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ACCOUNTS OF CHEMICAL RESEARCH Accounts of Chemical Research (ISSN 0001-4842) is published monthly by the American Chemical Society at 1155 16th Street, N.W., Washington, DC, 20036. Second-class postage paid at Washington, DC and additional mailing offices. POSTMASTER: Send address changes to Membership & Subscription Services, PO Box 3337, Columbus, OH, 43210. © Copyright, 1983, by the American Chemical Society. Permission of the American Chemical Society is granted for libraries and other users to make reprographic copies for use beyond that permitted by Section 107 or 108 of the U.S. Copyright Law, provided that the copying organization pay the appropriate per-copy fee through the Copyright Clearance Center, Inc., 21 Congress St., Salem, MA 01970. For reprint permission, please write to the Copyright Administrator, Books and Journals Division, at the ACS Washington address. Editorial Information Accounts of Chemical Research publishes concise, critical reviews of research areas currently under active investigation. Most articles are written by scientists active in the area reviewed. Reviews may be concerned in large part with work in the author's own laboratory, providing that relevant contributions by other investigators are mentioned sufficiently to place the author's research in perspective. Also published are occasional articles in which the author offers a critical assessment of a subject that has become somewhat muddled or even controversial, and proposes unifying concepts to clarify it. Articles should be directed concurrently to a general audience of research-minded chemists and to scientists directly concerned with the sub-

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ject of the article. In general, the first four or five pages of the manuscript should be directed mainly to the general reader, providing background and orientation as well as discussion of specialized terms or concepts. Because of the limited amount of journal space available, the usual allotment per article is 6 journal pages, corresponding roughly to a total of 25 pages of manuscript, including tables, bibliography, and drawings. Many articles are solicited by the Editor. Others are submitted on encouragement by the Editor after inquiry by a prospective author. Manuscripts submitted without prior consultation are also considered. All manuscripts are sent for review to competent reviewers, as part of the editorial process. Accounts of Chemical Research also publishes some correspondence from readers concerning the general theme of chemical research, or concerning the content of this journal. However, letters communicating new research results are not accepted for publication. The acceptance of letters is subject to standard constraints such as moderate length, good taste, and avoidance of redundancy. Manuscripts for publication and editorial correspondence prior to acceptance of manuscripts for publication should be sent to Joseph F. Bunnett, Editor, University of California, Santa Cruz, CA 95064. Manuscripts should be prepared in accordance with the general instructions given in "Handbook for Authors of Papers in American Chemical Society Publications" (available from Distribution Office at the ACS Washington address). They should be typed double spaced, submitted in quadruplicate, and accompanied by a completed copyright transfer form (see January issue). Additions and Corrections are published in the December issue. Correspondence regarding accepted papers and proofs should be directed to the Journals Department at the address shown below. Bulk reprints of individual articles are available. For information write to Distribution Office at the ACS Washington address.

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New and renewal subscriptions must be sent with payment to the Office of the Treasurer, Financial Operations, at the ACS Washington address. Subscriptions are available only on a calendar year basis. Rates above do not apply to nonmember subscribers in Japan, who must enter subscription orders with Maruzen Company Ltd., 3-10 Nihonbashi 2-chome, Chuo-ku, Tokyo 103, Japan. Tel: (03) 272-7211. Printed edition single issue prices: current year $7.00; prior year $7.75. Back volume price: $85.00. Foreign postage additional. Mail orders should be sent to Distribution Office at the ACS Washington address. Phone orders can be placed for printed, microfiche, and microfilm editions by calling the Books and Journals Division Sales Office toll free at (800) 424-6747 from anywhere in the continental United States; Washington, DC, area call (202) 8728065. Phone orders can be charged to Visa or MasterCard accounts. Changes of address must include both old and new addresses with ZIP code and a recent mailing label. Send all address changes to Membership & Subscription Services. Please allow six weeks for change to become effective. Claims for missing numbers will not be allowed if loss was due to failure of notice of change of address to be received in the time specified; if claim is dated (a) North America: more than 90 days beyond issue date, (b) all other foreign: more than one year beyond issue date; or if the reason given is "missing from files". Hard copy claims are handled by Membership & Subscription Services.

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V0LUME16 EDITOR JOSEPH F. BUNNETT ASSOCIATE EDITORS Joel E. Keizer John E. McMurry EDITORIAL ADVISORY BOARD Robert Abeles Richard Bernstein R. Stephen Berry Michel Boudart Maurice M. Bursey Edward A. Collins John T. Gerig Jenny P. Glusker Kendall N. Houk Jay K. Kochi Maurice M. Kreevoy Theodore Kuwana Ronald N. McElhaney Kurt Mislow George W. Parshall Kenneth N. Raymond Anthony M. Trozzolo Gene G. Wubbels Published by the AMERICAN CHEMICAL SOCIETY 1155 16th Street, N.W. Washington, D.C. 20036 BOOKS AND JOURNALS DIVISION D. H. Michael Bowen, Director Journals Department: Charles R. Bertsch, Head; Marianne C. Brogan, Associate Head; Mary E. Scanlan, Assistant Manager Marketing and Sales Department: Claud K. Robinson, Head Production Department: Elmer M. Pusey, Jr., Head Research and Development Department: Seldon W. Terrant, Head The American Chemical Society and its editors assume no responsibility for the statements and opinions advanced by contributors. Views expressed in the editorials are those of the writers and do not necessarily represent the official position of the American Chemical Society.

Office; Copyright 1983 by the American Chemical

NUMBER 1

Society

J A N U A R Y , 1983

Accounts Is Scrutinized It is desirable for all activities carried out on behalf of a society to be reviewed periodically. No matter how fine the performance of a bureau, a committee, or a journal once was, it may gradually change. We all know that a fine restaurant may gradually drift in the quality of its cuisine, the attractiveness of its decor, or the courtesy of its staff. It is in effect reviewed constantly by its customers and their judgment is declared very clearly in volume of sales. But such feedback is attenuated in the case of a journal. There is a big inertia factor in journal subscriptions. A few years ago the American Chemical Society undertook to monitor routinely all the journals it publishes, at the rate of one or two per year. In 1981 came the turn of Accounts of Chemical Research. A task force was organized, comprising nine distinguished chemists who represent different areas of chemistry and types of institutional affiliation. The task force was assisted by the ACS Books and Journals User Studies Program. Questionnaires were sent to all U.S. and foreign authors who published in Accounts in 1977 through 1981, to 396 randomly selected U.S. member subscribers, to all U.S. subscribers who discontinued their subscriptions at the end of 1981, and to Chairman of all ACS Divisions. There was a high rate of return of questionnaires, and the collated results are of much value. The general conclusion of the review, as announced by the ACS Committee on Publications, to which the task force reported, is that the scientific and intellectual health of Accounts is good. There were however some criticisms. The task force expressed a perception that some articles published in recent years were rather specialized and were therefore of interest only to a limited clientele. It also recommended that the representation of solicited manuscripts be increased, and the Committee added a recommendation that there be a more rapid turnover of personnel on the Editorial Advisory Board. These recommendations have been duly noted. There are features of interest in the questionnaire replies, especially in comments quoted verbatim. One is a fairly general recommendation, from all classes of respondents, that the representation of theoretical chemistry be decreased. We admit to being somewhat surprised at this, for we have not thought that field to be overemphasized in Accounts. Indeed, a count of field representation in Vol. 12 and 13 showed only 8 of 135, or 6%, of the articles to be concerned primarily with theoretical chemistry. We wonder whether the respondents were specifically protesting the theoretical chemistry content of Accounts or whether they were expressing a more general opinion. There were also, as might have been expected, contradictory recommendations. Thus, some said Accounts has too much biological chemistry while others said not enough. But some of the recommendations were more consistent, and they will significantly guide us in the future. Respondents of all classes indicated satisfication with our policy of keeping articles short. Our view has long been that readers are more likely to read an article through to the end if it is rather short, and thus that our policy serves the interests of authors as well as readers. Accounts authors agree, according to the questionnaire responses. However, we can report that an occasional author, while stating general satisfaction with this policy, points out that the special characteristics of his topic are such as to warrant extra space. When we receive three or four such statements in the same week we note with wry amusement that authors are human beings just as you and we are. Joseph F. Bunnett