I C H is Professor of Environmental Engineering Sciences in the Department of Civil and Mineral Engineering at the University of Minnesota in Minneapolis. He received a B.S. degree in chemistry from the University of Wisconsin—Eau Claire; an M.S. degree in analytical chemistry from the University of Wisconsin—Milwaukee; and a Ph.D. degree in water chemistry from the University of Wisconsin—Madison. Dr. Eisenreich joined the faculty of the University of Minnesota in 1975. He has published numerous articles on the transport and fate of nonpolar organic contaminants in large lakes, the impact of atmospheric deposition of trace metals and organic contaminants on aquatic ecosystems, and the biogeochemistry of wetlands. He has edited or coedited two books on atmospheric deposition to lakes and on polychlorinated biphenyls (PCBs) in the Great Lakes. He serves on the editorial advisory board of Environmental Science & Technology and on the editorial board of Water, Air and Soil Pollution, and is Associate Editor of the Journal of Great

Lakes

Research.

He is a frequent consultant to government and industry

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Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

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on the fate and transport of toxic organic contaminants in surface water and groundwater. Current research programs include the study of benthic processes in the Great Lakes using a deep-diving submersible, aquifer thermal energy storage, the chemical limnology of PCBs, interactions of organic chemicals with solids, biogeochemistry of bogs, and atmospheric chemistry and deposition of organic contaminants.

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Hites and Eisenreich; Sources and Fates of Aquatic Pollutants Advances in Chemistry; American Chemical Society: Washington, DC, 1987.