Musr Chemicals for the War,ami
After
TWO En aA 1 ILE
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SUlf^URYL CHLORIDE AND T H I O N Y L
CHLORIDE
Now is t h e time to get a head-start in the T h e s e t w o h i g h l y reactive inorganic chlorine post-war race for business. N o w is the ' compounds are particularly useful in the protime t o discuss w i t h H O O K E R chemists duction of a variety of organic chemicals. Sulthe plans you have made for the day f uryi Chloride may b e used to produce ehlor when victory removes war restrictions. Yout ideas plus o u r p h e n o l s w h i c h are used as antiseptics and disinfectants. In ideas may help both of us i n drawing on chemistry's limit* t h e presence o f organic peroxide catalysts, the reaction of less resources in t h e world of tomorrow. Sulfuryl Chloride w i t h hydrocarbons, organic acids and Ask for list N - 1 0 of principal H O O K E R products w i t h chlorides produces desired products with the exclusion of chemical formulas, descriptions, uses and s h i p p i n g c o n unwanted isomers or by-products. For example only m-xylyl tainer data. chloride i s obtained w h e n m-xylene is reacted with Sulfuryl Chloride. W i t h aliphatic hydrocarbons and benzoyl peroxide as catalyst, Sulfuryl Chloride will | H O O K E R SPECIFICATIONS | introduce only o n e chlorine atom per carbon atom. THIONYL CHLORtOE j SULFURYL CHLORIDE Thionyl Chloride is most useful in replacing with 1 Formula SOCh J SOftCfe chlorine t h e hydroxy group i n organic compounds. Fatty acid chlorides and alkyl chlorides from alcohols Thionyl Chloride is a clear, 1 Sulfuryl Chloride is ο water colorless liquid with a pun· I clear .heavy liquid with an 1 Description are typical of this reaction. A n interesting application gent irritating odor. 1 «xtremely pungent odor. i s in the manufacture of the synthetic anti-malarial "Atabrine**. Acid anhydrides may b e produced by Hooker Sulfuryl Chloride High Grade is practically colorless, using* one molecule of Thionyl Chloride for t w o molehas a boiling range o f 2° Hooker Thionyl Chloride is a 1 including 69.1 and is at least cules of t h e acid. T h i o n y l Chloride usually does not [ Specification* colorless to yellow or green 1 ° ° % pure Sulfuryl Chloride. liquid. 1 react w i t h aldehyde, ketone or ëthoxy groups and H o o k e r ' S u l f u r y r Chloride Technical is light yellow in may therefore be used w i t h acids of complicated color; it is not distilled. structure 'where o n e o f these groups is located near 5 gallon carboys j | Shipping 5 gallon carboys t h e carboxyl g r o u p . holding 05 lbs. net holding 65 .lbs, net 1 1 "Containers Thionyl Chloride acts as a dehydrating agent and is 1 2 gallon carboys 5 5 gallon steel drums 1 a n aid in the preparation o f esters. Xhis action is holding; 150 lbs. net ί holding 725 lbs. net 1 especially valuable i n the prodtsttk «i of esters of 5 S gallon steel drums holding 725 lbs. net phenols. Send for Technical Boll****; * 2P. VICTORY
U.
SPECIFICATIONS
HONKER
5.
WAR
BONOS
EVERYBODY -
ELECTROCHEMICAL
EVERY
PAY
DAY
COMPANY
NIAGARA FALLS, NEW YORK New York. Ν. Υ.
·
Tacoma, Wash.
*
Wilmington, Calif.
HOOKER CHEMICALS V O L U M E - 2 1 ; JN*©:
20
OCTOBER
2 5,
1943
pp441S
1693
