Stability of some transition metal ion complexes with a linear aliphatic

(+)[Mnm((-)-5,14-[14]aneN4)Bn]PF6, 53228-47-0; (+)[Cuii-. (H-5,14-[14]aneN4)](C104)2, 53447-11-3; (+)[N'in((-)-5,14-. [14]aneN4)](C104)2, 52553-45-4; ...
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302 Inorganic Chemistry, Vol. 14, No. 2, 1975

Barbucci, Paoletfi, and Vacca

A ~ ~ n o w ~ We e d wish ~ ~ lo~ thank ~ ~ .the donors of the Petroleum Research Fund, administered by the American Chemical Society, and the Colgate Research Council for their support. We are also grateful to M-r. Jeffrey B. Kessler? a Colgate student, for his assistance with the compound preparations.

7. S. Davis, J. P. Facklcr. and M. J. Weeks. Znorg. Chem., '7, 1994 (1968). R. Dingle, Inorg. Chem., 4. 1287 (1965).

Registry No. (+) [ Mn1I1((-)-5,14- [ 14]aneN4)Clz]PFs, 53228-45-8; (+) [MnIII((-)-5,14- [ 141aneN4)Brz]PF6, 53228-47-0; ( e )[cull((-)-5,14- [ 141aneN4)] (C104)2, 53447- I 1-3; (+) [KiII( (-)-5,14[14]aneN4)](Cl04)~,52553-45-4; (+)[Nir1((-)-5,14-[14]aneN4)(d-tart)], 53 166-27-1; (-)-5,14- [ 141aneN4. 53 187-8 1-8.

W. .J. Gearg, Coord. Chem. Rev., 7. 81 (1971). V. Katovic. L. Lindoy, and D. H. Busch, J . Chem. Educ.. 49. I17 (1972). N.F. Curtis, Y . hf. Curtis, and H. I