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Mar 7, 2008 - Stereoselective synthesis of styryllactone (+)-cardiobutanolide was accomplished in good overall yield from d-(â)-tartaric acid. Key features of the synthesis include the elaboration of a γ-hydroxy butyramide obtained from the dimeth
Stereoselective synthesis of the proposed American coneflower juvenile hormone mimic. Some observations on the cyclopropylcarbinyl rearrangement in ...
3056 Table I.
Rate Constants" for Reductions of Cobalt(II1) and Chromium(II1) Thiocyanate and Isothiocyanate Complexes ~~
M *+
7
React ion
Fez+
Cr 2+
+ M2+ + [(NH&CoSCNM "I* + M2++ [(NH~)~COSM~+]*
(NHz)jCoSCN2+ (NH3)aCoSCNZ+
1 . 9 X 106 0 . 8 x 105
1.2
x
10-1
C N (NH3)aCoNCS2+ M z ++ [(NH3)aCoNCSM4+]* (Hz0)sCrSCN2+ Mz++ [(H20)aCrSCNM4+]* (HzO)KrNCSz+ M z ++ [(H%O)sCrNCSM4+]*
