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Interface-Rich Materials and Assemblies
Surface with Reversible Green-light-switched Wettability by Donor-Acceptor Stenhouse Adducts Haiquan Zhao, Dongsheng Wang, Yue Fan, Mingrui Ren, Shumin Dong, and Yonghao Zheng Langmuir, Just Accepted Manuscript • DOI: 10.1021/acs.langmuir.8b03296 • Publication Date (Web): 19 Nov 2018 Downloaded from http://pubs.acs.org on November 23, 2018
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Langmuir
Surface with Reversible Green-light-switched Wettability by Donor-Acceptor Stenhouse Adducts Haiquan Zhao1, Dongsheng Wang1*, Yue Fan2, Mingrui Ren1, Shumin Dong1, Yonghao Zheng1,3* 1. School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 610054, China 2. Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu, 610054, China 3. Center for Applied Chemistry, University of Electronic Science and Technology of China, Chengdu, 610054, China E-mail:
[email protected] (D. Wang),
[email protected] (Y. Zheng) KEYWORDS: donor-acceptor Stenhouse adducts, photoresponsive system, wettability, surface, green light
ABSTRACT
In this report, we designed surfaces with reversible green-light-switched wettability by DonorAcceptor Stenhouse adducts (DASAs). Photoresponsive micro/nanoparticles were prepared by coating polydopamine on the surface of silica micro/nanoparticles and then post-modifying with DASA molecules. Then, the particles were immobilized on glass substrates surface either
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polydimethylsiloxane.
Silica
micro/nanoparticles with various diameters (0.2, 2.5 and 85 µm) were used to fabricate the photoresponsive surface. Green light irradiation switches the hydrophobic linear DASA to hydrophilic cyclic isomer, which further increases the wettability and contact angle hysteresis on surface. On the other hand, heating (100 oC) induces the cyclic-to-linear isomerization of DASA molecules, and switches the surface back to hydrophobic. The wettability of the DASAs modified surface is reversible under alternately green light irradiating and heating.
INTRODUCTION Surface functionalized with stimuli-responsive molecules can switch the properties and states under controlling of pH, heat, light or reductive1. Surface with light-switched wettability has been extensively investigated due to the potential applications in cell-culturing, microfluidics, oil/water separation and printing2. Photoresponsive organic molecules, including azobenzene, spiropyran, coumarin, and o-nitrobenzyl derivatives are applied. The photoisomerization (azobenzene, spiropyan) or photolysis (coumarin, o-nitrobenzyl derivatives) enable the surface to switch polarity and wettability under controlling of light3. However, all the above molecules are only responsive to UV light (
