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Probing the Electronic Structures of BaTiO/SrTiO Multilayered Film with Spatially Resolved Electron Energy-Loss Spectroscopy Guiju Liu, Yiqian Wang, Bin Zou, Wenshuang Liang, Neil McN. Alford, David W. McComb, and Peter K. Petrov J. Phys. Chem. C, Just Accepted Manuscript • DOI: 10.1021/acs.jpcc.6b03833 • Publication Date (Web): 12 Jul 2016 Downloaded from http://pubs.acs.org on July 13, 2016
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The Journal of Physical Chemistry
Probing the Electronic Structures of BaTiO3/SrTiO3 Multilayered Film with Spatially Resolved Electron Energy-Loss Spectroscopy Guiju Liu,1,† Yiqian Wang,1, †,* Bin Zou,2 Wenshuang Liang,1 Neil M. Alford,2 David W. McComb,2 Peter K. Petrov2 1
College of Physics & The Cultivation Base for State Key Laboratory, Qingdao
University, No. 308 Ningxia Road, Qingdao, 266071, People’s Republic of China 2
Department of Materials, Imperial College London, London, SW7 2AZ, United
Kingdom
Abstract A multilayered film of BaTiO3/SrTiO3 was grown on a LaAlO3 substrate using dual-target pulsed laser deposition technique. High-resolution scanning transmission electron microscopy observations show that nine unit-cell BaTiO3 layer and three unit-cell SrTiO3 layer are alternatively arranged in the epitaxial film where a sharp interface exists between the BaTiO3 and SrTiO3 layers. Electron energy-loss spectroscopy analysis demonstrates that the O-K edge spectra of SrTiO3 and BaTiO3 layers are quite distinct, in particular, the energy-loss peak at 547 eV in the SrTiO3 spectrum splits into two peaks in the BaTiO3 spectrum. The multiple-scattering calculations of O-K edge spectra for BaTiO3 and SrTiO3 agree well with the experimental results. The low energy region (
