Studies on the Absorption of Light Oils from Gases. - ACS Publications

light oil content of coal gas as carbonization proceeds, ... hour was rich in light oil; after that the content steadily ... sistance of Mr. MacGregor...
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T H E J O U R N A L OF I N D U S T R I A L A N D ENGINEERING C H E M I S T R Y

7 18

PRELIMINARY W O R K CENTRATION

OF

PRODUCED

O N T H E VARIATION I N T H E CONLIGHT

AT

O I L S I N THE

VARIOUS

COAL

STAGES

GAS

OF

CARBONIZATION

We have shown above t h a t t h e differential pressure method, bulbs of liquid benzene being used, gives a n easy and fairly accurate method for the estimation of the light oil content of a gas mixture. I n order t o obtain some idea of t h e change in t h e light oil content of coal gas as carbonization proceeds, we carried out the following experiments on one of t h e retorts of the Winnipeg Electric Railway Gas Plant: Through a hole drilled in the door of the retort, samples of gas were drawn off from time t o time, washed with water, and t h e light oil content estimated. A 340 cc. estimat‘ion flask was filled b y displacement of air with 2 t o 3 liters of gas. This was not sufficient and the results are probably low, though they are comparable with each other, as the treatment was uniform throughout. Light Oil Content of Gas Cm. H g

TIME Min.

0.94

O(a)

0.70 13 0.56 52 0.29 102 0.21 186 227 240Jb) ( a ) Retort charged with coal. ( b ) Carbonization complete, retort emptied.

I t will be seen t h a t the gas which came over the first hour was rich in light oil; after t h a t the content steadily declined. COMMERCIAL POSSIBILITIES

OF T H E METHOD PARTICU-

LARLY I N CONTROLLING T H E PROCESS O F A B SORPTION OF LIGHT OILS A T RECOVERY P L A N T S

Before the comple